三疣梭子蟹全人工工厂化育苗技术

2000年笔者在日照市水产研究所利用1450m^3水进行梭子蟹全人工工厂化育苗生产，共出Ⅱ-Ⅲ期幼蟹512．7万只，创造了出苗量为3500只／m^3，总产值为150多万元的直接经济效益，同时对幼体培育的密度进行了初步试验，结果表明：从Z1至M期幼体培育密度10－15万／m^3为宜，M期以后密度以0．8－1．5万／m^3为宜。     

Distribution of dissolved species and suspended particulate copper in an intertidal ecosystem affected by copper mine tailings in Northern Chile

The coastline near Chañaral in Northern Chile is one of the most highly Cu-contaminated zones in the world due to discharges from mining activities for more than 60 years. The speciation of Cu has been studied to determine the importance of organic complexation in highly contaminated areas, and to assess the likely physiological impacts of Cu on marine organisms. Dissolved Cu concentrations of up to 500 nM were measured, completely saturating organic ligands and leading to free Cu²⁺ concentrations in excess of 10^− 8 M. These values are higher than those reported in any other marine environment, and because they occur over an extensive area, provide a unique opportunity to study the effects of Cu on marine ecosystems and to see how Cu behaves when its speciation is predominantly inorganic. We found strong gradients in free Cu²⁺ between Chañaral and adjacent areas with lower Cu, where speciation is dominated by organic complexation. There is also a significant increase in the partitioning of Cu onto suspended particles in the contaminated areas, consistent with previous studies that showed that organic ligands stabilize Cu in the dissolved phase, whilst “excess” Cu is rapidly scavenged. Those high dissolved Cu concentrations persist in spite of solid phase partitioning and advective processes along this open-ocean coastline, suggesting that Cu inputs into the system are still very large. Measurements were made using anodic stripping voltammetry with a thin mercury film coated with Nafion, which previous workers have shown can mitigate ambiguity in the data arising from inadvertent reduction of organic complexes. Our findings suggest that this is a useful methodology for contaminated systems.     

矿山固体废弃物对地质环境的影响分析

在山西省重点地区固体废弃物现状调查研究的基础上,通过试样试验,分析研究了固体废弃物对土壤、大气、水环境的污染,探讨了对固体废弃物的治理及利用,为研究矿山生态环境地质研究提供参考,同时积累工作经验。     

区域经济空间集中化的产业成因分析——兼析海南省经济空间集中化问题

经济空间集中化起因于产业经济活动在一定空间内聚集并形成大规模的专业化生产，它以区域城市为增长中心，与区域产业结构转变有着密切的关系。经济空间集中化过程大致可以划分为三个与区域产业结构转变有关的经济增长阶段：初级阶段——均衡低速增长；中级阶段——集中快速增长；高级阶段——稳定增长。     

第14届世界无损检测大会工业CT的层析成像技术

介绍了新近１４届世界无损检测大会有关情况，并对工业ＣＴ的发展动态进行了简要的分析。     

四川盆地西部富钾卤水水文地球化学特征及其成因意义探讨

四川盆地西部宫钾卤水以深层卤水形式赋存于地下４０００余ｍ的中三叠统雷口坡组四段（Ｔ２ｌ４）盐系的碳酸盐岩储层中。富钾卤水与海水不同浓缩阶段相比，其中含Ｋ＋含量异常高，构成液态钾矿资源；Ｂｒ－、Ｉ－、Ｂ（３＋）、Ｌｉ＋等稀有组分也远超过综合利用工业品位，为优质化工原料水。富钾卤水为沉积变质和钾盐溶滤的复合成因，具有固夜态找钾的指示意义。本文为四川盆地固液态找钾提供了有价值的线索。     

垃圾和垃圾学──一门新兴科学的出现及其对中国固体废物处理事业的意义

垃圾产生于社会的每一个角落，垃圾也反映了人类生活的各个方面。可是，直至最近，社会依然极少理会垃圾中真正蕴藏着些什么，以及垃圾能够告诉我们些什么。１９７３年美国图森市亚利桑那大学威廉·拉舍基博士（ＷｉｌｌｉａｍＬＲａｔｈｊｅ）及其同事们所建立并发展的垃级计划，标志着一门新科学──垃圾学的兴起，即垃圾的系统研究、垃圾产生、运移、利用和处置的机理以及相关的社会经济和环境问题。美国和其它少数国家的垃圾学研究所揭示的各种事实、定律和原理，正划时代地碰击着现代社会、社会心理学、市场和许多其它领域，大量的城市固体废物不仅意味着自然资源的巨大浪费，而且垃圾处理，无论焚化或者填埋，都对环境构成了严重污染的威胁，尤其是对地下水资源。垃圾的管理、再循环和处置费用是昂贵的，而且总是受到错综复杂的社会和法律冲突的挑战，纽约和美国东部其它人口稠密地区所面临的严峻形势就是最好的例证，解决现今进退维谷的垃圾问题，需要包括技术的、社会的、环境的、经济的、政治的、法律的和公共教育在内的多方面协作。中国正经历着令人振奋的经济发展时期。预计以现在的国民经济发展速度，以及因巨量人口而导致的社会消费的急剧增长，在未来１０～２０年内，很有可能导致严重的     

Thermodynamic properties of tooeleite,Fe63+(As3+O3)4(SO4)(OH)4·4H2O

Tooeleite, nominally Fe₆³⁺(As³⁺O₃)₄(SO₄)(OH)₄·4H₂O, is a relatively uncommon mineral of some acid-mine drainage systems. Yet, if it does occur, it does so in large quantities, indicating that some specific conditions favor the formation of this mineral in the system Fe-As-S-O-H. In this contribution, we report the thermodynamic properties of synthetic tooeleite. The sample was characterized by powder X-ray diffraction, scanning electron microscopy, extended X-ray absorption fine-structure spectroscopy, and Mössbauer spectroscopy. These methods confirmed that the sample is pure, devoid of amorphous impurities of iron oxides, and that the oxidation state of arsenic is 3+. Using acid-solution calorimetry, the enthalpy of formation of this mineral from the elements at the standard conditions was determined as −6196.6 ± 8.6 kJ mol⁻¹. The entropy of tooeleite, calculated from low-temperature heat capacity data measured by relaxation calorimetry, is 899.0 ± 10.8 J mol⁻¹ K⁻¹. The calculated standard Gibbs free energy of formation is −5396.3 ± 9.3 kJ mol⁻¹. The log K_sp value, calculated for the reaction Fe₆(AsO₃)₄(SO₄)(OH)₄·4H₂O + 16H⁺ = 6Fe³⁺ + 4H₃AsO₃ + SO₄²⁻ + 8H₂O, is −17.25 ± 1.80. Tooeleite has stability field only at very high activities of aqueous sulfate and arsenate. As such, it does not appear to be a good candidate for arsenic immobilization at polluted sites. An inspection of speciation diagrams shows that the predominance field of Fe³⁺ and As³⁺ overlap only at strongly basic conditions. The formation of tooeleite, therefore, requires strictly selective oxidation of Fe²⁺ to Fe³⁺ and, at the same time, firm conservation of the trivalent oxidation state of arsenic. Such conditions can be realized only by biological systems (microorganisms) which can selectively oxidize one redox-active element but leave the other ones untouched. Hence, tooeleite is the first example of an “obligatory” biomineral under the conditions prevailing at or near the Earth's surface because its formation under these conditions necessitates the action of microorganisms.     

辽宁省海洋服务新业态培育与法律保障研究

海洋服务业已成为海洋经济发展的重要引擎,"十三五"时期是辽宁省海洋经济加快转型升级的关键期,要求培育新动能、发展新模式。因此,培育海洋服务新业态对辽宁省海洋经济发展具有重要意义。文章针对辽宁海洋服务业发展滞后,规模偏小、区域发展不平衡,同质化严重、科技含量低,层次相对低下、与其他产业融合不足,资源整合较差等问题,提出培育海洋服务新业态重要路径为:积极发展四大产业,提高经济规模总量;优化产业区域布局,形成错位发展;提高科技含量,提升海洋服务业层次;促进海洋服务业与其他行业融合协调,提升资源整合度。法律保障措施为:完善法规体系、严格项目审批、提高执法水平、健全应急管理。