Geochemistry and provenance of the Turquoise Bluff Slate,northeastern Tasmania: tectonic significance

The Ordovician Turquoise Bluff Slate in northeastern Tasmania is a 2?km-thick sequence of deep-marine siliceous black slates. It is dominated by meta-siltstones with bimodal grainsize distributions typical of turbidite T_E-1 and T_E-2 facies. The slates have high SiO₂ indicating they are hemipelagites. The high Ba and V indicate they were deposited in an anoxic environment associated with high oceanic productivity. All these features are common in muddy turbidites. U–Th–Pb dating of detrital monazite and authigenic xenotime in the slates supports previous evidence that the dominant cleavage, in this unit, formed during the Benambran Orogeny. The whole-rock composition of the slates is similar to black slates in the Adaminaby Group, NSW. A review of Paleozoic whole-rock compositions from the Lachlan Orogen confirms they all have trace element contents similar to average Australian shale. However, there are subtle differences in composition. The Turquoise Bluff Slate and other Mathinna Supergroup rocks from the Eastern Tasmania Terrane have higher average Cr content than similar age turbidites from Victoria and NSW. This probably reflects a small contribution from Tasmania Cambrian ultramafic rocks in the provenance. If this were correct, northeastern Tasmania was closer to western Tasmania in the Paleozoic than other provinces of the Lachlan Orogen, southeastern Australia. Other subtle features of the whole-rock composition of Paleozoic sedimentary rocks from the Lachlan Orogen indicate it may be possible to recognise provincial variations in composition that will provide new constraints on tectonic models of southeastern Australia.     

Contrasting environmental effects of astronomically driven climate change on three Eocene hemipelagic successions from the Basque–Cantabrian Basin

Several processes can contribute to the formation of hemipelagic limestone–marl alternations as a consequence of astronomically driven climate change. The aim of this study was to decipher which environmental factors governed the formation of three Eocene hemipelagic successions of the Basque–Cantabrian Basin using a comprehensive set of physical and bulk carbonate geochemical data (bed thickness, mineralogy, %CaCO₃, δ¹³C and δ¹⁸O). The results show that the significance of several environmental processes varied depending on the palaeogeographic setting and eccentricity‐modulated precessional seasonality. In the Sopelana starved deep‐sea basin, limestones were formed as a consequence of high pelagic carbonate productivity during periods of warm seawater and sluggish circulation, which corresponded with periods of low seasonality (summers at aphelion); conversely, marls accumulated when pelagic carbonate productivity decreased during periods with cooler waters and more vigorous circulation, which occurred when seasonality was higher (summers at perihelion). In the Gorrondatxe submarine fan fringe, marls accumulated when high seasonality produced significant continental rainfall and run‐off, causing the dilution of pelagic carbonate sedimentation with terrigenous supplies. In the Oyambre upper slope, marls also accumulated when seasonality was high, as pelagic carbonate productivity decreased due to both the expansion of low‐salinity waters on the ocean surface and the increase in continentally derived nutrients, which caused detrimental seawater conditions for calcareous plankton. Both in Gorrondatxe and Oyambre, limestones accumulated when boreal summer at aphelion caused low seasonality, which allowed relatively stable conditions to prevail. At minimum eccentricity, when precession‐driven seasonality contrast diminished, changes in pelagic carbonate productivity were significant in the three sections. On the contrary, at maximum eccentricity, when seasonality peaked due to summers occurring at perihelion, the effects of other environmental processes, such as continental and oceanic currents, became influential. However, the influence of these processes minimized when summertime coincided with aphelion at maximum eccentricity and seasonality was weakest.     

Evaluation of bulk carbonate δ13C data from Triassic hemipelagites and the initial composition of carbonate mud

Bulk carbonate samples of hemipelagic limestone–marl alternations from the Middle and Upper Triassic of Italy are analysed for their isotopic compositions. Middle Triassic samples are representative of the Livinallongo Formation of the Dolomites, while Upper Triassic hemipelagites were sampled in the Pignola 2 section, within the Calcari con Selce Formation of the Southern Apennines in Southern Italy. Triassic hemipelagites occur either as nodular limestones with chert nodules or as plane‐bedded limestone–marl alternations which are locally silicified. In the Middle Triassic Livinallongo Formation, diagenetic alteration primarily affected the stable isotopic composition of sediment surrounding carbonate nodules, whereas the latter show almost pristine compositions. Diagenesis lowered the carbon and oxygen isotope values of bulk carbonate and introduced a strong correlation between δ¹³C and δ¹⁸O values. In the Middle Triassic successions of the Dolomites, bulk carbonate of nodular limestone facies is most commonly unaltered, whereas carbonate of the plane‐bedded facies is uniformly affected by diagenetic alteration. In contrast to carbonate nodules, plane‐bedded facies often show compaction features. Although both types of pelagic carbonate rocks show very similar petrographic characteristics, scanning electron microscopy studies reveal that nodular limestone consists of micrite (< 5 μm in diameter), whereas samples of the plane‐bedded facies are composed of calcite crystals ca 10 μm in size showing pitted, polished surfaces. These observations suggest that nodular and plane‐bedded facies underwent different diagenetic pathways determined by the prevailing mineralogy of the precursor sediment, i.e. probably high‐Mg calcite in the nodular facies and aragonite in the case of the plane‐bedded facies. Similar to Middle Triassic nodular facies, Upper Triassic nodular limestones of the Lagonegro Basin are also characterized by uncorrelated δ¹³C and δ¹⁸O values and exhibit small, less than 5 μm size, crystals. The alternation of calcitic and aragonitic precursors in the Middle Triassic of the Dolomites is thought to mirror rapid changes in the type of carbonate production of adjacent platforms. Bioturbation and dissolution of metastable carbonate grains played a key role during early lithification of nodular limestone beds, whereby early stabilization recorded the carbon isotopic composition of sea water. The bulk carbonate δ¹³C values of Middle and Upper Triassic hemipelagites from Italy agree with those of Tethyan low‐Mg calcite shells of articulate brachiopods, confirming that Triassic hemipelagites retained the primary carbon isotopic composition of the bottom sea water. A trend of increasing δ¹³C from the Late Anisian to the Early Carnian, partly seen in the data set presented here, is also recognized in successions from tropical palaeolatitudes elsewhere. The carbon isotopic composition of Middle and Upper Triassic nodular hemipelagic limestones can thus be used for chemostratigraphic correlation and palaeoenvironmental studies.     

马里亚纳海槽的沉积

马里亚纳海槽是一个正在扩张的弧后盆地。文章分析中国和联邦德国合作考察马里亚纳海槽两个沉积岩心的一般沉积特征、物质来源及其影响因素。两岩心沉积物均以砂质粉砂、粉砂和粘土质粉砂为主,含较多黑色火山灰层和黑色纹理,岩性分析表明,物质以火山碎屑为主。由于两岩心所处具体构造位置不同,导致岩性、构造和物质来源不同。61KL岩心有4或5个递变层序,为典型的浊流沉积,物质主要来自东部活动的马里亚纳火山弧,由浊流搬运而沉积。57KL岩心物质主要来自海槽扩张裂谷本身的火山喷发。两岩心均为半远洋沉积物。     

Evolution of an accretionary complex along the north arm of the Island of Sulawesi, Indonesia

Abstract Seismic reflections across the accretionary prism of the North Sulawesi provide excellent images of the various structural domains landward of the frontal thrust. The structural domain in the accretionary prism area of the North Sulawesi Trench can be divided into four zones: (i) trench area; (ii) Zone A; (iii) Zone B; and (iv) Zone C. Zone A is an active imbrication zone where a decollement is well imaged. Zone B is dominated by out‐of‐sequence thrusts and small slope basins. Zone C is structurally high in the forearc basin, overlain by a thick sedimentary sequence. The subducted and accreted sedimentary packages are separated by the decollement. Topography of the oceanic basement is rough, both in the basin and beneath the wedge. The accretionary prism along the North Sulawesi Trench grew because of the collision between eastern Sulawesi and the Bangai–Sula microcontinent along the Sorong Fault in the middle Miocene. This collision produced a large rotation of the north arm of Sulawesi Island. Rotation and northward movement of the north arm of Sulawesi may have resulted in southward subduction and development of the accretionary wedge along North Sulawesi. Lateral variations are wider in the western areas relative to the eastern areas. This is due to greater convergence rates in the western area: 5 km/My for the west and 1.5 km/My for the east. An accretionary prism model indicates that the initiation of growth of the accretionary prism in the North Sulawesi Trench occurred approximately 5 Ma. A comparison between the North Sulawesi accretionary prism and the Nankai accretionary prism of Japan reveals similar internal structures, suggesting similar mechanical processes and structural evolution.     

Primary and diagenetic isotopic signals in fossils and hemipelagic carbonates: the Lower Jurassic of northern Spain

Stable isotope and trace element analyses of 230 Jurassic (Pliensbachian–Toarcian) samples from northern Spain have been performed to test the use of geochemical variations in fossils (belemnites and brachiopods) and whole‐rock hemipelagic carbonates as palaeoceanographic indicators. Although the succession analysed (Reinosa area, westernmost Basque–Cantabrian Basin) has been subject to severe thermal alteration during burial diagenesis, the samples appear to be well preserved. The degree of diagenetic alteration of the samples has been assessed through the application of integrated petrographic, chemical and cathodoluminescence analyses. It is demonstrated that brachiopods and whole‐rock carbonates, although widely used for palaeoceanic studies, do not retain their primary marine geochemical composition after burial diagenesis. In contrast, there is strong evidence that belemnite rostra preserve original isotopic values despite pervasive diagenesis of the host rock. Well‐preserved belemnite shells (non‐luminescent to slightly luminescent) typically show stable isotope values of +4·3‰ to –0·7‰δ¹³C, +0·7‰ to –3·2‰δ¹⁸O, and trace element contents of <32 μg g^–1 Mn, <250 μg g^–1 Fe, >950 μg g^–1 Sr and Sr/Mn ratios >80. This study suggests that the degree to which diagenesis has affected the preservation of an original isotopic composition may differ for different low‐Mg calcite fossil shells and hemipelagic bulk carbonates, behaviour that should be considered when marine isotopic signatures from other ancient carbonate rocks are investigated. Multiple non‐luminescent contemporaneous belemnite samples passed the petrographic and geochemical tests to be considered as palaeoceanic recorders, yet their δ¹³C and δ¹⁸O values exhibited moderate scatter. Such variability is likely to be related to the palaeoecological behaviour of belemnites and/or high‐frequency secular variations in sea‐water chemistry superimposed on the long‐term isotopic trend. A pronounced positive carbon‐isotope excursion (up to +4·3‰) is documented in the early Toarcian serpentinus biozone, which correlates with the Toarcian δ¹³C maximum reported in other European and Tethyan regions.     

Classification of the Sibumasu and Paleo-Tethys tectonic division in Thailand using chert lithofacies

Two types of chert are defined in Thailand based on lithology, faunal content, and stratigraphy. 'Pelagic chert' consists of densely packed radiolarian tests in a microcrystalline quartz matrix with no terrigenous material and is found as blocks embedded within sheared matrix. 'Hemipelagic chert' also has a microcrystalline quartz matrix, and contains not only scattered radiolarian tests, but also calcareous organisms such as foraminifers. The pelagic cherts range in age from Devonian to Middle Triassic, whereas hemipelagic chert is only from the Early to the Late Triassic. Lithological and stratigraphic characteristics indicate that the pelagic chert originated in the Paleo-Tethys, whereas the hemipelagic chert accumulated on the eastern margin of the Sibumasu Block. The hemipelagic and pelagic chert are exposed in two north-trending belt-like zones. The western zone includes the hemipelagic chert, as well as glaciomarine and other Paleozoic to Mesozoic successions, overlying a Precambrian basement that consists exclusively of Sibumasu elements. The eastern zone contains pelagic chert and limestone and should be correlated to the Inthanon Zone. The Inthanon Zone is characterized by the presence not only of Paleo-Tethyan sedimentary rocks, but also of Sibumasu Block elements that structurally underlie the Paleo-Tethyan rocks. The boundary between the Sibumasu and Paleo-Tethys zones is a north-trending, low-angle thrust that resulted from the collision of the Sibumasu and Indochina blocks.