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1.
Chris Yakymchuk Adrian Rehm Zhuoheng Liao John M. Cottle 《Journal of Metamorphic Geology》2019,37(6):839-862
Sapphirine–quartz granulites from the Cocachacra region of the Arequipa Massif in southern Peru record early Neoproterozoic ultrahigh‐temperature metamorphism. Phase equilibrium modelling and zircon petrochronology are used to quantify timing and pressure–temperature (P–T) conditions of metamorphism. Modelling of three magnetite‐bearing sapphirine–quartz samples indicates peak temperatures of >950°C at ~0.7 GPa and a clockwise P–T evolution. Elevated concentrations of Al in orthopyroxene are also consistent with ultrahigh‐temperature conditions. Neoblastic zircon records ages of c. 1.0–0.9 Ga that are interpreted to record protracted ultrahigh‐temperature metamorphism. Th/U ratios of zircon of up to 100 reflect U‐depleted whole‐rock compositions. Concentrations of heavy rare earth elements in zircon do not show systematic trends with U–Pb age but do correlate with variable whole‐rock compositions. Very large positive Ce anomalies in zircon from two samples probably relate to strongly oxidizing conditions during neoblastic zircon crystallization. Low concentrations of Ti‐in‐zircon (<10 ppm) are interpreted to result from reduced titania activities due to the strongly oxidized nature of the granulites and the sequestration of titanium‐rich minerals away from the reaction volume. Whole‐rock compositions and oxidation state have a strong influence on the trace element composition of metamorphic zircon, which has implications for interpreting the geological significance of ages retrieved from zircon in oxidized metamorphic rocks. 相似文献
2.
Based on the Intensive Field Campaign(IFC-1)data of Boreal Ecosystem-Atmosphere Study(BOREAS).a three-dimensional meso-β scale model is used to simulate the effect of boreal forests onthe lower atmosphere.A fine horizontal resolution of 2 km×2 km is used in order to distinguish thevegetative heterogeneity in the boreal region.A total of 20×25 grid points cover the entire sub-modeling area in BOREAS' South Study Area(SSA).The ecosystem types and their coverage ineach grid square are extracted from the North American Land Cover Characteristics Data Base(NALCCD)generated by the U.S.Geographical Survey(USGS)and the University of Nebraska-Lincoln(UNL).The topography of the study area is taken from the Digital Elevation Map(DEM)of USGS.The model outputs include the components of the energy balance budget within the canopyand at the ground.the turbulence parameters in the atmospheric boundary layer and the wind.temperature and humidity profiles extending up to a height of 1500 m.In addition to the fine timeand spatial step,the unique feature of the present model is the incorporation of both dynamic andbiological effects of the Boreal forest into the model parameterization scheme.The model resultscompare favorably with BOREAS' IFC-1 data in 1994 when the forest was in the luxuriant growingperiod. 相似文献
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Vertical measurements of , and N2O concentrations, and uptake, and oxidation rates were measured at 5 sites in western Cook Strait, New Zealand, between 31 March and 3 April 1983. Nitrate increased with depth at all stations reaching a maximum of 10.5 μg-atom at the most strongly stratified station whereas was relatively constant with depth at all stations (~0.1 μg-atom ). The highest rates of oxidation generally occurred in the near surface waters and decreased with depth. N2O levels were near saturation with respect to the air above the sea surface and showed no obvious changes during 24 h incubation. oxidation by nitrifying bacteria may account for about 30% of the total utilization (i.e. bacterial+agal) and, assuming oxidation through to , may supply about 40% of the algal requirements of in the study area. These results suggest that bacterial nitrification is of potential importance to the nitrogen dynamics of the western Cook Strait, particularly with respect to the nitrogen demands of the phytoplankton. 相似文献
6.
1IntroductionOne of the key factors related to basin geody-namics is deep process controlling formation and evolution of sedimentary basin. Depth and tempera-ture of asthenosphere,existence of mantle plume,occurrence of mantle melting,and amounts of melts under depressurization during thinning of lithosphere are controlling factors influenced formation and characteristics of extensional basin directly (Li,1994). Rifting is probably governed by frictional forces exerted on the base of litho… 相似文献
7.
Manoj K. Pandit Helga de Wall Narendra K. Chauhan 《Journal of Earth System Science》2008,117(3):201-209
A number of fine-grained sericite bearing pelitic, schistose lithologies occur along the Archean (Banded Gneiss Complex)-Proterozoic
(Aravalli Supergroup) contact (APC) in the Udaipur valley in NW Indian craton. These Al-rich lithologies (subsequently metamorphosed)
have been described as ‘paleosols’, developed over a 3.3 Ga old Archean gneissic basement and are overlain by Paleoproterozoic
Aravalli quartzite. The paleosol was developed between 2.5 and 2.1, coincident with the globally recognized Great Oxidation
Event (GOE). In previous studies these paleosol sections were interpreted to have developed under reducing environment, however,
the finding of a ‘ferricrete’ zone in the upper part of Tulsi Namla section (east of Udaipur) during the present study (in
addition to earlier reported lithologies) has led to an alternative suggestion of oxygen-rich conditions during paleosol development.
The Tulsi Namla paleosol section shows all the features characteristic of a complete paleosol section described from other
Archean cratons. The paleosol includes sericite schist with kyanite as the prevalent Al-silicate in the lower part of profile
while chloritoid and Fe-oxides typify the Fe-rich upper part. Alumina has remained immobile during the weathering process
while Fe and Mn show a decrease in the lower part of the section and an abrupt rise in the upper part, in the ferricrete zone.
The field and geochemical data indicate that the Tulsi Namla section is an in situ weathering profile and at least the upper part shows evidence of oxidizing conditions. 相似文献
8.
Correlations between heavy metals and organic carbon extracted by dry oxidation procedure in urban roadside soils 总被引:1,自引:0,他引:1
Xue Song Wang 《Environmental Geology》2008,54(2):269-273
The organic fraction in soils has a significant influence on heavy metal transport. In this study, the organic carbon content
was measured by dry oxidation procedure from 21 Xuzhou urban roadside soils to assess the relationships between the concentrations
of heavy metals (Pb, Cu, Zn, and Cr) and the amount of organic carbon. The anthropogenic heavy metals (e.g. Pb, Cu, Zn) were
strongly correlated with organic carbon (denoted by Corg−c) extracted by dry oxidation while natural heavy metal (e.g. Cr) showed no correlation to the Corg−c. The anthropogenic heavy metals were also strongly correlated with the amount of the total carbon. These results show that
the anthropogenic heavy metals are mainly enriched in the organic matter in the Xuzhou urban roadside soils. 相似文献
9.
Mauro Lo Cascio Yan Liang Nobumichi Shimizu Paul C. Hess 《Contributions to Mineralogy and Petrology》2008,156(1):87-102
The grain-scale processes of peridotite melting were examined at 1,340°C and 1.5 GPa using reaction couples formed by juxtaposing
pre-synthesized clinopyroxenite against pre-synthesized orthopyroxenite or harzburgite in graphite and platinum-lined molybdenum
capsules. Reaction between the clinopyroxene and orthopyroxene-rich aggregates produces a melt-enriched, orthopyroxene-free,
olivine + clinopyroxene reactive boundary layer. Major and trace element abundance in clinopyroxene vary systematically across
the reactive boundary layer with compositional trends similar to the published clinopyroxene core-to-rim compositional variations
in the bulk lherzolite partial melting studies conducted at similar P–T conditions. The growth of the reactive boundary layer takes place at the expense of the orthopyroxenite or harzburgite and
is consistent with grain-scale processes that involve dissolution, precipitation, reprecipitation, and diffusive exchange
between the interstitial melt and surrounding crystals. An important consequence of dissolution–reprecipitation during crystal-melt
interaction is the dramatic decrease in diffusive reequilibration time between coexisting minerals and melt. This effect is
especially important for high charged, slow diffusing cations during peridotite melting and melt-rock reaction. Apparent clinopyroxene-melt
partition coefficients for REE, Sr, Y, Ti, and Zr, measured from reprecipitated clinopyroxene and coexisting melt in the reactive
boundary layer, approach their equilibrium values reported in the literature. Disequilibrium melting models based on volume
diffusion in solid limited mechanism are likely to significantly underestimate the rates at which major and trace elements
in residual minerals reequilibrate with their surrounding melt.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
10.