Triassic Nb-enriched basalts, magnesian andesites, and adakites of the Qiangtang terrane (Central Tibet): evidence for metasomatism by slab-derived melts in the mantle wedge

New chronological, geochemical, and isotopic data are reported for Triassic (219–236 Ma) adakite-magnesian andesite-Nb-enriched basaltic rock associations from the Tuotuohe area, central Qiangtang terrane. The adakites and magnesian andesites are characterized by high Sr/Y (25–45), La/Yb (14–42) and Na₂O/K₂O (12–49) ratios, high Al₂O₃ (15.34–18.28 wt%) and moderate to high Sr concentrations (220–498 ppm) and ε_ND (t) (+0.86 to +1.21) values. Low enrichments of Th, Rb relative to Nb, and subequal normalized Nb and La contents, and enrichments of light rare earth elements combine to distinguish a group of Nb-enriched basaltic rocks (NEBs). They have positive ε_ND (t) (+2.57 to +5.16) values. Positive correlations between Th, La and Nb and an absence of negative Nb anomalies on mantle normalized plots indicate the NEBs are products of a mantle source metasomatized by a slab melt rather than by hydrous fluids. A continuous compositional variation between adakites and magnesian andesites confirms slab melt interaction with mantle peridotite. The spatial association of the NEBs with adakites and magnesian andesites define an “adakitic metasomatic volcanic series” recognized in many demonstrably subduction-related environments (e.g., Mindanao arc, Philippines; Kamchatka arc, Russia; and southern Baja California arc, Mexico). The age of the Touhuohe suite, and its correlation with Triassic NEB to the north indicates that volcanism derived from subduction-modified mantle was abundant prior to 220 Ma in the central Qiangtang terrane.     

Petrology and U-Pb Zircon Geochronology of Amphibole-rich Cumulates with Sanukitic Affinity from Husky Ridge (Northern Victoria Land, Antarctica): Insights into the Role of Amphibole in the Petrogenesis of Subduction-related Magmas

A microanalytical trace element and geochronological study wascarried out on mafic amphibole-rich cumulates (quartz diorites)cropping out in northern Victoria Land (Antarctica). Associatedtonalites and basement rocks were also investigated. Rock texturesand major and trace element mineral compositions reveal thepresence in quartz diorites of two mineral assemblages: (1)clinopyroxene-I + brown amphibole ± dark mica; (2) clinopyroxene-II+ green amphibole + plagioclase + quartz. Both mineral assemblagescontain mafic phases with elevated Mg-number, but their traceelement signatures differ significantly. In situ U–Pbzircon geochronology was carried out to support petrogeneticand geological interpretations. Quartz diorites were emplacedin the mid-crust probably at 516 ± 3 Ma. Parental meltsof quartz diorites were computed by applying solid/liquid partitioncoefficients. The melt in equilibrium with the first mineralassemblage (melt-I) is extremely depleted in heavy rare earthelements (HREE), Y, Ti, Zr and Hf (at about 0·2 timesnormal mid-ocean ridge basalt) and enriched in B, Th, U, thelarge ion lithophile elements and light REE (LREE). It sharesmany similarities with sanukitic melts (e.g. Setouchi andesites),which originated by equilibration of subduction-derived sedimentmelts with a refractory mantle. The melt in equilibrium withthe second mineral assemblage (melt-II) is characterized bya steep LREE enrichment (La_N/Yb_N up to 39), a U-shaped HREEpattern and low Ti, which is depleted relative to HREE. Thetrace element signature of melt-II can be acquired through amphibolecrystallization starting from a sanukitic melt similar to melt-I,probably in a deeper magma chamber. Our results allow us toconstrain that melts from the subducted slab were produced ona regional scale, in accordance with literature data, belowa large sector of the east Gondwana margin during the mid-Cambrian.Implications for the role of amphibole in petrogenesis of subduction-relatedmagmas are also discussed. KEY WORDS: amphibole; sanukite; high-Mg andesites; Ross Orogeny; Antarctica     

Petrogenesis of orthopyroxene- and amphibole-bearing andesites, Mustique, Grenadine Islands, Lesser Antilles Arc: Isotope, trace element and physical constraints

Abstract On the island of Mustique, fresh and propylitized olivine–plagioclase–clinopyroxene basalt, plagioclase–clinopyroxene–orthopyroxene and plagioclase–clinopyroxene–amphibole andesite lavas and minor intrusions are interbedded with Oligocene pyroclastic and epiclastic rocks. Chemical data show that two isotopically identical, but chemically different, suites of lava are present: (i) the OPXS (⁸⁷Sr/⁸⁶Sr 0.70403–0.70454; ¹⁴³Nd/¹⁴⁴Nd 0.512952–0.512986; δ¹⁸O_cpx 5.49 and 5.61), comprising basalts and orthopyroxene‐bearing andesites; and (ii) the AMPHS (⁸⁷Sr/⁸⁶Sr 0.70401–0.70457; ¹⁴³Nd/¹⁴⁴Nd 0.512981–0.513037; δ¹⁸O_cpx 5.54), made up of basalts and amphibole‐bearing andesites. The OPXS has higher contents of TiO₂, P₂O₅, light rare earth elements, Sm, Pb, Th, U, Zr, Y and Nb, and higher La/Yb ratios than the AMPHS. The isotopic data suggest that both suites formed from melts derived from the same subduction‐modified depleted mantle source as the volcanic rocks of nearby St Vincent and Bequia, and the northern islands of the Lesser Antilles Arc. The immobile trace element contents, and La/Yb ratios, of the OPXS are indicative of ～10% partial melting of the source, whereas those of the AMPHS are indicative of ～25% partial melting. The within‐suite chemical variation of the OPXS is consistent with ～45% fractional crystallization of its intratelluric mineral assemblages, and that of the AMPHS is consistent with the removal of ～65% of its intratelluric assemblages. Experimental evidence suggests that both suites of basalt crystallized at pressures <8 kbar from melts containing 1–2 wt% water. After extensive fractional crystallization, the andesites crystallized at pressures between approximately 5 and 2 kbar. The OPXS magmas appear to have lost more of their water content than the AMPHS magmas. Thus, the OPXS andesites formed from melts with an estimated water content of 2–3 wt%, whereas the AMPHS andesites formed from melts containing at least 4.5 wt% water.     

右江盆地晚侏罗世钾玄质高镁安山岩的厘定及其构造意义

右江盆地在大地构造上处于特提斯和滨太平洋构造域的结合部位。本文报道了该盆地东部杨屯安山岩的岩相学、年代学和地球化学特征。杨屯安山岩具斑状结构和气孔状构造,斑晶主要为辉石,基质以针状斜长石微晶为主,含少量辉石。LA-ICP-MS锆石U-Pb定年结果表明杨屯安山岩的喷发时代为159.3±2.8Ma,即晚侏罗世。样品的Si O2含量为53.13%~55.71%,具高MgO(6.74%~8.85%)、Mg#值(63~72)、Cr(416×10~(-6)~565×10~(-6))和Ni(207×10~(-6)~246×10~(-6)),低Fe OT/MgO(0.83~1.23)等特征,与典型高镁安山岩的特征相似。所有样品具高K2O(3.39%~4.77%)和K2O/Na2O(1.31~2.33),同时也具钾玄质岩石的地球化学特征。样品强烈富集大离子亲石元素和轻稀土元素,而亏损高场强元素,具较高的Rb/Sr(0.20~0.46)和较低的Ba/Rb(7.17~9.30),富集的Sr-Nd同位素组成((87Sr/86Sr)i=0.70738~0.70739,εNd(t)=-3.6~-3.4)。元素和同位素特征表明杨屯钾玄质高镁安山岩是含金云母的富集岩石圈地幔部分熔融的产物,形成于板内伸展环境而不是岛弧环境。晚侏罗世杨屯钾玄质高镁安山岩的厘定,反映了该时期右江地区处于岩石圈伸展-减薄阶段。     

藏北羌塘中部日湾茶卡地区晚三叠世安山岩与闪长质包体岩石成因及地质意义

龙木错-双湖-澜沧江缝合带将羌塘板块划分为南、北2个次级板块,在缝合带两侧大规模发育晚三叠世岩浆作用,并伴随大量的高压超高压变质岩。在缝合带以南的日湾茶卡地区识别出一套安山岩,其中发育大量的暗色闪长质捕虏体,锆石U-Pb测年结果在安山岩中获得了364.7±1.9Ma和223.9±1.3Ma两组年龄信息,锆石原位Hf同位素测试结果εHf(t)分别为+7.22~+8.69和-5.94~-4.14。结合羌塘中部已有的研究成果,认为闪长质捕虏体形成于晚泥盆世洋壳俯冲背景,是地幔楔部分熔融底侵至地壳的产物;而安山岩形成于晚三叠世碰撞后伸展背景,是深部板片断离机制下深俯冲陆壳边缘一侧熔体混染晚泥盆世新生地壳的产物。安山岩中闪长质捕虏体的发现支持了俯冲带作为大陆生长的重要场所的观点。     

Sugarloaf Mountain,central Arizona,USA: A small-scale example of Miocene basalt-rhyolite magma mixing to yield andesitic magmas

Sugarloaf Mountain is a 200-m high volcanic landform in central Arizona, USA, within the transition from the southern Basin and Range to the Colorado Plateau. It is composed of Miocene alkalic basalt (47.2–49.1?wt.% SiO₂; 6.7–7.7?wt.% MgO) and overlying andesite and dacite lavas (61.4–63.9?wt.% SiO₂; 3.5–4.7?wt.% MgO). Sugarloaf Mountain therefore offers an opportunity to evaluate the origin of andesite magmas with respect to coexisting basalt. Important for evaluating Sugarloaf basalt and andesite (plus dacite) is that the andesites contain basaltic minerals olivine (cores Fo_76-86) and clinopyroxene (～Fs_9-18Wo_35-44) coexisting with Na-plagioclase (An_48-28Or_1.4–7), quartz, amphibole, and minor orthopyroxene, biotite, and sanidine. Noteworthy is that andesite mineral textures include reaction and spongy zones and embayments in and on Na-plagioclase and quartz phenocrysts, where some reacted Na-plagioclases have higher-An mantles, plus some similarly reacted and embayed olivine, clinopyroxene, and amphibole phenocrysts.Fractional crystallization of Sugarloaf basaltic magmas cannot alone yield the andesites because their ～61 to 64?wt.% SiO₂ is attended by incompatible REE and HFSE abundances lower than in the basalts (e.g., Ce 77–105 in andesites vs 114–166?ppm in basalts; Zr 149–173 vs 183–237; Nb 21–25 vs 34–42). On the other hand, andesite mineral assemblages, textures, and compositions are consistent with basaltic magmas having mixed with rhyolitic magmas, provided the rhyolite(s) had relatively low REE and HFSE abundances. Linear binary mixing calculations yield good first approximation results for producing andesitic compositions from Sugarloaf basalt compositions and a central Arizona low-REE, low-HFSE rhyolite. For example, mixing proportions 52:48 of Sugarloaf basalt and low incompatible-element rhyolite yields a hybrid composition that matches Sugarloaf andesite well ? although we do not claim to have exact endmembers, but rather, viable proxies. Additionally, the observed mineral textures are all consistent with hot basalt magma mixing into rhyolite magma. Compositional differences among the phenocrysts of Na-plagioclase, clinopyroxene, and amphibole in the andesites suggest several mixing events, and amphibole thermobarometry calculates depths corresponding to 8–16?km and 850° to 980?°C. The amphibole P-T observed for a rather tight compositional range of andesite compositions is consistent with the gathering of several different basalt-rhyolite hybrids into a homogenizing ‘collection' zone prior to eruptions. We interpret Sugarloaf Mountain to represent basalt-rhyolite mixings on a relatively small scale as part of the large scale Miocene (～20 to 15 Ma) magmatism of central Arizona. A particular qualification for this example of hybridization, however, is that the rhyolite endmember have relatively low REE and HFSE abundances.     

广州增城地质公园安山质-流纹质火山岩地球化学特征及Rb-Sr年龄测定

广州市增城地质公园发育有大量的燕山期安山岩和流纹岩,由于缺少详细的岩石地球化学研究,这些火山岩的成因和所代表的大地构造意义一直未明确.文章对上述火山岩进行了较为系统的全岩地球化学以及同位素地球化学分析.研究结果显示,安山岩具有安第斯型火山岩特点,显示Nb、Ta、Sr和Ti的亏损,Isr值介于0.70332～0.7144...     

北秦岭黑河丹凤群岛弧火山岩建造的发现及其构造意义

陕西省周至县黑河丹凤群有大规模安山岩浆活动的证据，地球化学研究表明这些安山岩形成于典型的岛弧环境，如：轻稀土富集；在痕量元素原始地幔标准化丰度模型图上，所有样品均具有明显的Ｎｂ、Ｔｉ和Ｐ负异常；在Ｂａ－Ｎｂ－Ｔｈ－Ｌａ图解上，所有样品均落在岛弧区等。由此可以推断黑河丹凤群有一套安山岩为主的岛弧火山岩建造。这一发现为证明北秦岭古生代岛弧构造环境提供了重要的证据，为进一步揭示秦岭造山带的构造格架和演化历史提供了信息。     

Anhydrous and water-saturated melting experiments of an olivine andesite from Mt Yakushi-Yama, northeastern Shikoku, Japan

Abstract Melting experiments have been carried out on an olivine andesite of Mt Yakushi-Yama from the Miocene Setouchi volcanic belt in northeastern Shikoku, Japan. This andesite has been characterized by a low ratio of FeO*/Mg° (= 0.78). Phase relations have been determined within the pressure range of 2.8 to 19.3 kbar at 1000-1300°C under anhydrous and water-saturated conditions. At pressures less than 8.8 kbar, olivine is a liquidus phase. Orthopyroxene appears on the liquidus at 9.3 kbar under the anhydrous conditions. The multiple saturation point rises up to 17.5 kbar for water-saturated experiments. The andesite melt coexists with olivine and orthopyroxene just below the liquidus at 8.8–9.3 kbar and 1230°C for dry conditions, and at 17.5 kbar and 1060°C under water-saturated conditions. These experimental results indicate that the Yakushi-Yama olivine andesite magma could coexist with a harzburgitic mantle at depths between about 30 and 60 km, and at temperatures between 1060 and 1230°C. Experimental data also suggest a possibility that a high magnesian andesite magma would be generated by a direct partial melting of the uppermost harzburgitic mantle under anhydrous conditions.