水溶液中聚合物在粘土上的吸附

水溶液中聚合物在粘土上的吸附对于聚合物污染防治和污水处理等都有重要意义。Scheutjens-Fleer理论是应用范围最广的聚合物吸附理论,适应于从单体到长链高聚物,从链无相互作用的稀溶液到纯聚合物的吸附研究。本文简要介绍了有关聚合物吸附的重要参数,包括吸附量、耦合分数或直接表面覆盖、平均层厚度和链段密度,以及相应的测定方法。文中分析了影响聚合物吸附研究发展的主要问题,指出水溶液中聚合物在粘土上的吸附研究的发展方向是综合研究吸附等温线和A/V效应、耦合分数、吸附层厚度、吸附分级现象和对粘土层间的影响,并与Scheutjens-Fleer理论计算结果进行比较。     

聚合物驱组合段塞分注实验研究

萨尔图油田南二区东部140号断层以东地区葡11—4油层,以多段多韵律和正韵律沉积为主,平均孔隙度30．0％,平均空气渗透率1980×10^-3μm2。水驱结束时该油层平均含水92％,采出程度39．5％。计划对该区块实施聚合物驱开采。以往经验认为,组合段塞调整注聚技术能够有效改善流度控制作用。然而对组合注入情况下如何进一步提高驱油效果、注入井分注时机、层段注入强度对开发效果有何影响却很少探讨。通过室内驱油实验,在聚驱的组合段塞注入不同时机（水驱空白阶段、含水下降阶段、含水稳定阶段、含水回升阶段）下调整注入强度实施分注以及在含水回升分注基础上进一步调整注入强度,同时对比不分注实验,评价各方案驱油效果。实验表明：不实施分注时聚驱采收率在水驱基础上提高了19．07个百分点,而组合段塞注入时实施分注均能够在不分注基础上进一步提高驱油效果;空白水驱时实施分注采收率提高幅度最大,为26．55个百分点;随着分注时机的滞后采收率提高幅度增加值依次递减,分注时机越早越好。     

聚合物驱油浓度与粘度的研究

本文对聚全物驱油试验获得聚合物溶液的方式和聚合物浓度、粘度的测定进行了研究和比较，得到了辉锐公司自动混配装置中的可编程控制器设置浓度的修正值。此研究对控制聚合物浓度稳定、准确地注入和聚合物驱油效果的评价具有实际价值。     

Superhydrophobic and superoleophillic surface of porous beaded electrospun polystrene and polysytrene-zeolite fiber for crude oil-water separation

This research presents a cheap route procedure for the preparation of a potential adsorbent with superhydrophobic/superoleophillic properties for selective removal of crude oil from water. In this study, expanded polystyrene (EPS) was electrospun to produce beaded fibers in which zeolite was introduced to the polymer matrix in order to impart rough surface to non-beaded fiber. Films of the EPS and EPS/Zeolite solutions were also made for comparative study. The electrospun fibers EPS, EPS/Zeolite and resultant films were characterized using SEM, BET, FTIR and optical contact angle. The fibers exhibited superhydrophobic and superoleophillic wetting properties with water (>150⁰) and crude oil (0⁰). The selective removal of crude oil presents new opportunity for the re-use of EPS as adsorbent in petroleum/petrochemical industry.     

聚合物防塌钻井液在天津地热定向井的应用

针对天津市地热定向井施工中存在的孔壁不稳的问题，经过摸索，采用聚合物防塌钻井液进行护壁堵漏，取得了良好的效果。介绍了聚合物防塌 井液的组分、作用机理、特点以及现场应用情况。     

In - Depth Colloidal Dispersion Gels Improve Oil Recovery Efficiency

Princinple of colloidal dispersion gels technologyColloidal dispersion gels are made of low concentrations of POlymer and crosslinker. Polymer concentrations normally range from 100 to 1200 ppm.In this concentration range, there is not enoughpolymer to fo…     

锂离子二次电池电解质的研究动态

简要介绍了锂离子电池和其电解质的发展概况 ,并重点介绍了锂离子电池电解质的分类以及各自的性能特点 ,展望了锂离子电池电解质的发展前景。     

ALTERNATIVE INDICES OF THE OVERLOAD FREQUENCY IN AN EFFLUENT RE-USE SYSTEM

An effluent re-use system is examined in which all effluent was stored until it could be used for the irrigation of crops, the storage having sufficient capacity to limit overloading to one in ten years. Three methods for estimating the required storage capacity were compared using climate data from four locations in New South Wales, Australia. A daily soil water budget identified the irrigation opportunities, and a storage subroutine in the budget calculated the peak storage requirement in each year The first method used the ninth decile in the cumulative probability distribution of the annual peak storage requirements as a direct estimate of the storage capacity with a 10% frequency of overloading. The other methods used the peak storage requirement in selected design years. These represented years with either the tenth smallest annual irrigation potential or the tenth largest annual rainfall. Methods which used design years tended to underestimate the storage requirements because the indices did not assess the daily distribution of rainfall within a month or year. Although the overload frequency was set at 10%, the overload was less than 2% of the total volume of effluent because overloading did not occur throughout the year.     

The role of syntectonic sedimentation in the evolution of doubly vergent thrust wedges and foreland folds

This paper shows the evolution of time-constrained two-dimensional scaled analogue models of doubly vergent thrust systems in the presence of syntectonic sedimentation. Two sets of experiments were considered: (1) the addition of a syntectonic layer composed of a polymer and overlying sand in the prowedge; and (2) the addition to the previous condition of a progradational sedimentary load. Results from the first set of experiments indicate that the foreland fold-and-thrust belt has a strong relationship with the competence of the syntectonic layers. When the competence is low, the deformation produces tight asymmetric detachment-folds. As the competence increases, the fold-and-thrust belt shows break-trough folds with longer and better defined foreland-vergence. Results from the second set of experiments indicate that structural vergence is determined by the sense of progradation of the syntectonic layers, and in the case of strong aggradation at the prowedge, extension and reactive diapirism form contemporaneously with the contraction. Three end-members are proposed for mountain front thrust systems formed in the presence of syntectonic polymer and sand sedimentation: (1) outcropping fold-and-thrust belt sequence, in the case of no syntectonic sedimentation; (2) long displacement blind-thrust sheets, in the case of under-filled basins and (3) short displacement blind-thrust sheets, in the case of over-filled basins. All results indicate that ductile units at the base of syntectonic layers increase the displacement of the underlying frontal thrusts at the prowedge, and reduce the critical taper. Results also indicate that at very high sedimentary rates and hyper-critical taper conditions the prowedge collapses. Conclusions drawn from this research may be applied as an analogue to foreland evolution and to evaluate hydrocarbon generation, migration, and entrapment in thrust belts in areas where seismic imaging is generally poor.