A laboratory test of the soil chemical submodels of two models of catchment acidification

Parameters for ion exchange selectivity and aluminium hydroxide dissolution in the soil chemical submodels used in applications of the Birkenes model and of MAGIC are compared and several discrepancies identified for organic soils. A laboratory column simulation of the soil chemical submodels is proposed and applied to soils from the Loch Dee area in Galloway. Experimental results were well predicted by a simplified version of MAGIC, with ion exchange selectivity parameters similar to those used in a previous simulation of one subcatchment of Loch Dee. The aluminium hydroxide dissolution parameter used previously was found to be too low for the organic soil materials, where a value of 106 predicted the experimental results more closely. The model developed also included a simple silicate weathering reaction to release base cations into the system. It is concluded that such simple laboratory simulations are useful for independent calibration of the soil chemical submodel of catchment models.     

Fast neutral particles as probes of the extent of Io's exosphere

The spatial extent of ion cyclotron waves at Io has been interpreted as requiring a multistep acceleration and transport process: exospheric ions are accelerated outward (relative to Jupiter) due to the corotation electric field, neutralized due to charge exchange in the surrounding exosphere, and then reionized after traveling far across magnetic field lines, at which point they generate the waves. The trajectories of the particles away from Io are sensitive to the location of their initial ionization. This paper examines the spatial distributions of fast neutrals produced under varying conditions in order to provide constraints on the possible structure and nature of the Io exosphere. While a rapid onset of cyclotron waves at a specific location around Io can be modeled with a single, point-source region of ions, such as might occur over a volcano, the regional extent of the waves suggests multiple or distributed sources.     

东海黑潮水与陆架水的季节性输运和交换

在流星分析和ｔ－Ｓ点聚分析的基础上，在台湾东北部ＩＳ断面和东海中部ＰＮ断面上选取适当的纵剖面作为分界面，将以面分成东、西两侧，计算了界面两侧的海水交换星。结果表明：１．东海陆架区海水交换可归纳为两种类型，即“穿插型”和“进退型”。２．参与分界面处海水交换总量的年平均是夏季最大，春、秋季次之，冬季最小。黑潮水向陆架区输运量为０．５８×１０６ｍ３／ｓ，陆架水向黑潮刚输运量为０．８４×１０６ｍ３／ｓ；参与交换的总量为１．４２×１０６ｍ３／ｓ．３．相对输运量计算结果表明；黑潮水对陆架区水文状况的影响是冬季最强，秋、春季次之，夏季最弱，而陆架水对黑潮区水文状况的影响是夏季最大，秋季次之，春季和冬季最小。     

虚拟现实技术在矿物数字博物馆中的应用

详细介绍基于照片的虚拟现实技术在矿物数字博物馆中的实现方法和应用,并对VRML与基于照片的虚拟现实技术进行分析研究,进而对两种实现方法的发展方向和应用前景提出见解。     

平流层-对流层交换研究进展

平流层与对流层之间的物质输送和混合（STE）是控制自然和人为排放的化学痕量物质对大气成分影响的一个重要过程。STE可以影响温室气体在上对流层和下平流层中的垂直分布，进而影响气候。要预报全球气候变化就必须了解平流层与对流层之间动力、化学及辐射的耦合。从 STE研究的尺度问题，热带和中纬度地区STE研究以及我国STE研究现状进行了评述。STE具有多种尺度和形式，热带外平流层由波强迫驱动的全球尺度环流，可以诊断长时间尺度的STE，它不能充分描述短时间尺度过程。热带外低平流层环流不能简单地描述为纬向平均，要正确描述痕量气体的分布必须包含纬向非对称的天气尺度过程。热带地区的滴漏管理论提供了一个新的诊断 STE框架。目前对中纬度地区对流层顶折叠和切断低压的研究是比较充分的。     

浓硫酸钠水溶液中的离子对

不同浓度的Na2SO4水溶液的拉曼光谱显示了SO42-的四个拉曼活性带:980 cm-1处的SO42-的对称伸缩振动模式v1带,1 106 cm-1处的反对称伸缩振动模式v3带,448 cm-1处的变形振动模式v2带和617 cm-1处的变形振动模式v4带。482 cm-1处的肩膀峰是由于NaSO4-离子对的形成对448 cm-1的v2带的影响而形成的SO42-的一个新的振动峰。浓Na2SO4水溶液中,水共享离子对[Na+.H2O.SO42-]-是主要的离子对物种。随着Na2SO4水溶液浓度的增加,Na+和SO42-的相互作用增强,NaSO4-离子对所占的摩尔分数增加。     

Formation and stability of mixed Mg/Ca/phytate species in synthetic seawater media: Consequences on ligand speciation

The results of a potentiometric investigation (by ISE-H⁺, glass electrode) on the speciation of phytate ion (Phy¹²⁻) in an ionic medium simulating the major components (Na⁺, K⁺, Ca²⁺, Mg²⁺, Cl⁻ and SO₄²⁻) of natural seawater, at different salinities and t = 25 °C, are reported. The work was particularly aimed at determining the possible formation of mixed Ca²⁺–Mg²⁺–phytate ion pairs, and to establish how including the formation of these mixed species would affect the speciation modeling in seawater media. After testing various speciation models, that considering the formation of the MgCaH₃Phy⁵⁻, MgCaH₄Phy⁴⁻, Mg₂CaH₃Phy³⁻ and Mg₂CaH₄Phy²⁻ species was accepted, and corresponding stability constants were determined at two salinities (S = 5, 10). A discussion is reported both on the choice of the experimental conditions and on the possibility to extend these results to those typical of real seawater. A detailed procedure is also described to demonstrate that the stability of these species is higher than that statistically predicted. As reported in literature, a parameter, namely log X, has been determined in order to quantify this extra stability for the formation of each mixed species at various salinities. For example, at S = 10, log X₁₁₃ = 2.67 and log X₁₁₄ = 1.37 for MgCaH₃Phy⁵⁻ and MgCaH₄Phy⁴⁻ (statistical value is log X_stat = 0.60), and log X₂₁₃ = 6.11 and log X₂₁₄ = 2.15 for Mg₂CaH₃Phy³⁻ and Mg₂CaH₄Phy²⁻ (log X_stat = 1.43), respectively. Results obtained also showed that the formation of these species may occur even in conditions of low salinity (i.e. low concentration of alkaline earth cations) and low pH (i.e., more protonated ligand).     

我国海洋战略性新兴产业国际化发展研究

海洋战略性新兴产业的国际化发展对于建设海洋强国和发展海洋经济具有重要的理论和实际意义。文章分析我国海洋战略性新兴产业国际化起步晚和发展快、产业结构不断完善和区域发展水平存在差异的发展状况,提出目前存在的缺乏区域协调配合和交流合作以及政府支持政策亟须细化等主要问题,探索区域差异化发展模式、产业技术创新联盟合作模式、多元化投融资模式和国际合作模式等海洋战略性新兴产业国际化发展模式,在此基础上提出优化产业结构和布局、完善发展体制机制、加强国际交流合作、加强资金投入和人才培养以及强化示范项目建设的对策建议。     

离子色谱法测定矿物包裹体中阴离子

本文介绍了用离子色谱法同时测定矿物包裹体中F~-、Cl~-、PO_4~(3-)、Br~-、NO_3~-、SO_4~(2-)6种阴离子的新方法。研究了流动相浓度对保留时间的影响以及消除负峰干扰的方法。