重油凝胶色谱制备样品中痕量镍的分析研究

研究表明微波密闭消解法对重油凝肢色谱制各样品的前处理，不造成易挥发有机金属化合物的损失，对样品无污染。采用消解前定容，配合石墨炉二次进样富集样品，可以测定样品中低至10^—9级的镍。方法应用于镍在渣油中随相对分子质量分布分析中，标准样品对照数据吻合好，相对标准偏差(RSD，n＝11)为8％。     

含水层渗透性能变化对水位影响的数值模拟研究

应用有限差分法,对弹性孔隙介质在无水平应力作用情况下的充水过程和充水稳定后部分区域阻塞情况下水头调整过程进行了分析。研究结果显示:就含水层内某一点而言,其水头除与位置和含水层的边界条件有关外,还与它本身及其周围区域的压力传导系数有关;含水层不同程度的阻塞会引起给定点的水位变化,而且不同的阻塞范围对含水层的水头分布和给定点的水头变化有很大的影响。     

海藻多糖分子量及其分布测定Ⅱ——GPC/LALLS联机测定四种海藻多糖分子量分布

采用凝胶渗透色谱与激光小角光散射仪联机(GPC/LALLS)测定了青岛海洋大学海洋药物与食品研究所新研制的四种海藻多糖的分子量分布。分别得到四种海藻多糖的微分、积分分子量分布曲线图、分布宽度指数(D)和数量平均、重量平均和Z均分子量。     

An artificial neural network for groutability prediction of permeation grouting with microfine cement grouts

The use of microfine cements in permeation grouting has been growing as a strategy in geotechnical engineering because it usually provides improved groutability (N). One of the major challenges of using microfine cement grouts is the ability to estimate the N within a reasonable level of error. The suitability of traditional groutability prediction formulas, which are mostly based on the grain-size of the soil and the grout, is questionable for semi-nanometer scale grout. This study first investigated the accuracy of the current formulas; we found that the accuracy ranges from 45% to 68%, a level that is not adequate for practical engineering. An alternative approach, based on a Radial Basis Function Neural Network (RBFNN), was developed. RBFNN provides a prediction with a 95.8% accuracy within a short time frame. Several parameters were considered in our proposed network; besides the grain-size of the soil (D₁₀/D₁₅), other important parameters included the void ratio (e), the fines content (FC), the uniformity coefficient (C_u), the coefficient of gradation (C_z) and the water-to-cement ratio (w/c). A total of 240 in situ data samples were collected to support the training and testing of the network. After finding a good correlation between the field observation and the RBFNN output, it was concluded that RBFNN is a suitable and reliable tool to predict the outcome of permeation grouting when microfine cement grout is used.     

Numerical investigation of the gel barrier formation with vertical injection pipe

Permeation grouting is the injection of a fluid grout into ground and production of a solidified mass to carry increased load and/or fill voids to control water flow. This study examined a technology of constructing horizontal gel barrier by the permeation grouting through multiple vertical injection pipes. Colloidal Silica (CS) solution was used as a gelling liquid to be injected and solidified in the unsaturated soil. Formation of a gel bulb was simulated and the results were compared with those obtained from the sleeve pipe injection with horizontal pipes. The gel bulb generated from the injection method employing vertical pipe showed greater sensitivity of the bulb’s lateral extent to variations in operating conditions compared to the sleeve pipe injection. Although in the limited numbers, in all examined cases, the vertical-pipe system appeared to consume a larger volume of CS solution than the horizontal-pipe system to form an equivalent horizontal gel barrier. This result supports our intuition that the injection with the horizontal pipes may be more effective than the one with vertical pipes in constructing horizontal gel barrier.     

承压井水位对气压动态过程的响应

本文从气压影响承压井水位的偏微分方程出发,考虑到井孔和含水层之间相互渗流的边界条件,得出了方程的解。给出了承压井水位对气庄动态过程响应的气压效率和位相滞后。讨论了气压效率和位相滞后与水井含水层系统各参数的关系。并指出气压效率越大的承压井,其含水层对应力应变的敏感程度越差。     

承压井水位对地表水潮汐的响应

本文以地表水潮汐影响承压井水位的偏微分方程为基础,考虑到井孔和含水层之间相互渗流的边界条件,得出方程的解。通过对解中水井含水层参数给予一些可能的值进行数值计算,绘出了承压井水位地表潮汐荷载效率与位相滞后曲线,讨论了这个效率和位相滞后水井含水层参数之间的关系。认为这个效率主要取决于含水层的孔隙度和固体骨架压缩系数;孔隙度愈小,压缩系数愈大,则效率也愈大。而位相滞后主要取决于含水层的渗透系数和厚度;这两个参数越大,则位相滞后越小。 本文还介绍了上海地区地下水位与地表水潮汐的观测结果。把这些观测结果和本文理论结果比较分析,两者符合得较好。     

加速溶剂提取/GC-MS同时测定动物组织中有机氯农药和多氯联苯

动物组织样品油脂含量大、干扰杂质多,对其中低含量有机氯农药及多氯联苯的分析会造成较大程度的影响。针对动物组织样品基质复杂的特点,本文以二氯甲烷-丙酮（体积比为1：1）的溶剂体系,采用加速溶剂萃取技术对样品进行提取,在提取过程中尽量减少脂肪的共提出,然后采用凝胶渗透色谱技术去除样品中的大部分油脂,再结合弗罗里硅土为填料的固相萃取方法对样品进一步净化,能够达到充分去除油脂和小分子杂质的目的。采用气相色谱-质谱分析17种有机氯农药及7种指示性多氯联苯,各化合物的回收率在81.6%~113.4%之间,检出限在1.02~3.59 ng/g之间,技术指标优于部分国家标准。本方法改进了动物样品的净化效果,建立了凝胶渗透色谱结合固相萃取技术的净化方法,达到了样品快速自动提取、溶剂用量少、基质净化彻底的目的,降低了方法检出限,能够满足快速、准确检测动物组织中低含量持久性有机污染物的要求。