Dynamic recrystallization near the brittle-plastic transition in naturally and experimentally deformed quartz aggregates

The electron backscattering diffraction technique (EBSD) was used to analyze bulging recrystallization microstructures from naturally and experimentally deformed quartz aggregates, both of which are characterized by porphyroclasts with finely serrated grain boundaries and grain boundary bulges set in a matrix of very fine recrystallized grains. For the Tonale mylonites we investigated, a temperature range of 300–380 °C, 0.25 GPa confining pressure, a flow stress range of ~ 0.1–0.2 GPa, and a strain rate of ~ 10^− 13 s^− 1 were estimated. Experimental samples of Black Hills quartzite were analyzed, which had been deformed in axial compression at 700 °C, 1.2–1.5 GPa confining pressure, a flow stress of ~ 0.3–0.4 GPa, a strain rate of ~ 10^− 6 s^− 1, and to 44% to 73% axial shortening. Using orientation imaging we investigated the dynamic recrystallization microstructures and discuss which processes may contribute to their development. Our results suggest that several deformation processes are important for the dismantling of the porphyroclasts and the formation of recrystallized grains. Grain boundary bulges are not only formed by local grain boundary migration, but they also display a lattice misorientation indicative of subgrain rotation. Dynamic recrystallization affects especially the rims of host porphyroclasts with a hard orientation, i.e. with an orientation unsuitable for easy basal slip. In addition, Dauphiné twins within porphyroclasts are preferred sites for recrystallization. We interpret large misorientation angles in the experimental samples, which increase with increasing strain, as formed by the activity of fluid-assisted grain boundary sliding.     

The development of subgrain misorientations with strain in dry synthetic NaCl measured using EBSD

The development of subgrain boundary misorientations with strain in dry, synthetic NaCl polycrystals, deformed at elevated temperature, has been investigated using electron backscattered diffraction (EBSD). At low natural strains, up to 0.5, average misorientations of subgrain boundaries increase with strain and a power law relationship exists between strain and average misorientations. The average misorientations are strongly influenced by grain orientation, suggesting that the misorientation–strain relationship may also be texture dependent in materials with high plastic anisotropy, like NaCl. A slight grain size dependency of the average misorientations was observed. The results indicate that with suitable calibration, average subgrain boundary misorientations may offer a method for estimating the strain accommodated by dislocation creep in NaCl and thus perhaps in other geological materials, although current theories for polycrystalline plasticity imply that misorientations may also depend on stress in some situations.     

The role of subgrain boundaries in partial melting

Evidence for partial melting along subgrain boundaries in quartz and plagioclase is documented for rocks from the Lost Creek Gneiss of the Llano Uplift, central Texas, the Wet Mountains of central Colorado, and the Albany-Fraser Orogen, southwestern Australia. Domains of quartz or plagioclase crystals along subgrain boundaries are preferentially involved in partial melting over unstrained domains of these minerals. Material along subgrain boundaries in quartz and plagioclase has the same morphology as melt pseudomorphs present along grain boundaries and is commonly laterally continuous with this former grain boundary melt, indicating the material along subgrain boundaries can also be categorized as a melt pseudomorph. Subgrain boundaries consist of arrays of dislocations within a crystal lattice, and unlike fractures would not act as conduits for melt migration. Instead, the presence of former melt along subgrain boundaries requires that partial melting occurred in these locations because it is kinetically more favorable for melting reactions to occur there. Preferential melting in high strain locations may be attributed to strain energy, which provides a minor energetic contribution to the reaction and leads to preferential melting in locations with weakened bonds, and/or the presence of small quantities of water associated with dislocations, which may enhance diffusion rates or locally lower the temperature needed for partial melting.     

Theory and applicability of a recrystallized grain size paleopiezometer

An approximate theoretical relation is derived which relates stress during steady state creep to both subgrain size and dynamically recrystallized grain size. The relation results from equating the dislocation strain energy in the grain boundary to that in the enclosed volume. Available data on metals and silicates are in excellent agreement with the theory. For paleopiezometry, the recrystallized grain size must be preserved by quenching, by cooling under stress, or by inhibition of grain growth by intimate mixture of two or more phases. In general, stress may be underestimated using rocks in which grain size has been reduced by dynamic recrystallization, especially if the grain size is very small. Stress may be overestimated using coarse grained rocks in which the grain size has increased toward the steady state value. Quantitative limits remain to be established. The theoretical relation can in principle be applied to any metal or mineral if only the effective isotropic elastic moduli and the Burgers vector are known. When used as a paleopiezometer, the technique indicates that high stresses on the order of 100 MPa are not infrequently associated with mantle diapirism and with large scale thrust faulting. Consideration of the Mt. Albert ultramafic body suggests that texturally inferred stresses from peridotite massifs and from ultramafic xenoliths in alkali olivine basalts might reflect either horizontal variations in stress across a rising diapir or else a vertical variation in stress as defined by the pyroxene geobarometer (Mercier et al. 1977). In either case the stresses are probably characteristic of local diapirism. Stresses characteristic of global upper mantle flow might be inferred from xenoliths originating from above kimberlite-producing diapirs.     

ESTIMATE OF DIFFERENTIAL FLOW STRESS AND STRAIN RATE FOR HONGHE FAULT ZONE

Microstructures of quartz in Honghe mylonite zone are studied and recent result of microstructural paleopiezometry is used in this paper to estimate the differential flow stress and strain rate for the southern Honghe fault zone. The calculations show that the differential flow stress during the development of mylonites of the southern Honghe fault zone varied gradually from 45MPa in the south to 120MPa in the north. Because the formation depth of mylonite zone became shallow from south to north, this variation indicates the decrease of flow stress with depth. The strain rate was roughly of the order of 10-12/se