Permeability development in vesiculating magmas: implications for fragmentation

 Fragmentation, or the "coming apart" of magma during a plinian eruption, remains one of the least understood processes in volcanology, although assumptions about the timing and mechanisms of fragmentation are key parameters in all existing eruption models. Despite evidence to the contrary, most models assume that fragmentation occurs at a critical vesicularity (volume percent vesicles) of 75–83%. We propose instead that the degree to which magma is fragmented is determined by factors controlling bubble coalescence: magma viscosity, temperature, bubble size distribution, bubble shapes, and time. Bubble coalescence in vesiculating magmas creates permeability which serves to connect the dispersed gas phase. When sufficiently developed, permeability allows subsequent exsolved and expanded gas to escape, thus preserving a sufficiently interconnected region of vesicular magma as a pumice clast, rather than fully fragmenting it to ash. For this reason pumice is likely to preserve information about (a) how permeability develops and (b) the critical permeability needed to insure clast preservation. We present measurements and calculations that constrain the conditions (vesicularity, bubble size distribution, time, pressure difference, viscosity) necessary for adequate permeability to develop. We suggest that magma fragments explosively to ash when and where, in a heterogeneously vesiculating magma, these conditions are not met. Both the development of permeability by bubble wall thinning and rupture and the loss of gas through a permeable network of bubbles require time, consistent with the observation that degree of fragmentation (i.e., amount of ash) increases with increasing eruption rate. Received: 5 July 1995 / Accepted: 27 December 1995     

The submarine eruption of the Bombarda volcano,Milos Island,Cyclades, Greece

The Milos volcanic field includes a well-exposed volcaniclastic succession which records a long history of submarine explosive volcanism. The Bombarda volcano, a rhyolitic monogenetic center, erupted ∼1.7 Ma at a depth <200 m below sea level. The aphyric products are represented by a volcaniclastic apron (up to 50 m thick) and a lava dome. The apron is composed of pale gray juvenile fragments and accessory lithic clasts ranging from ash to blocks. The juvenile clasts are highly vesicular to non-vesicular; the vesicles are dominantly tube vesicles. The volcaniclastic apron is made up of three fades: massive to normally graded pumice-lithic breccia, stratified pumice-lithic breccia, and laminated ash with pumice blocks. We interpret the apron beds to be the result of water-supported, volcaniclastic mass-How emplacement, derived directly from the collapse of a small-volume, subaqueous eruption column and from syn-eruptive, down-slope resedimentation of volcaniclastic debris. During this eruptive phase, the activity could have involved a complex combination of phreatomagmatic explosions and minor submarine effusion. The lava dome, emplaced later in the source area, is made up of flow-banded lava and separated from the apron by an obsidian carapace a few meters thick. The near-vertical orientation of the carapace suggests that the dome was intruded within the apron. Remobilization of pyroclastic debris could have been triggered by seismic activity and the lava dome emplacement. Published online: 30 January 2003 Editorial responsibility: J. McPhie     

Complex spatter- and pumice-rich pyroclastic deposits from an andesitic caldera-forming eruption: the Siwi pyroclastic sequence,Tanna, Vanuatu

The small- to moderate-volume, Quaternary, Siwi pyroclastic sequence was erupted during formation of a 4 km-wide caldera on the eastern margin of Tanna, an island arc volcano in southern Vanuatu. This high-potassium, andesitic eruption followed a period of effusive basaltic andesite volcanism and represents the most felsic magma erupted from the volcano. The sequence is up to 13 m thick and can be traced in near-continuous outcrop over 11 km. Facies grade laterally from lithic-rich, partly welded spatter agglomerate along the caldera rim to two medial, pumiceous, non-welded ignimbrites that are separated by a layer of lithic-rich, spatter agglomerate. Juvenile clasts comprise a wide range of densities and grain sizes. They vary between black, incipiently vesicular, highly elongate spatter clasts that have breadcrusted pumiceous rinds and reach several metres across to silky, grey pumice lapilli. The pumice lapilli range from highly vesicular clasts with tube or coalesced spherical vesicles to denser finely vesicular clasts that include lithic fragments.Textural and lithofacies characteristics of the Siwi pyroclastic sequence suggest that the first phase of the eruption produced a base surge deposit and spatter-poor pumiceous ignimbrite. A voluminous eruption of spatter and lithic pyroclasts coincided with a relatively deep withdrawal of magma presumably driven by a catastrophic collapse of the magma chamber roof. During this phase, spatter clasts rapidly accumulated in the proximal zone largely as fallout, creating a variably welded and lithic-rich agglomerate. This phase was followed by the eruption of moderately to highly vesiculated magma that generated the most widespread, upper pumiceous ignimbrite. The combination of spatter and pumice in pyroclastic deposits from a single eruption appears to be related to highly explosive, magmatic eruptions involving low-viscosity magmas. The combination also indicates the coexistence of a spatter fountain and explosive eruption plume for much of the eruption.Editorial responsibility: R. Cioni     

Role of conduit shear on ascent of the crystal-rich magma feeding the 800-year-<Emphasis Type="SmallCaps">b.p.</Emphasis> Plinian eruption of Quilotoa Volcano (Ecuador)

We have characterized pumice products belonging to the climactic phase of the 800-year-b.p. Quilotoa eruption. Bulk rock compositions, petrography, mineral, and glass chemistry and textural investigations were performed on the three end-member pumice types, namely white, gray, and mingled pumices. All the investigated pumice clasts are dacites characterized by the same bulk rock composition and mineralogical assemblage, but glass compositions and bulk textures change according to different pumice types. White pumice has higher crystallinity (~48 wt%), abundant euhedral pheno/microphenocrysts, no groundmass microlites, the most evolved glass compositions (74–78 wt% SiO₂), and heterogeneous vesicle populations marked by deformed and highly coalesced vesicles with thin walls. Gray pumice exhibits lower crystallinity (29–36 wt%), abundant broken and/or resorbed crystals, ubiquitous groundmass phenocryst fragments and microlites, the widest range of glass compositions (69–78 wt% SiO₂), and quite homogeneous poorly deformed and coalesced vesicles with thicker walls. Mingled pumices are characterized by the alternation of bands or patches with white and gray pumice compositional and textural characteristics. We attribute heterogeneities in glass compositions and crystal and vesicle textures to processes occurring within volcanic conduits as magma is ascending to the surface. In particular, the above observations and results are consistent with an origin of a gray magma by heating of the original white magma in a strongly sheared region of the conduit because of a mechanism of viscous dissipation and crystal grinding and resorption at the conduit walls. The less viscous gray magma, therefore, would enable the onset and preservation of a high mass flux of the eruption otherwise difficult to explain for highly viscous crystal-rich dacitic magmas.Editorial responsibility: D. Dingwell     

Experimental simulations of gas-driven eruptions: kinetics of bubble growth and effect of geometry

 Simulated gas-driven eruptions using CO₂–water-polymer systems are reported. Eruptions are initiated by rapidly decompressing CO₂–saturated water containing up to 1.0 wt.% CO₂. Both cylindrical test cells and a flask test cell were used to examine the effect of magma chamber/conduit geometry on eruption dynamics. Bubble-growth kinetics are examined quantitatively in experiments using cylindrical test cells. Uninhibited bubble growth can be roughly expressed as dr/dt≈λD(β-1)/(γt ^1/3) for a CO₂–water-polymer system at 0–22  °C and with viscosities up to 5 Pa·s, where r is the radius of bubbles, λ and D are the Ostwald solubility coefficient and diffusivity of the gas in the liquid, β is the degree of saturation (decompression ratio), and γ characterizes how the boundary layer thickness increases with time and is roughly 1.0×10^–5 m/s^1/3 in this system. Unlike the radius of cylindrical test cells, which does not affect the eruption threshold and dynamics, the shape of the test cells (flask vs cylindrical) affects the dynamics but not the threshold of eruptions. For cylindrical test cells, the front motion is characterized by constant acceleration with both Δh (the height increase) and ΔV (the volume increase) being proportional to t ²; for the flask test cell, however, neither Δh nor ΔV is proportional to t ² as the conduit radius varies. Test-cell geometry also affects foam stability. In the flask test cell, as it moves from the wider base chamber into the narrower conduit, the bubbly flow becomes fragmented, affecting the eruption dynamics. The fragmentation may be caused by a sudden increase in acceleration induced by conduit-shape change, or by the presence of obstacles to the bubbly flow. This result may help explain the range in vesicularities of pumice and reticulite. Received: 16 May 1997 / Accepted: 11 October 1997     

冲绳海槽浮岩的高温高压纵波速度

对采自冲绳海槽中部海底的浮岩样品和邻近陆地樱岛火山的安山岩样品进行了温度 (常温 - 15 0 0℃ )与压力 (常压 - 2 .4 GPa)实验 ,测得在较低温度 -压力条件下 (<1GPa,<80 0℃ )浮岩样品的纵波速度小于安山岩样品的纵波速度 ,在较高温度 -压力条件下 (>1GPa,>80 0℃ )二者的纵波速度接近一致 (5 .9km /s)。 1GPa/80 0℃是浮岩样品和安山岩样品的热动力相变点 ,推测该点的深度大于 18km。     

Removal of Selenium Species from Waters Using Various Surface‐Modified Natural Particles and Waste Materials

Waste red mud and natural pumice/volcanic slag particles were surface modified and their selenium adsorption from waters was investigated. Acid activation/heat treatment of original red mud (ORM) particles significantly increased their micropore and external surface area and cumulative volume of pores. Iron oxide coating of pumice/slags and acid activation of ORM decreased their pH_pzc values and increased surface acidity. Selenite/selenate adsorption on iron oxide surfaces and acid activated red mud (AARM) was very fast with approximately first‐order adsorption kinetics. Iron oxide coating of pumice/slag and acid activation of ORM particles significantly enhanced their selenite and selenate uptakes. Maximum Se adsorption capacities as high as 6.3 (mg Se/g adsorbent) were obtained by AARM. The extent of selenate uptakes by the surface modified particles was generally lower than those of selenite. Due to competition among Se species and other background water matrix for iron oxide adsorption sites, reduced selenite/selenate uptakes were found in natural water compared to single solute tests. Higher Se uptakes by iron oxide surfaces were found at pH 7.5 compared to pH 8.9, due to increased electrostatic repulsion among iron oxides and Se species at higher pH. The most effective adsorbents among the tested 17 different particles for Se uptake were AARM and iron oxide coated pumice. Se concentrations less than drinking water standards (5–10 µg/L) can be achieved by these particles. These low‐cost, natural, or recyclable waste particles appear to be promising adsorbents for Se removal after their surface modification.     

Kinetics of heterogeneous bubble nucleation in rhyolitic melts: implications for the number density of bubbles in volcanic conduits and for pumice textures

We performed decompression experiments to simulate the ascent of a phenocryst-bearing rhyolitic magma in a volcanic conduit. The starting materials were bubble-free rhyolites water-saturated at 200 MPa–800°C under oxidizing conditions: they contained 6.0 wt% dissolved H₂O and a dense population of hematite crystals (8.7 ± 2 × 10⁵ mm⁻³). Pressure was decreased from the saturation value to a final value ranging from 99 to 20 MPa, at constant temperature (800°C); the rate of decompression was either 1,000 or 27.8 kPa/s. In all experiments, we observed a single event of heterogeneous bubble nucleation beginning at a pressure P _N equal to 63 ± 3 MPa in the 1,000 kPa/s series, and to 69 ± 1 MPa in the 27.8 kPa/s series. Below P _N, the degree of water supersaturation in the liquid rapidly decreased to a few 0.1 wt%, the nucleation rate dropped, and the bubble number density (BND) stabilized to a value strongly sensitive to decompression rate: 80 mm⁻³ at 27.8 kPa/s vs. 5,900 mm⁻³ at 1,000 kPa/s. This behaviour is like the behavior formerly described in the case of homogeneous bubble nucleation in the rhyolite-H₂O system and in numerical simulations of vesiculation in ascending magmas. Similar degrees of water supersaturation were measured at 27.8 and 1,000 kPa/s, implying that a faster decompression rate does not result in a larger departure from equilibrium. Our experimental results imply that BNDs in acid to intermediate magmas ascending in volcanic conduits will depend on both the decompression rate and the number density of phenocrysts, especially the number density of magnetite microphenocrysts (1–100 mm⁻³), which is the only mineral species able to reduce significantly the degree of water supersaturation required for bubble nucleation. Very low BNDs (≈1 mm⁻³) are predicted in the case of effusive eruptions ( ≈ 0.1 kPa/s). High BNDs (up to 10⁷ mm⁻³) and bimodal bubble size distributions are expected in the case of explosive eruptions: (1) a relatively small number density of bubbles (1–100 mm⁻³) will first nucleate in the lower part of the conduit ( ≈ 10 kPa/s), either at high pressure on magnetite or at lower pressure on quartz and feldspar (or by homogeneous nucleation in the liquid) and (2) then, extreme decompression rates near the fragmentation level ( ≈ 10³ kPa/s) will trigger a major nucleation event leading to the multitude of small bubbles, typically a few micrometers to a few tens of micrometers in diameter, which characterizes most silicic pumices.     

Fragmentation of magma during Plinian volcanic eruptions

 The ratio of the volume of vesicles (gas) to that of glass (liquid) in pumice clasts (V _G /V _L ) reflects the degassing and dynamic history experienced by a magma during an explosive eruption. V _G /V _L in pumices from a large number of Plinian eruption deposits is shown here to vary by two orders of magnitude, even between pumices at a given level in a deposit. These variations in V _G /V _L do not correlate with crystallinity or initial water content of the magmas or their eruptive intensities, despite large ranges in these variables. Gas volume ratios of pumices do, however, vary systematically with magma viscosity estimated at the point of fragmentation, and we infer that pumices do not quench at the level of fragmentation but undergo some post-fragmentary evolution. On the timescale of Plinian eruptions, pumices with viscosities <10⁹ Pa s can expand after fragmentation, as long as their bubbles retain gas, at a rate inversely proportional to their viscosity. Once the bubbles connect to form a permeable network and lose their gas, expansion halts and pumices with viscosities <10⁵ Pa s can collapse under the action of surface tension. Textural evidence from bubble sizes and shapes in pumices indicates that both expansion and collapse have taken place. The magnitudes of expansion and collapse, therefore, depend critically on the timing of bubble connectivity relative to the final moment of quenching. We propose that bubbles in different pumices become connected at different times throughout the time span between fragmentation and quenching. After accounting for these effects, we derive new information on the fragmentation process from two characteristics of pumices. The most important is a relatively constant minimum value of V _G /V _L of ∼1.78 (64 vol.% vesicularity) in all samples with viscosities >10⁵ Pa s. This value is independent of magma composition and thus reflects a property of the eruptive mechanism. The other characteristic is that highly expanded pumices (>85 vol.% vesicularities) are common, which argues against overpressure in bubbles as a mechanism for fragmenting magma. We suggest that magma fragments when it reaches a vesicularity of ∼64 vol.%, but only if sheared sufficiently strongly. The intensity of shear varies as a function of velocity in the conduit, which is related to overpressure in the chamber, so that changes in overpressure with time are important in controlling the common progression from explosive to effusive activity at volcanoes. Received: 19 April 1995 / Accepted: 3 April 1996