Laboratory kinetics of C2H radical reactions with ethane, propane, and n-butane at T = 96-296 K: implications for Titan

The kinetics of the reactions of C₂H radical with ethane (k₁), propane (k₂), and n-butane (k₃) are studied over the temperature range of T = 96-296 K with a pulsed Laval nozzle apparatus that utilizes a pulsed laser photolysis-chemiluminescence technique. The C₂H decay profiles in the presence of both the alkane reactant and O₂ are monitored by the CH(A²Δ) chemiluminescence tracer method. The results, together with available literature data, yield the following Arrhenius expressions: k₁(T) = (0.51 ± 0.06) × 10⁻¹⁰ exp[(−76 ± 30)K/T] cm³ molecule⁻¹ s⁻¹ (T = 96-800 K), k₂(T) = (0.98 ± 0.32) × 10⁻¹⁰exp[(−71 ± 60)K/T] cm³ molecule⁻¹ s⁻¹ (T = 96-361 K), and k₃(T) = (1.23 ± 0.26) × 10⁻¹⁰ cm³ molecule⁻¹ s⁻¹ (T = 96-297 K). At T = 296 K, k₁ is measured as a function of total pressure and has little or no pressure dependence. The results from this work support a direct hydrogen abstraction mechanism for the title reactions. Implications to the atmospheric chemistry of Titan are discussed.     

Understanding the behavior of Prometheus and Pandora

We revisit the dynamics of Prometheus and Pandora, two small moons flanking Saturn's F ring. Departures of their orbits from freely precessing ellipses result from mutual interactions via their 121:118 mean motion resonance. Motions are chaotic because the resonance is split into four overlapping components. Orbital longitudes were observed to drift away from predictions based on Voyager ephemerides. A sudden jump in mean motions took place close to the time at which the orbits' apses were antialigned in 2000. Numerical integrations reproduce both the longitude drifts and the jumps. The latter have been attributed to the greater strength of interactions near apse antialignment (every 6.2 yr), and it has been assumed that this drift-jump behavior will continue indefinitely. We re-examine the dynamics of the Prometheus-Pandora system by analogy with that of a nearly adiabatic, parametric pendulum. In terms of this analogy, the current value of the action of the satellite system is close to its maximum in the chaotic zone. Consequently, at present, the two separatrix crossings per precessional cycle occur close to apse antialignment. In this state libration only occurs when the potential's amplitude is nearly maximal, and the “jumps” in mean motion arise during the short intervals of libration that separate long stretches of circulation. Because chaotic systems explore the entire region of phase space available to them, we expect that at other times the Prometheus-Pandora system would be found in states of medium or low action. In a low action state it would spend most of the time in libration, and separatrix crossings would occur near apse alignment. We predict that transitions between these different states can happen in as little as a decade. Therefore, it is incorrect to assume that sudden changes in the orbits only happen near apse antialignment.     

Origin of chaos in the Prometheus-Pandora system

We demonstrate that the chaotic orbits of Prometheus and Pandora are due to interactions associated with the 121:118 mean motion resonance. Differential precession splits this resonance into a quartet of components equally spaced in frequency. Libration widths of the individual components exceed the splitting, resulting in resonance overlap which causes the chaos. Mean motions of Prometheus and Pandora wander chaotically in zones of width 1.8 and 3.1 deg yr⁻¹, respectively. A model with 1.5 degrees of freedom captures the essential features of the chaotic dynamics. We use it to show that the Lyapunov exponent of 0.3 yr⁻¹ arises because the critical argument of the dominant member of the resonant quartet makes approximately two separatrix crossings every 6.2 year precessional cycle.     

Microwave observations of Saturn's rings: anisotropy in directly transmitted and scattered saturnian thermal emission

We present a new Very Large Array (VLA) image of Saturn, made from data taken in October 1998 at a wavelength of λ3.6 cm. The moderate ring opening angle (B≈15°) allows us to explore direct transmission of microwave photons through the A and C rings. We find a strong asymmetry of photons transmitted through the A ring, but not in the C ring, a new diagnostic of wake structure in the ring particles. We also find a weak asymmetry between east and west for the far side of the ansae. To facilitate quantitative comparison between dynamic models of the A ring and radio observations, we extend our Monte Carlo radiative transfer code (described in Dunn et al., 2002, Icarus 160, 132-160) to include idealized wakes. We show the idealized model can reproduce the properties of dynamic simulations in directly transmitted light. We examine the model behavior in directly transmitted and scattered light over a range of physical and geometric wake parameters. Finally, we present a wake model with a plausible set of physical parameters that quantitatively reproduces the observed intensity and asymmetry of the A ring both across the planet and in the ansae.     

No Hexagonal Wave around Saturn's Southern Pole

Hubble Space Telescope (HST) images (1997-2002) do not show a hexagonal wave in the south pole that is a counterpart of the northern one (D. A. Godfrey 1988, Icarus76, 335-356). However, a polar jet similar to that in which the north polar hexagonal wave is embedded has been discovered in the southern hemisphere. The HST images also reveal the existence of a small polar “cap” about 2000 km in diameter that marks the rotational pole of the planet, as well as unexpected changes in the nearby cloud structure on a timescale of years.     

由土卫九(Phoebe)轨道数值改进求解土星质量

为测定土星质量,对收集到的1905年至2006年期间的686次观测[其中包括182次照相观测和504次CCD(电荷耦合器件)观测]通过数值积分进行拟合来改进土星的暗弱的外卫星Phoebe的轨道,并得到土星系总质量msa的新的测定值:3 497.0-1msun(太阳质量),为更精确地测定土星质量提供了一个有价值的参考值。     

A deeper look at the colors of the saturnian irregular satellites

We have performed broadband color photometry of the twelve brightest irregular satellites of Saturn with the goal of understanding their surface composition, as well as their physical relationship. We find that the satellites have a wide variety of different surface colors, from the negative spectral slopes of the two retrograde satellites S IX Phoebe (S^′=−2.5±0.4) and S XXV Mundilfari (S^′=−5.0±1.9) to the fairly red slope of S XXII Ijiraq (S^′=19.5±0.9). We further find that there exist a correlation between dynamical families and spectral slope, with the prograde clusters, the Gallic and Inuit, showing tight clustering in colors among most of their members. The retrograde objects are dynamically and physically more dispersed, but some internal structure is apparent.     

Hydrocarbon lakes on Titan

The Huygens Probe detected dendritic drainage-like features, methane clouds and a high surface relative humidity (∼50%) on Titan in the vicinity of its landing site [Tomasko, M.G., and 39 colleagues, 2005. Nature 438, 765-778; Niemann, H.B., and 17 colleagues, 2005. Nature 438, 779-784], suggesting sources of methane that replenish this gas against photo- and charged-particle chemical loss on short (10-100) million year timescales [Atreya, S.K., Adams, E.Y., Niemann, H.B., Demick-Montelara, J.E., Owen, T.C., Fulchignoni, M., Ferri, F., Wilson, E.H., 2006. Planet. Space Sci. In press]. On the other hand, Cassini Orbiter remote sensing shows dry and even desert-like landscapes with dunes [Lorenz, R.D., and 39 colleagues, 2006a. Science 312, 724-727], some areas worked by fluvial erosion, but no large-scale bodies of liquid [Elachi, C., and 34 colleagues, 2005. Science 308, 970-974]. Either the atmospheric methane relative humidity is declining in a steady fashion over time, or the sources that maintain the relative humidity are geographically restricted, small, or hidden within the crust itself. In this paper we explore the hypothesis that the present-day methane relative humidity is maintained entirely by lakes that cover a small part of the surface area of Titan. We calculate the required minimum surface area coverage of such lakes, assess the stabilizing influence of ethane, and the implications for moist convection in the atmosphere. We show that, under Titan's surface conditions, methane evaporates rapidly enough that shorelines of any existing lakes could potentially migrate by several hundred m to tens of km per year, rates that could be detected by the Cassini orbiter. We furthermore show that the high relative humidity of methane in Titan's lower atmosphere could be maintained by evaporation from lakes covering only 0.002-0.02 of the whole surface.     

Degree-one convection and the origin of Enceladus' dichotomy

Recently, the Cassini spacecraft has detected ongoing geologic activity near the south pole of Saturn's moon Enceladus. In contrast, the satellite's north-polar region is heavily cratered and appears to have been geologically inactive for a long time. We propose that this hemispheric dichotomy is caused by interior dynamics with degree-one convection driving the south-polar activity. We investigate a number of core sizes and internal heating rates for which degree-one convection occurs. The numerical simulations imply that a core radius of less than 100±20 km and an energy input at a rate of 3.0 to 5.5 GW would be required for degree-one convection to prevail. This is within the range of the observed thermal power release near Enceladus' south pole. Provided that Enceladus is not fully differentiated, degree-one convection is found to be a viable mechanism to explain Enceladus' hemispheric dichotomy.