近地层O3和CO2浓度变化对冬小麦影响的数值模拟：Ⅱ模拟结果和分析

针对CO2和O3浓度变化对冬小麦影响,改进了农田生态系统碳氮生物化学模型(DNDC),并利用模型模拟了O3和CO2浓度变化对冬小麦生长发育和产量的影响,检验了模型的模拟效果.通过对原DNDC模型适用性的调整,使之适用于固城站,为进一步改进作物模型打下了可靠的基础.通过试验资料验证表明,模型较好地反映了O3和CO2浓度变化对冬小麦生长发育和产量形成的影响.通过敏感性分析得出,模型对温度变化反映灵敏;在CO2浓度倍增情况下,O3浓度变化对冬小麦的复合影响分析看出,一定浓度范围内,CO2可缓解O3对作物影响的负效应,O3对CO2带来的正效应有削弱作用.     

O3浓度增加对冬小麦影响的试验研究

利用OTC 1型开顶式气室对冬小麦进行不同O3 浓度处理的试验研究。结果表明 ,O3 浓度增加 ,冬小麦发育期表现为开花前期有所延迟 ,开花后期的各发育期明显提前 ,生育期缩短 ,植株矮化 ,干物质累积量明显下降。无论是长时期通气处理还是阶段性通气处理 ,产量均明显降低     

青藏高原平流层臭氧和气溶胶的变化趋势研究

通过分析SAGEⅡ资料,发现青藏高原平流层臭氧存在递减趋势,15—50 km臭氧的变化对臭氧总量变化贡献最大,其中25—50 km和15—25 km两层的贡献大致相当。通过青藏高原和中国东部地区平流层臭氧变化的对比,清楚地看出:两地臭氧总量变化的差异主要是由于在15—25 km臭氧变化不同所致。5—7月臭氧变化趋势的情况与年平均的变化类似,两地臭氧变化的差异主要在平流层低层,即15—25 km。青藏高原平流层气溶胶面密度的时间变化序列显示:大的火山喷发对青藏高原平流层气溶胶具有重要影响,其影响可持续6年左右。从1997年至今,青藏高原18—25 km气溶胶面密度增加,最大的增长出现在23 km,每年大约增长4%—5%。而在16—17 km气溶胶的面密度出现减少趋势。与此同时,在37 km以下,青藏高原的温度出现递减的趋势,而且其递减速度比中国东部地区快;在37—50 km,温度出现增加的趋势,青藏高原的增温也比中国东部地区快。青藏高原平流层低层气溶胶的增加和温度的降低都将增强该区域非均相反应的作用。     

臭氧及臭氧类高级氧化技术降解甲基对硫磷的效能

文章研究了臭氧及臭氧类高级氧化技术(AOPs-O3)在不同pH条件下降解甲基对硫磷(MP)的效能。结果表明,在pH 3~10的条件下(反应过程控制pH),单独臭氧化5min即可完全降解MP,但不同pH下化学耗氧量(COD)和有机磷的释放率差异明显。在pH为3.3,7.5和9.4的条件下单独臭氧30min后COD的去除率分别为55.17%,89.64%和93.10%,有机磷的释放率分别为16.33%,95.00%和99.99%。考虑酸性条件下可以规避碳酸盐的负面影响(特别是高浓度废水),利用O3/H2O2/Ti(IV)在pH 3.3条件下处理MP溶液,COD去除率和有机磷释放率分别达到89.64%和81.57%。相对法计算求得MP与O3和羟基自由基(·OH)的速率常数分别为31.98L·(mol·s)-1和7.488×109 L·(mol·s)-1。活性污泥法的测试结果表明,MP经O3/Ti(IV)/H2O2(pH=3.3)和O3(pH=9.4)可提升含MP废水的可生化性,但与培养液体系相比仍具有一定的毒性。     

Representativeness of total ozone trends as derived from satellite BUV and ground-based measurements

The information content of the 7-year BUV data set has been reexamined by a comparison with a fairly large set of ground Dobson and M-83 instruments. The satellite-ground intercomparison of total ozone was done under different types of ground observation techniques (observation code) and different instrument exposure (exposure code) and for various distances of the subsatellite point from the station. Because of the existing latitudinal gradient in total ozone, at a given station the bias ground-BUV tends to be smaller when the subsatellite point is at a latitude higher than the station's latitude. Knowing the total ozone gradient at a given station, the BUV total ozone has been corrected to account for the ozone gradient and the correlation was calculated with the corresponding ground observations. These correlations seem to offer no improvement when compared with the correlations between the ground ozone and the actual BUV ozone at distances of the subsatellite point from the station within 200 km from the station used in previous studies. The seasonal variation of the BUV-ground correlation reveals information on the noise level of the measurements and the geographical distribution of the percentage mean bias: (Ground-BUV)×100/(Ground) is discussed. Both on short and on longer time scales it appears that the BUV derived recommended total ozone data set is reasonably good and possible instrumental drifts are not large. The analysis includes an extension through April 1977 of the BUV and contour-derived total ozone trends byLondon andLing (1980). Over the northern hemisphere both data sets (contour and BUV) show comparable trends over middle and high latitudes which range from –3 D.U./year to –5 D.U./year during the 7-year period April 1970–April 1977. In the southern hemisphere, however, long-term variation in total ozone cannot be determined from ground observations alone. It is concluded that for unknown reasons during the 7-year period of study, total ozone has been decreasing over most of the globe. The negative growth rates at high latitudes of the northern hemisphere are highly significant.     

极区大气臭氧变化对中国气候影响的数值模拟

首先利用TOMS资料分析了南北极区大气臭氧总量的季节变化特征。结果表明 ,南北极区的臭氧减少都是春季下降最快 ,然后通过数值试验得到 ,极区大气臭氧减少将造成高低层温度差值分布大致相反 ,由于臭氧减少也将使我国的大气环流形势和降水分布特征发生改变。在我国的不同区域 ,各气象要素的变化也具有不同特征。     

The action of chlorine on the ozone layer as given by a zonally averaged two-dimensional model

In order to study the behavior of stratospheric minor constituents related to aeronomic processes and atmospheric transport in the meridional plane, a numerical two-dimensional model is established.This model is applied to the study of chlorine compounds in the stratosphere. A special attention is devoted to the effect in the ozonosphere of an increase of CIX due to anthropogenic activities.     

基于WACCM+DART的临近空间SABER和MLS臭氧观测同化试验研究

本研究在WACCM+DART（Whole Atmosphere Community Climate Model,Data Assimilation Research Test-Bed）临近空间资料同化预报系统中加入SABER（Sounding of the Atmosphere using Broadband Emission Radiometry）和MLS（Microwave Limb Sounder）臭氧观测同化接口,并以2016年2月一次平流层爆发性增温（SSW）过程为模拟个例进行了SABER和MLS臭氧观测同化试验,得出以下结论:同化SABER和MLS臭氧体积浓度观测得出的WACCM+DART臭氧分析场能够较真实反映SSW期间北极上空平流层臭氧廓线随时间的演变特征,且与ERA5（Fifth Generation of ECMWF Reanalyses）再分析资料描述的臭氧变化特征具有很好的一致性;基于SABER和MLS臭氧观测的WACCM臭氧6 h预报检验表明同化臭氧观测对臭氧分析和预报误差的改善效果主要体现在南半球高纬平流层和北半球中高纬平流层中上层-中间层底部;基于ERA5再分析资料的WACCM+DART分析场检验表明同化SABER和MLS臭氧体积浓度资料可在提高北半球高纬地区上平流层-中间层底部臭氧场分析质量的同时减小该地区上平流层-中间层底部温度场和中间层底部纬向风场的分析误差;基于MLS臭氧资料的臭氧中期预报检验表明相对控制试验同化SABER和MLS臭氧体积浓度资料能更好改善0~5 d下平流层和中间层底部臭氧的预报效果。     

Monitoring Mongolia Gobi dust transport using OMI data

The characteristics of long-distance dust transport from Asia to the United States over the Pacific Ocean are statistically analyzed using OMI AI (Ozone Monitoring Instrument Aerosol Index) data during 2005–2007. The results show that there is a high correlation of AI (the correlation coefficients are as high as 0.83 in March, 0.62 in April and 0.54 in May) between the Mongolia Gobi Desert and the west coast region of the United States (40°–50°N, 120°–130°W), indicating a strong source-receptor area relationship. Through calculating the lag correlation coefficient of the dust propagation time, we determined that the dust propagation time from the Mongolia Gobi Desert to the west coast of the United States is about 6–7 days at the 99% confidence level.