基于WS-Security的安全动态电子商务

Web服务方式的动态电子商务是电子商务的最终目标，安全问题是制约动态电子商务实现的主要因素。在介绍了WS-Security规范后，给出了一个建立动态电子商务的案例，分析了这个过程中可能面临的安全风险，提出了一种如何实现电子商务中重要的机密性、完整性问题的方法。     

Petrogenesis of andalusite–kyanite–sillimanite veins and host rocks, Sanandaj-Sirjan metamorphic belt, Hamadan, Iran

Quartz‐rich veins in metapelitic schists of the Sanandaj‐Sirjan belt, Hamadan region, Iran, commonly contain two Al₂SiO₅ polymorphs, and, more rarely, three coexisting Al₂SiO₅ polymorphs. In most andalusite and sillimanite schists, the types of polymorphs in veins correlate with Al₂SiO₅ polymorph(s) in the host rocks, although vein polymorphs are texturally and compositionally distinct from those in adjacent host rocks; e.g. vein andalusite is enriched in Fe₂O₃ relative to host rock andalusite. Low‐grade rocks contain andalusite + quartz veins, medium‐grade rocks contain andalusite + sillimanite + quartz ± plagioclase veins, and high‐grade rocks contain sillimanite + quartz + plagioclase veins/leucosomes. Although most andalusite and sillimanite‐bearing veins occur in host rocks that also contain Al₂SiO₅, kyanite‐quartz veins crosscut rocks that lack Al₂SiO₅ (e.g. staurolite schist, granite). A quartz vein containing andalusite + kyanite + sillimanite + staurolite + muscovite occurs in andalusite–sillimanite host rocks. Textural relationships in this vein indicate the crystallization sequence andalusite to kyanite to sillimanite. This crystallization sequence conflicts with the observation that kyanite‐quartz veins post‐date andalusite–sillimanite veins and at least one intrusive phase of a granite that produced a low‐pressure–high‐temperature contact aureole; these relationships imply a sequence of andalusite to sillimanite to kyanite. Varying crystallization sequences for rocks in a largely coherent metamorphic belt can be explained by P–T paths of different rocks passing near (slightly above, slightly below) the Al₂SiO₅ triple point, and by overprinting of multiple metamorphic events in a terrane that evolved from a continental arc to a collisional orogen.     

江西省武功山地区浒坑钨矿床的Re-Os年龄及其地质意义

浒坑钨矿床是位于江西省中部武功山成矿带的大型石英脉型黑钨矿床。为了确定该矿床的成矿时代,笔者选取了浒坑含钨石英脉中与黑钨矿共生的辉钼矿进行了高精度Re-Os同位素定年,并获得5个辉钼矿样品的Re-Os等时线年龄和模式加权平均年龄分别为150.2±2.2Ma和149.82±0.92Ma。测年数据表明浒坑钨矿床的成矿时代为150Ma左右,是华南地区中生代大规模成岩成矿作用高峰期的产物。辉钼矿含铼较低,表明成矿物质可能来自壳源,与形成浒坑花岗岩体的燕山期重熔S型花岗岩岩浆活动有关。该矿床形成于燕山期岩石圈伸展减薄环境。     

高地震区公路隧道地震动力响应分析

基于土一结构相互作用理论,对高地震区一实际重大工程的公路隧道洞口段结构进行了抗震计算,得到了衬砌结构各控制点的位移、加速度及内力响应规律。结果表明：在人工合成地震波条件下,衬砌墙脚、拱腰为抗震薄弱位置;结构的加速度波形与输入波形相似;这些结果为抗震设计提供了一些依据。     

Syntectonic Mobility of Supergene Nickel Ores of New Caledonia (Southwest Pacific). Evidence from Garnierite Veins and Faulted Regolith

Supergene nickel deposits of New Caledonia that have been formed in the Neogene by weathering of obducted ultramafic rocks are controlled by fracture development. The relationship of tropical weathering and tectonic structures, faults and tension gashes, have been investigated in order to determine whether fractures play a passive role only, as previously thought; or alternatively, if brittle tectonics was acting together with alteration. Observation of time‐relationship, textures, and mineralogy of various fracture fills and fault gouges shows that active faulting has played a prominent role not only in facilitating drainage and providing room for synkinematic crystallization of supergene nickel silicate, but also in mobilizing already formed sparse nickel ore, producing the very high grade ore nicknamed “green gold”.     

Albite vein formation during exhumation of high-pressure terranes: a case study from alpine Corsica

The formation of late‐stage veins can yield valuable information about the movement and composition of fluids during uplift and exhumation of high‐pressure terranes. Albite veins are especially suited to this purpose because they are ubiquitously associated with the greenschist facies overprint in high‐pressure rocks. Albite veins in retrogressed metabasic rocks from high‐pressure ophiolitic units of Alpine Corsica (France) are nearly monomineralic, and have distinct alteration haloes composed of actinolite + epidote + chlorite + albite. Estimated P–T conditions of albite vein formation are 478 ± 31 °C and 0.37 ± 0.14 GPa. The P–T estimates and petrographic constraints indicate that the albite veins formed after the regional greenschist facies retrogression, in response to continued decompression and exhumation of the terrane. Stable isotope geochemistry of the albite veins, their associated alteration haloes and unaltered hostrocks indicates that the vein‐forming fluid was derived from the ophiolite units and probably from the metabasalts within each ophiolite slice. That the vein‐forming fluid was locally derived means that a viable source of fluid to form the veins was retained in the rocks during high‐pressure metamorphism, indicating that the rocks did not completely dehydrate. This conclusion is supported by the observation of abundant lawsonite at the highest metamorphic grades. Fluids were liberated during retrogression via decompression dehydration reactions such as those that break down hydrous high‐pressure minerals like lawsonite. Albite precipitation into veins is sensitive to the solubility and speciation of Al, which is more pressure sensitive than other factors which might influence albite vein formation such as silica saturation or Na:K fluid ratios. Hydraulic fracturing in response to fluid generation during decompression was probably the main mechanism of vein formation. The associated pressure decrease with fracturing and fluid decompression may also have been sufficient to change the solubility of Al and drive albite precipitation in fracture systems.     

羌塘盆地最大规模沥青脉的发现及其意义

在羌塘盆地已经发现了190余处油气显示。近年笔者在盆地北部晚侏罗世地层中发现了迄今最大规模的沥青脉。研究结果表明，该沥青脉产出于上侏罗统索瓦组地层之中，地层下部系与沥青脉的形成有一定关系的中株罗统夏里组局部含油气显示的盐丘。沥青族组分(％)为：饱和烃5．72、芳烃18．46、沥青质52.37、非烃23．45，说明核沥青脉经过了运移、氮化的过程。同时，沥青脉产出于复背斜范围内，利于油气聚集成藏。这一发现对于羌塘盆地的油气地质的作用具有现实意义。     

砂宝斯金矿区多矿物脉特征及其对砂岩的改造

砂宝斯矿区的成矿围岩为长石石英砂岩，砂岩被多期次的石英脉、方解石脉和高岭石脉所穿切，这些多矿物脉是热液流体运移的结果。矿物脉形成过程中对围岩进行了热改造，使砂岩发生了压溶作用、胶结作用和溶蚀作用，形成了蚀变砂岩。由于流体酸碱性和温压的变化，孔隙水介质的性质由酸性向碱性转变，在酸性成岩环境下形成的蚀变高岭石、伊利石将转变成绿泥石、绢云母等。绢云母的大量出现，石英次生加大和自生粘土矿物的形成均是热液流体活动的产物。     

砂岩岩脉(岩墙、岩床)的一种可能成因——冲蚀沟槽的充填

黄河三角洲的边滩、心滩上发育了大量冲蚀沟槽（冲槽）．这些冲蚀沟槽深数厘米至1m～2m，宽数厘米至数米，长数十厘米至十几、二十余米，但以深数十厘米，宽数厘米至十余厘米，长数米者多见。形态多样，有直立板片状、直立楔状、“⊥”状、梯形状、“U”形状及树枝状等，其内有时被风成砂充填。经成岩作用后，它们便会转变成砂岩岩脉（岩墙、岩床）。因此，冲蚀沟槽的（砂）充填可能是一种砂岩岩脉（岩墙、岩床）的形成方式．