Equilibrium constants of triethanolamine in major seawater salts

Acid–base equilibrium constants of triethanolamine (TEA) have been determined by potentiometric titrations with a glass electrode, at 25 °C. Ionic strength was kept constant with only one electrolyte (using one of these salts: NaCl, KCl, MgCl₂ or CaCl₂), with binary mixtures of MgCl₂ and CaCl₂, and finally, in a solution with a composition approximately similar to that of natural seawater without sulfate. Equilibrium constants have been expressed in function of ionic strength by means of Pitzer equations and interaction parameters proposed in this theory have been obtained. It has been found that acid–base behaviour of TEA depends greatly on the salt used: basicity of TEA is decreased by CaCl₂, while it is increased by the other electrolytes used in this work.     

使用GAMIT进行高精度基线向量解算的方法与实践

GAM IT是国际上常用的GPS定位定轨软件,但由于其安装的平台(UN IX/LINUX)与我们通用的W indow s平台有所差异,使得GAM IT的入门较难。因此本文结合具体实例,介绍GAM IT的安装、基本操作以及应用GAM IT进行高精度基线向量解算,供初学者参考。     

全站仪交汇法在高速公路路面沉降监测中的应用

文章介绍了全站仪交会法沉降监测,方便简洁地解决了测量人员不能进入的高速公路等特殊位置的测量问题,并通过对该方法的精度分析,论证了其可行性和有效性,对以后类似的测量工作提供经验和依据。     

数字测图技术在阜新市地理数据库更新中的应用

采用GPS和全站仪联合作业的数字测图方式进行了外业快速数据采集。并利用南方CASS软件对数据进行内业成图工作,最后利用大型的地理信息系统软件ArcGIS进行地理数据的入库,从而实现了阜新市区地理数据库的更新,此方式具有速度快、效率高和精度高等优点,可以借鉴到同类的地区。     

GPS-RTK联合全站仪的野外数据采集

对于地形测绘和其它环境条件复杂的地区,用常规方法进行数据采集比较困难,传统的测绘方法越来越不能满足测量效率和成本的要求,但采用GPS RTK与全站仪联合作业,使RTK与全站仪优势互补,在保证测量精度的前提下,可大幅度提高测量速度和效率。     

The effect of acid deposition on base cation cycling in a karstic-forested catchment： Evidence from strontium isotopes

Bedrock weathering and atmospheric deposition are the two primary sources of base cations （K^＋, Na^＋, Ca^2＋ and Mg^2＋） to forest ecosystems. Therefore, the key problem is to understand the relative inputs from these two sources and the cycling in the ecosystem. This study focuses on the effects of acid deposition on cation cycling in a small-forested karstic catchment in Guizhou Province. Sr isotope ratios were used as a tracer for understanding the transport process between the different cation pools： rock, soil, surface water, atmospheric deposition and plant. The samples of wet deposition, total deposition, throughfall, surface and ground waters, vegetation, and soil were monthly collected. The exchangeable Sr^2＋ and Ca^2＋ in soil samples were extracted by using 1 M ammonium acetate. The leaf-tissue samples were ashed at 550℃, and the residue was digested in ultrapure HClO4 and HNO3. All water samples were filtrated through 0.45 μm aperture filter paper. Base cation concentrations and Sr isotopic composition were analyzed for all the samples. The results show that acid deposition （average pH 4.9） frequently occurred in the studied region. Cation abundance follows an increasing manner from rainwater, throughfall, to surface water or ground water samples, suggesting that acid deposition at first eiuviates Ca^2＋ , Mg^2＋ and Sr^2＋ from leaf, then the exchangeable cations from soil, and at last cations accumulate in surface water or ground water.     

MATLAB及其在重力基点网平差中的应用

MATLAB作为最优秀的数学软件之一，在国内外工程技术界产生愈来愈大的影响，其强大的数据计算和图形显示功能尤为突出。复杂的物探重力基点网平差计算通过用MATLAB的矩阵计算功能，变得简单易懂。而编制的MATLAB的M文件程序，计算快速准确。相信MATLAB在物探数据处理工作中将发挥重要的作用。     

Comparative study of the inelastic response of base isolated buildings

This article presents a numeric comparative study of the inelastic structural response of base isolated buildings. The comparative study includes the following isolation systems: laminated rubber bearings, New Zealand one, pure friction and the frictional pendulum ones. The study is based on obtaining non‐linear response spectra for various design parameters using six earthquake records. Usually the base isolation of a new building seeks to maintain the structure in the linear elastic range. The response of old weak buildings or the response of new ones subjected to extreme earthquakes may not be, necessarily, in the aforementioned ideal elastic range. Consequently, it is important to characterize the response of isolated buildings responding inelastically. A conclusion from this research is that the isolators affect significantly the structural response of weak systems. Rubber isolators seem slightly less sensitive to plastification that may occur in the structure compared to friction isolators. Ductility demands in the structure are affected significantly by friction and neoprene protected systems, in particular sliding ones where larger demands are obtained. Copyright © 2002 John Wiley & Sons, Ltd.     

空间点相对关系的精密检测

工业检测的精度一般要求很高，常规的检测手段难以达到。本文对空间点相对关系的精密检测方法和精度进行分析，实践表明该方法行之有效。     

按不同气候背景制作单站MOS预报方程

在基层业务体制的框架基本形成以后，县局在参考上级指导预报的同时，初步开展对单站数值预报模式的研究，注意中、小尺度天气的变化规律，以提高订正预报的精度。