激发态质子转移分子2-(2'-羟基苯基)苯并噻唑溶液的全光开关效应

研究了激发态质子转移(ESPT)分子2-(2'-羟基苯基)苯并噻唑(HBT)在不同极性溶剂中的光开关行为,探讨了溶剂极性对HBT分子光开光效应的影响.揭示了光开关脉冲信号的形成原因,建立了基于光诱导HBT分子激发态非线性折射效应的皮秒全光开关的理论模型.根据对时间响应函数的理论计算和实验结果分析,确定了光开关脉冲信号下降前沿和上升后沿的形成机理以及影响因素,并提出了增强光开关信号下降前沿的关断深度,提升上升后沿的恢复速度的有效途径和方法.本文工作为制成皮秒量级关断,微秒甚至纳秒量级重新打开的快速全光开关器     

Computational methods for fitting statistical distribution models of multi-site binding equilibria

Statistical distribution models of multi-site binding equilibria have potential applicability in the study of acid-base and metal complexation chemistry of humic substances in soils, sediments, and natural waters. A mathematical derivation is presented for the general continuous model for the case of proton binding; computational methods are described for fitting numerically the parameters in such models. Among models considered are those based on nontruncated, truncated, and bimodal (mixed) distributions. Specific emphasis is placed on Gaussian distribution models.     

一种适合定点使用的DTZ型质子旋进磁力仪

系统地介绍了ＤＴＺ系列质子旋进磁力仪的思路和性能特点，通过台站使用认为，ＤＴＺ系列仪器能满足地磁台观测精度的要求，具有实际使用的价值。     

“资源一号”卫星星内粒子探测器对扰动事件的观测

本文比较了在太阳平静和扰动时期“资源一号”卫星星内粒子探测器对卫星舱内高能粒子的观测结果，发现在平静时期观测结果很好地反映了辐射带高能粒子在该高度上的分布情况.在扰动时期，粒子探测器观测到高能粒子分布出现重大变化，本文进一步讨论了影响高能粒子在近地空间分布的可能因素.     

Relationship between global seismicity and solar activities

The relations between sunspot numbers and earthquakes (M≧6), solar 10.7 cm radio flux and earthquakes, solar proton events and earthquakes have been analyzed in this paper. It has been found that: (1) Earthquakes occur frequently around the minimum years of solar activity. Generally, the earthquake activities are relatively less during the peak value years of solar activity, some say, around the period when magnetic polarity in the solar polar regions is reversed. (2) the earthquake frequency in the minimum period of solar activity is closely related to the maximum annual means of sunspot numbers, the maximum annual means of solar 10.7 cm radio flux and solar proton events of a whole solar cycle, and the relation between earthquake and solar proton events is closer than others. (3) As judged by above interrelationship, the period from 1995 to 1997 will be the years while earthquake activities are frequent. In the paper, the simple physical discussion has been carried out. These results supported the exploration and studies of some researchers to a certain extent. This work is supported by Foundation of the Chinese Academy of Sciences (major item).     

The importance of energetic particle precipitation on the chemical composition of the middle atmosphere

An assessment is made of the relative contribution of certain classes of energetic particle precipitation to the chemical composition of the middle atmosphere with emphasis placed on the production of odd nitrogen and odd hydrogen species and their subsequent role in the catalytic removal of ozone. Galactic cosmic radiation is an important source of odd nitrogen in the lower stratosphere but since the peak energy deposition occurs below the region where catalytic removal of O₃ is most effective, it is questionable whether this mechanism is important in the overall terrestrial ozone budget. The precipitation of energetic solar protons can periodically produce dramatic enhancement in upper stratospheric NO. The long residence time of NO in this region of the atmosphere, where catalytic interaction with O₃ is also most effective, mandates that this mechanism be included in future modelling of the global distribution of O₃. Throughout the mesosphere the precipitation of energetic electrons from the outer radiation belt (60°70°) can sporadically act as a major local source of odd hydrogen and odd nitrogen leading to observable O₃ depletion. Future satellite studies should be directed at simultaneously measuring the precipitation flux and the concomitant atmosphere modification, and these results should be employed to develop more sophisticated models of this important coupling.     

Experimental study of the effect of temperature on ion cluster formation using ion mobility spectrometry

Ion mobility spectrometry offers a robust and effective technique to study ion clusters in ambient conditions. Here, we have experimentally studied the influence of temperature on the positive ion cluster formation of 2-propanol vapor in air, along with parallel measurements for n-butyl acetate vapor in air. For both of these low proton affinity compounds in the ppm concentration range, temperatures below 0 °C tend to favor formation of dimers and trimers. The measurements indicate that approximate estimations for the fractions of these n-mers (n > 1) in the ion spectra, can be obtained by classical theory for ion induced nucleation. Presence of natural background vapors however slightly blurs the data, especially for the fraction of monomers, so that accurate prediction of the fractions of n-mers in the spectra would require more accurate information on the gas composition. The findings concerning thermal behavior of ions help to understand better ion phenomena also in field conditions.     

Detection of high-energy solar neutrons and protons by ground level detectors on April 15, 2001

In association with the large solar flare of April 15, 2001, the Chacaltaya neutron monitor observed a 3.6σ enhancement of the counting rate between 13:51 and 14:15 UT. Since the enhancement was observed beginning 11 min before the GLE, solar neutrons must be involved in this enhancement. The integral energy spectrum of solar neutrons can be expressed by a simple power law in energy with the index γ=-3.0±1.0. On the other hand, an integral energy spectrum of solar protons has been obtained in the energy range between 650 MeV and 12 GeV. The spectrum can also be expressed by a power law with the power index γ=-2.75±0.15. The flux of solar protons observed at Chacaltaya (at 12 GeV) was already one order less than the flux of the galactic cosmic rays. It may be the first simultaneous observation of the energy spectra of both high-energy protons and neutrons. Comparing the Yohkoh soft X-ray telescope images with the observed particle time profiles, an interesting picture of the particle acceleration mechanism has been deduced.     

极光粒子沉降研究:谱形式及其在极区大气中的传输

分析了近年来南极地区极光沉降粒子的卫星、火箭、地面观测和研究结果,分别给出了极光椭圆区、极盖区、南大西洋异常区和极尖／极隙区粒子沉降的形式来源和特点。并根据磁尾研究的新进展,提出极光粒子沉降谱存在另外两种形式谱：（１）κ分布谱;（２）κ分布加上一个或多个脉冲谱,这两种谱来源于磁尾中性片区（绝热区非绝热区）。南极不同的区域,极光粒子有不同的沉降特点。这些沉降对极区电离层产生极大的影响。根据带电粒子在磁化大气中运动的Ｆｏｋｋｅｒ Ｐｌａｎｋ 方程,利用带电粒子在大气中传输的电离理论,导出极光粒子谱在极区大气中传播的解析表达式,对各种极光粒子谱在极区中的演化规律加以分析,并以此来解释在南极地区探测到的不同高度的极光电子谱的演化     

太阳质子事件耀斑的短期预报

回顾产生太阳质子事件耀斑的短期预报,讨论短期预报在近期应做的研究．给出以下结论：（１）在６０年代和７０年代,质子事件耀斑的预报有相当大的进展;（２）新预报方法的探索和质子流在日冕与行星际的传播问题,是当前改进短期预报的关键;（３）对实际应用的短期预报工作的改进,可能需要从空间天气预报的角度,研究太阳活动区的分类．