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1.
R. PALMERI M. L. FREZZOTTI G. GODARD R. J. DAVIES 《Journal of Metamorphic Geology》2009,27(9):685-705
Monocrystalline quartz inclusions in garnet and omphacite from various eclogite samples from the Lanterman Range (Northern Victoria Land, Antarctica) have been investigated by cathodoluminescence (CL), Raman spectroscopy and imaging, and in situ X‐ray (XR) microdiffraction using the synchrotron. A few inclusions, with a clear‐to‐opalescent lustre, show ‘anomalous’ Raman spectra characterized by weak α‐quartz modes, the broadening of the main α‐quartz peak at 465 cm?1, and additional vibrations at 480–485, 520–523 and 608 cm?1. CL and Raman imaging indicate that this ‘anomalous’α‐quartz occurs as relicts within ordinary α‐quartz, and that it was preserved in the internal parts of small quartz inclusions. XR diffraction circular patterns display irregular and broad α‐quartz spots, some of which show an anomalous d‐spacing tightening of ~2%. They also show some very weak, hazy clouds that have d‐spacing compatible with coesite but not with α‐quartz. Raman spectrometry and XR microdiffraction characterize the anomalies with respect to α‐quartz as (i) a pressure‐induced disordering and incipient amorphization, mainly revealed by the 480–485 and 608‐cm?1 Raman bands, together with (ii) a lattice densification, evidenced by d‐spacing tightening; (iii) the cryptic development of coesite, 520–523 cm?1 being the main Raman peak of coesite and (iv) Brazil micro‐twinning. This ‘anomalous’α‐quartz represents the first example of pressure‐induced incipient amorphization of a metastable phase in a crustal rock. This issue is really surprising because pressure‐induced amorphization of metastable α‐quartz, observed in impactites and known to occur between 15 and 32 GPa during ultrahigh‐pressure (UHP) experiments at room temperature, is in principle irrelevant under normal geological P–T conditions. A shock (due to a seism?) or a local overpressure at the inclusion scale (due to expansion mismatch between quartz and its host mineral) seem the only geological mechanisms that can produce such incipient amorphization in crustal rocks. This discovery throws new light on the modality of the quartz‐coesite transition and on the pressure regimes (non‐lithostatic v. lithostatic) during high‐pressure/UHP metamorphism. In particular, incipient amorphization of quartz could favour the quartz‐coesite transition, or allow the growth of metastable coesite, as already experimentally observed. 相似文献
2.
P. A. M. Van Hoof M. E. Foord R. F. Heeter J. E. Bailey H.-K. Chung M. E. Cuneo W. H. Goldstein V. Jonauskas F. P. Keenan R. Kisielius D. A. Liedahl C. Ramsbottom S. J. Rose P. T. Springer R. S. Thoe 《Astrophysics and Space Science》2005,298(1-2):147-153
In experiments at the high-power Z-facility at Sandia National Laboratory in Albuquerque, New Mexico, we have been able to
produce a low density photoionized laboratory plasma of Fe mixed with NaF. The conditions in the experiment allow a meaningful
comparison with X-ray emission from astrophysical sources. The charge state distributions of Fe, Na and F are determined in
this plasma using high resolution X-ray spectroscopy. Independent measurements of the density and radiation flux indicate
unprecedented values for the ionization parameter ξ = 20–25 erg cm s−1 under nearly steady-state conditions. First comparisons of the measured charge state distributions with X-ray photoionization
models show reasonable agreement, although many questions remain. 相似文献
3.
4.
M. G. Revnivtsev 《Astronomy Letters》2003,29(6):383-386
Analysis of the RXTE slew data in October 1996 revealed a weak X-ray burst from the millisecond pulsar SAX J 1808.4-3658. The 3–20-keV energy spectrum of the source can be described by a power law with an index of 2.0 and a(3-to 20 keV) luminosity of ~1.4×1035 erg s?1 (the distance to the source was taken to be 2.5 kpc). Because of the short exposure time, we failed to detect weak pulsations at a frequency of 401 Hz in the source. The (2σ) upper limit of the pulse fraction is ~13%. 相似文献
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6.
David M. Hirsch 《Contributions to Mineralogy and Petrology》2008,155(4):401-415
Garnet-bearing schists from the Waterville Formation of south-central Maine provide an opportunity to examine the factors
governing porphyroblast size over a range of metamorphic grade. Three-dimensional sizes and locations for all garnet porphyroblasts
were determined for three samples along the metamorphic field gradient spanning lowest garnet through sillimanite grade, using
high-resolution X-ray computed tomography. Comparison of crystal size distributions to previous data sets obtained by stereological
methods for the same samples reveals significant differences in mode, mean, and shape of the distributions. Quantitative textural
analysis shows that the garnets in each rock crystallized in a diffusion-controlled nucleation and growth regime. In contrast
to the typical observation of a correlation between porphyroblast size and position along a metamorphic field gradient, porphyroblast
size of the lowest-grade specimen is intermediate between the high- and middle-grade specimens’ sizes. Mean porphyroblast
size does not correlate with peak temperatures from garnet-biotite Fe-Mg exchange thermometry, nor is post-crystallization
annealing (Ostwald Ripening) required to produce the observed textures, as was previously proposed for these rocks. Robust
pseudosection calculations fail to reproduce the observed garnet core compositions for two specimens, suggesting that these
calc-pelites experienced metasomatism. For each of these two specimens, Monte Carlo calculations suggest potential pre-metasomatism
bulk compositions that replicate garnet core compositions. Pseudosection analyses allow the estimation of the critical temperatures
for garnet growth: ∼481, ∼477, and ∼485°C for the lowest-garnet-zone, middle-garnet-zone, and sillimanite-zone specimens,
respectively. Porphyroblast size appears to be determined in this case by a combination of the heating rate during garnet
crystallization, the critical temperature for the garnet-forming reaction and the kinetics of nucleation. Numerical simulations
of thermally accelerated, diffusion-controlled nucleation, and growth for the three samples closely match measured crystal
size distributions. These observations and simulations suggest that previous hypotheses linking the garnet size primarily
to the temperature at the onset of porphyroblast nucleation can only partially explain the observed textures. Also important
in determining porphyroblast size are the heating rate and the distribution of favorable nucleation sites. 相似文献
7.
In situ strength measurements on natural upper-mantle minerals 总被引:1,自引:0,他引:1
Junji Yamamoto Jun-ichi Ando Hiroyuki Kagi Toru Inoue Akihiro Yamada Daisuke Yamazaki Tetsuo Irifune 《Physics and Chemistry of Minerals》2008,35(5):249-257
Using in situ strength measurements at pressures up to 10 GPa and at room temperature, 400, 600, and 700°C, we examined rheological
properties of olivine, orthopyroxene, and chromian-spinel contained in a mantle-derived xenolith. Mineral strengths were estimated
using widths of X-ray diffraction peaks as a function of pressure, temperature, and time. Differential stresses of all minerals
increase with increasing pressure, but they decrease with increasing temperature because of elastic strain on compression
and stress relaxation during heating. During compression at room temperature, all minerals deform plastically at differential
stress of 4–6 GPa. During subsequent heating, thermally induced yielding is observed in olivine at 600°C. Neither orthopyroxene
nor spinel shows complete stress relaxation, but both retain some stress even at 700°C. The strength of the minerals decreases
in the order of chromian-spinel ≈ orthopyroxene > olivine for these conditions. This order of strength is consistent with
the residual pressure of fluid inclusions in mantle xenoliths. 相似文献
8.
Crustal structure of the Eastern Alps along the TRANSALP profile from wide-angle seismic tomography 总被引:1,自引:1,他引:1
The objective of the TRANSALP project is an investigation of the Eastern Alps with regard to their deep structure and dynamic evolution. The core of the project is a 340-km-long seismic profile at 12°E between Munich and Venice. This paper deals with the P-wave velocity distribution as derived from active source travel time tomography. Our database consists of Vibroseis and explosion seismic travel times recorded at up to 100 seismological stations distributed in a 30-km-wide corridor along the profile. In order to derive a velocity and reflector model, we simultaneously inverted refractions and reflections using a derivative of a damped least squares approach for local earthquake tomography. 8000 travel time picks from dense Vibroseis recordings provide the basis for high resolution in the upper crust. Explosion seismic wide-angle reflection travel times constrain both deeper crustal velocities and structure of the crust–mantle boundary with low resolution. In the resulting model, the Adriatic crust shows significantly higher P-wave velocities than the European crust. The European Moho is dipping south at an angle of 7°. The Adriatic Moho dips north with a gentle inclination at shallower depths. This geometry suggests S-directed subduction. Azimuthal variations of the first-break velocities as well as observations of shear wave splitting reveal strong anisotropy in the Tauern Window. We explain this finding by foliations and laminations generated by lateral extrusion. Based on the P-wave model we also localized almost 100 local earthquakes recorded during the 2-month acquisition campaign in 1999. Seismicity patterns in the North seem related to the Inn valley shear zone, and to thrusting of Austroalpine units over European basement. The alignment of deep seismicity in the Trento-Vicenza region with the top of the Adriatic lower crust corroborates the suggestion of a deep thrust fault in the Southern Alps. 相似文献
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