Determination of Cu,Fe, and Ni in Spices after Preconcentration on Diaion‐HP 20 Resin as Their Zincon Complexes

In this work, a new separation–preconcentration method was developed for the determination of trace amounts of Cu(II), Ni(II), and Fe(III) by flame atomic absorption spectrometry (FAAS). Analytes were complexed by using zincon (2‐[2‐[alpha(2‐hydroxy‐5‐sulfophenylazo) benzylidene] hydrazino] benzoic acid sodium salt). The analyte ions were quantitatively adsorbed on a Diaion HP‐20 resin at pH 5. The retained metal ions on the resin were eluted by acetone. The analytical parameters such as pH of the sample, eluent type and volume, sample volume, and flow rates of the solution and the eluent were investigated. The influences of concomitant ions on the recoveries of the analytes were also examined. The instrumental detection limits for the analytes after application of the presented solid‐phase extraction procedure were in the range of 0.72–1.41 µg/L. The validation of the presented procedure was checked by analyzing certified reference material of SRM1515 Apple Leaves. The procedure was performed by analyzing some spice samples.     

青海大黑山钨矿黑云二长花岗岩的锆石U-Pb同位素定年及岩石地球化学特征

大黑山钨矿位于祁连山加里东造山带,其形成与宝库河黑云二长花岗岩密切相关。黑云二长花岗岩锆石LA-ICPMS U-Pb测年结果显示其形成年龄为:450.2±2.8Ma,为加里东期岩浆活动的产物。地球化学数据显示,宝库河黑云二长花岗岩富硅(SiO2含量为73.03%～74.18%)、富钾(K2O/Na2O为1.13～1.94,K2O+Na2O含量为7.25%～8.51%)、铝过饱和(A/CNK为1.04～1.12),为过铝质钙碱性-高钾钙碱性花岗岩。P2O5含量低(0.03%～0.08%),且具有随SiO2含量的增长呈现负增长的趋势。稀土含量低,Eu明显负异常,LREE分异强烈,HREE分异不明显。微量元素蛛网图中Th、U、Pb、Zr、Hf呈现明显的正异常,Ba、Sr、Ta、Nb、P、Ti呈现负异常,为I型花岗岩。结合对区域动力地质背景的分析,表明宝库河黑云二长花岗岩形成于活动大陆边缘,由地壳物质熔融并结晶形成。