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1.
Chemical structure of Jurassic vitrinites isolated from the coals in basins in NW China have been checked using solid state 13C NMR and flash pyrolysis-GC/MS. Study shows some Jurassic collodetrinites are rich in aliphatic products in pyrolysates, consisting with the high amount of methylene carbon in 13C NMR spectra. In contrast, pyrolysates of Jurassic collotelinites are rich in phenols and alkylbenzenes. Also one Pennsylvanian and one Permian vitrinite selected from the Ordos basin, NW China have been checked for comparison. The proportion of aliphatics is low in pyrolysates, and aliphatic carbon peak in 13C NMR spectrum of Permian vitrinite is mostly composed of gas-prone carbons compared with collodetrinites in those Jurassic basins. But both pyrolysis and 13C NMR data shows the Pennsylvanian vitrinite is not only gas-prone but also oil-prone. Relatively high proportion of long chain aliphatic structure of some Jurassic vitrinite in Junggar, Turpan-Hami basins may be due to the contribution of liptodetrinites, which may be included during the formation of vitrinites. And it seems that suberinite is the most possible precursor of long chain aliphatics in the structure of Jurassic collodetrinite. 相似文献
2.
Mucous macroaggregates, recently observed in the northern Adriatic in summer of 1997 and late spring of 2000, are primarily the product of phytoplankton (diatom) exudates during favourable environmental conditions in late spring, and can be viewed as macrogels. The FT-IR and 1H-NMR spectra of macroaggregate samples from the northern Adriatic, collected in different formation stages in July 1997, August 1997, September 1997 and June 2000, as well as of cultured diatom Skeletonema costatum, showed that they are similar and composed of aliphatic components and polysaccharides bonded through carboxylic and amide groups, and organosilicon compounds. The stability of macrogels of macroaggregates is, according to FT-IR and X-ray analyses, most probably enhanced by interactions with entrapped particles of calcite, quartz and clay minerals. These organic-mineral associations seem to be important for mucous phenomena. According to 1H-NMR spectra, the temporal differences in macroaggregate composition show a relative increasing percentage of organosilicon compounds and aliphatic components bonded to carbohydrates through ester and amide groups, and an increasing ratio between aliphatic structures and carbohydrates. This indicates that aliphatic chains bonded to Si and carbohydrates may contribute to the persistence and stability of macroaggregates in the summer stratified waters in the northern Adriatic, while the temporal decrease of carbohydrate content is most probably due to microbial and photochemical degradation of algal reserve polysaccharides. 相似文献
3.
Akinobu Miyakoshi Takeshi Hayashi Atsunao Marui Yasuo Sakura Shinichi Kawashima Masafumi Kawai 《International Journal of Earth Sciences》2008,97(2):401-411
Information on the distribution of subsurface temperature and hydraulic heads at 24 observation wells in and around the Tokyo
Lowland, the eastern part of the Tokyo Metropolitan area, were examined to make clear the relationship between groundwater
and the subsurface thermal environment in the urban area. Minimums in temperature–depth logs due to subsurface temperature
increasing at shallow parts were recognized in 21 wells. This fact shows subsurface temperature is affected by ground surface
warming in almost all of this area. Deeper than minimums, where the effects of surface warming became relatively small, regional
variation is observed as follows: high temperatures are shown in the central part to the southern part, and low temperatures
shown in the inland to eastern part. The high temperature area corresponds to an area where the lower boundary of groundwater
flow is relatively shallow. This area corresponds also to an area with severe land subsidence resulting from excessive groundwater
pumping. It is considered that this high temperature area is formed by the effects of upward groundwater flow affected by
hydrogeological conditions and pumping. On the other hand, a comparison between past data (1956–1967) and present data (2001–2003)
revealed widespread decreasing temperature in the inland area. This is explained by downward groundwater flow based on an
analysis of temperature–depth logs. This fact suggests that subsurface temperature is not only increasing from the effects
of surface warming but also decreasing from the effects of groundwater environment change due to pumping. 相似文献
4.
利用核磁共振方法研究水文地质问题及应用实例 总被引:14,自引:1,他引:14
地面核磁共振找水方法是目前唯一直接找水的物探新方法。本文在介绍NMR方法原理的基础上,结合NMR方法技术特点和在中国的应用实例,论述了NMR方法在探测地下水、地下水资源评价等方面的效果,并提出了进一步开展新方法的工作建议。 相似文献
5.
目的 医学核磁共振与地面核磁共振找水是核磁共振技术应用的不同领域。本文通过对二者在方法原理、技术、应用等方面的对比研究,提出了地面核磁共振找水工作建议。 相似文献
6.
高岭石—莫来石反应系列:^27Al和^29SiMAS NMR研究 总被引:21,自引:2,他引:21
根据艰我国八个不同成因和特征的高岭土样品在450-1450℃热处理产物的MAS NMR谱和XRD,IR,DTA等研究结果,结合有关资料讨论了高岭石-莫来石反应序列的几个重要问题:1.高岭石的结构,尤其是五配位铝;2.980℃放热峰后的高温相是γ-Al2O3而不是Al-Si尖晶石;3.对于莫来石化过程,认为初始莫来石850-950℃变高岭石形成,二次莫来石由分凝的SiO2和γ-Al2O3在1200- 相似文献
7.
Characterizing the properties of dissolved organic matter isolated by XAD and C-18 solid phase extraction and ultrafiltration 总被引:1,自引:0,他引:1
8.
9.
孔隙度和渗透率是储层评价的两个重要参数.岩石毛管压力曲线和核磁共振T2谱图是描述储层微观结构特征的重要参数.通过测量不同压力条件下岩心样品的孔隙度和渗透率,得到了孔隙度和渗透率随压力的变化情况.实验结果表明:孔隙度和渗透率随着压力的增加而降低,并且与压力服从对数函数变化规律.不同孔隙度渗透率区间的砂岩样品,孔隙度和渗透率随着压力变化的趋势不同.通过测量不同粒级砂岩样品的毛管压力曲线和核磁共振T2谱图,证实了孔隙结构对孔隙度和渗透率的影响,微观孔隙结构是决定渗透性好坏的关键因素. 相似文献
10.
With the increasing development of coalbed methane (CBM) field, the quantitative characterization and evaluation of coal reservoir physical properties is becoming more and more important to CBM scale development. In order to solve the limitations of conventional methods for testing coal reservoir physical properties, the authors used the high-tech technologies such as nuclear magnetic resonance technology and CT scanning technology to effectively solve the problems of in-situ and integrity of rock samples and acquire the porosity and permeability. Nuclear magnetic resonance and CT scanning experiments of coal samples were carried out to rapidly obtain the pore type, pore size distribution and connectivity, effective porosity, spatial distribution of pore fissures and other refined coal reservoir physical parameters, based on the samples of middle and low rank coal in Shenfu block and high rank coal in Shizhuangnan block. So a set of quantitative characterization analysis technology that can be applied to coal reservoirs with different coal rank was formed. 相似文献