Asymmetrically zoned reaction rims: assessment of grain boundary diffusivities and growth rates related to natural diffusion-controlled mineral reactions

This study explores garnet coronas around hedenbergite, which were formed by the reaction plagioclase + hedenbergite→garnet + quartz, to derive information about diffusion paths that allowed for material redistribution during reaction progress. Whereas quartz forms disconnected single grains along the garnet/hedenbergite boundaries, garnet forms ～20‐μm‐wide continuous polycrystalline rims along former plagioclase/hedenbergite phase boundaries. Individual garnet crystals are separated by low‐angle grain boundaries, which commonly form a direct link between the reaction interfaces of the plagioclase|garnet|hedenbergite succession. Compositional variations in garnet involve: (i) an overall asymmetric compositional zoning in Ca, Fe²⁺, Fe³⁺ and Al across the garnet layer; and (ii) micron‐scale compositional variations in the near‐grain boundary regions and along plagioclase/garnet phase boundaries. These compositional variations formed during garnet rim growth. Thereby, transfer of the chemical components occurred by a combination of fast‐path diffusion along grain boundaries within the garnet rim, slow diffusion through the interior of the garnet grains, and by fast diffusion along the garnet/plagioclase and the garnet/hedenbergite phase boundaries. Numerical simulation indicates that diffusion of Ca, Al and Fe²⁺ occurred about three to four, four and six to seven orders of magnitude faster along the grain boundaries than through the interior of the garnet grains. Fast‐path diffusion along grain boundaries contributed substantially to the bulk material transfer across the growing garnet rim. Despite the contribution of fast‐path diffusion, bulk diffusion through the garnet rim was too slow to allow for chemical equilibration of the phases involved in garnet rim formation even on a micrometre scale. Based on published garnet volume diffusion data the growth interval of a 20‐μm‐wide garnet rim is estimated at ～10³–10⁴ years at the inferred reaction conditions of 760 ± 50 °C at 7.6 kbar. Using the same parameterization of the growth law, 100‐μm‐ and 1‐mm‐thick garnet rims would grow within 10⁵–10⁶ and 10⁶–10⁷ years respectively.     

罗氏沼虾育苗用水中Mg2+与Ca2+含量及Mg2+/Ca2+对出苗率的影响

１９９１年３－６月和１９９２年３－６月在南汇县东海水产养殖公司对罗氏沼虾育苗用水调配原则与不同基础水的调配方法进行试验研究。结果表明，育苗用水中Ｍｇ＾２＋与Ｃａ＾２＋含量及Ｍｇ＾２＋／Ｃａ＾２＋必须达到一定的范围，这是调配的基本原则。以鱼塘水作基础水时，需添加６种化学药品，其中Ｍｇ＾２＋与Ｃａ＾２＋含量可适范围分别为３００．０－４４０．０ｍｇ／Ｌ与１７０．０－２４４．０ｍｇ／Ｌ，Ｍｇ＾２＋／Ｃａ＾     

Evaluation of toxicity in tributaries of the Mersey estuary using the isopod Asellus aquaticus (L.)

Increasing numbers of industrial, agricultural and natural chemicals are present in sewage effluent and are known to elicit toxic effects in laboratory exposures, but little is known of their combined sub-lethal effect in the field. In this study, a combination of esterase activity and ventilation rate assays was performed to determine the neurological and physiological function of the freshwater crustacean Asellus aquaticus (L.) at sites above and below a sewage treatment works (STW). Cholinesterase and carboxylesterase activities were significantly inhibited (n=8, P<0.05) and ventilation rates increased (n=8, P=0.0001) in A. aquaticus at STW sites compared to those from reference sites, indicating a decrease in neurological and physiological function. The ecological relevance of these findings for the population dynamics of the organisms in the field is discussed.     

Growth of the Mediterranean Gorgonian Lophogorgia ceratophyta (L., 1758)

Abstract. Growth of the shallow-water gorgonian Lophogorgia ceratophyta was investigated in an infralittoral station located in La Spezia Gulf, Ligurian Sea. Mean annual height growth rate was estimated to be 2.57 cm · a^-1. The fractal dimension of the colonies was found to gradually evolve in complexity, exhibiting a simpler branching pattern in younger specimens. The maintenance of a low, invariable ramification complexity as an optimal choice in managing relationships between water and the colony's living tissues is also discussed.     

Seismic potential of Southern Italy

To improve estimates of the long-term average seismic potential of the slowly straining South Central Mediterranean plate boundary zone, we integrate constraints on tectonic style and deformation rates from geodetic and geologic data with the traditional constraints from seismicity catalogs. We express seismic potential (long-term average earthquake recurrence rates as a function of magnitude) in the form of truncated Gutenberg–Richter distributions for seven seismotectonic source zones. Seismic coupling seems to be large or even complete in most zones. An exception is the southern Tyrrhenian thrust zone, where most of the African–European convergence is accommodated. Here aseismic deformation is estimated to range from at least 25% along the western part to almost 100% aseismic slip around the Aeolian Islands. Even so, seismic potential of this zone has previously been significantly underestimated, due to the low levels of recorded past seismicity. By contrast, the series of 19 M6–7 earthquakes that hit Calabria in the 18th and 19th century released tectonic strain rates accumulated over time spans up to several times the catalog duration, and seismic potential is revised downward. The southern Tyrrhenian thrust zone and the extensional Calabrian faults, as well as the northeastern Sicilian transtensional zone between them (which includes the Messina Straits, where a destructive M7 event occurred in 1908), all have a similar seismic potential with minimum recurrence times of M ≥ 6.5 of 150–220 years. This potential is lower than that of the Southern Apennines (M ≥ 6.5 recurring every 60 to 140 years), but higher than that of southeastern Sicily (minimum M ≥ 6.5 recurrence times of 400 years). The high seismicity levels recorded in southeastern Sicily indicate some clustering and are most compatible with a tectonic scenario where the Ionian deforms internally, and motions at the Calabrian Trench are small. The estimated seismic potential for the Calabrian Trench and Central and Western Sicily are the lowest (minimum M ≥ 6.5 recurrence times of 550–800 years). Most zones are probably capable of generating earthquakes up to magnitudes 7–7.5, with the exception of Central and Western Sicily where maximum events sizes most likely do not exceed 7.     

Geochronology of Middle and Upper Pleistocene Loess Sections in Hungary

The application of both thermoluminescence and infrared stimulated luminescence dating to the extensively studied “classical” Hungarian loess/paleosol sequences from Basaharc, Mende, and Paks provides a reliable chronological framework and climatostratigraphic reconstruction for the last interglacial/glacial cycle. Based on this combined luminescence dating study a new chronology is proposed for the “Young Loess” in Hungary. Luminescence dating suggests that the loess below the MF2 horizon formed during the penultimate glaciation. The MF1 horizon probably formed during an interstade within oxygen isotope stage 3. For the youngest loess, overlying MF1, a very high accumulation rate was determined. Large time gaps occur above MF2 and MF1, indicating that most of the record of the last glaciation is missing in the standard sections at Basaharc, Mende, and Paks. Either large discontinuities or a very low accumulation rate occurred in all three type sections during the soil-forming periods. High-resolution studies of climatic proxies using this combined luminescence dating approach provide a reliable chronological framework for loess and loess derivatives of the last glacial cycle in Hungary, although a precise and complete chronostratigraphic reconstruction cannot be achieved from the incomplete records found at these sites.     

Erosion rates of alpine bedrock summit surfaces deduced from in situ Be and Al

We have measured the concentration of in situ produced cosmogenic ¹⁰Be and ²⁶Al from bare bedrock surfaces on summit flats in four western U.S. mountain ranges. The maximum mean bare-bedrock erosion rate from these alpine environments is 7.6 ± 3.9 m My⁻¹. Individual measurements vary between 2 and 19 m My⁻¹. These erosion rates are similar to previous cosmogenic radionuclide (CRN) erosion rates measured in other environments, except for those from extremely arid regions. This indicates that bare bedrock is not weathered into transportable material more rapidly in alpine environments than in other environments, even though frost weathering should be intense in these areas. Our CRN-deduced point measurements of bedrock erosion are slower than typical basin-averaged denudation rates ( 50 m My⁻¹). If our measured CRN erosion rates are accurate indicators of the rate at which summit flats are lowered by erosion, then relief in the mountain ranges examined here is probably increasing.

We develop a model of outcrop erosion to investigate the magnitude of errors associated with applying the steady-state erosion model to episodically eroding outcrops. Our simulations show that interpreting measurements with the steady-state erosion model can yield erosion rates which are either greater or less than the actual long-term mean erosion rate. While errors resulting from episodic erosion are potentially greater than both measurement and production rate errors for single samples, the mean value of many steady-state erosion rate measurements provides a much better estimate of the long-term erosion rate.     

Erratic judgements: re-evaluating solutional erosion rates of limestones using erratic-pedestal sites, including Norber, Yorkshire

The re-interpretation of surface karst landforms in Northern England has led to a re-examination of well-known erratic-pedestal sites that were the origin for karst denudation rates applied extensively, on the supposition that erratics protect underlying limestone from rainwater solution. Height of the pedestal has been used to calculate long-term solutional-lowering, as much as 50 cm in 15 ka (33.3 mm/ka) from UK sites. The sites include Norber and Scar Close, Yorkshire, UK. This paper shows that the sites have been misinterpreted, in particular at Norber where the erratics lie on a pre-existing structurally stepped surface. Norber and several other sites also experience much mechanical weathering, in relatively weak, well-fractured limestones, a process which must be distinguished from solution. Sites in strong, less-fractured limestones demonstrate lower rates, which are sounder indications of land surface lowering. Some pedestals have been confirmed as partly resulting from solutional weathering in surrounding soil and vegetation. Re-evaluation reduces solution rates to 3–13 cm in 15 ka. Applying such rates has profound implications for understanding limestone landscapes, challenging orthodox views.     

Geospatial analysis of a coastal sand dune field evolution: Jockey's Ridge, North Carolina

Preservation and effective management of highly dynamic coastal features located in areas under development pressures requires in-depth understanding of their evolution. Modern geospatial technologies such as lidar, real time kinematic GPS, and three-dimensional GIS provide tools for efficient acquisition of high resolution data, geospatial analysis, feature extraction, and quantification of change. These techniques were applied to the Jockey's Ridge, North Carolina, the largest active dune field on the east coast of the United States, with the goal to quantify its deflation and rapid horizontal migration. Digitized contours, photogrammetric, lidar and GPS point data were used to compute a multitemporal elevation model of the dune field capturing its evolution for the period of 1974– 2004. In addition, peak elevation data were available for 1915 and 1953. Analysis revealed possible rapid growth of the dune complex between 1915–1953, followed by a slower rate of deflation that continues today. The main dune peak grew from 20.1 m in 1915 to 41.8 m in 1953 and has since eroded to 21.9 m in 2004. Two of the smaller peaks within the dune complex have recently gained elevation, approaching the current height of the main dune. Steady annual rate of main peak elevation loss since 1953 suggests that increase in the number of visitors after the park was established in 1974 had little effect on the rate of dune deflation. Horizontal dune migration of 3–6 m/yr in southerly direction has carried the sand out of the park boundaries and threatened several houses. As a result, the south dune section was removed and the sand was placed at the northern end of the park to serve as a potential source. Sand fencing has been an effective management strategy for both slowing the dune migration and forcing growth in dune elevation. Understanding the causes of the current movements can point to potential solutions and suggest new perspectives on management of the dune as a tourist attraction and as a recreation site, while preserving its unique geomorphic character and dynamic behavior.