The double solid reactant method: II. An application to the shallow groundwaters of the Porto Plain,Vulcano Island (Italy)

This paper presents an example of application of the double solid reactant method (DSRM) of Accornero and Marini (Environmental Geology, 2007a), an effective way for modeling the fate of several dissolved trace elements during water–rock interaction. The EQ3/6 software package was used for simulating the irreversible water–rock mass transfer accompanying the generation of the groundwaters of the Porto Plain shallow aquifer, starting from a degassed diluted crateric steam condensate. Reaction path modeling was performed in reaction progress mode and under closed-system conditions. The simulations assumed: (1) bulk dissolution (i.e., without any constraint on the kinetics of dissolution/precipitation reactions) of a single solid phase, a leucite-latitic glass, and (2) precipitation of amorphous silica, barite, alunite, jarosite, anhydrite, kaolinite, a solid mixture of smectites, fluorite, a solid mixture of hydroxides, illite-K, a solid mixture of saponites, a solid mixture of trigonal carbonates and a solid mixture of orthorhombic carbonates. Analytical concentrations of major chemical elements and several trace elements (Cr, Mn, Fe, Ni, Cu, Zn, As, Sr and Ba) in groundwaters were satisfactorily reproduced. In addition to these simulations, similar runs for a rhyolite, a latite and a trachyte permitted to calculate major oxide contents for the authigenic paragenesis which are comparable, to a first approximation, with the corresponding data measured for local altered rocks belonging to the silicic, advanced argillic and intermediate argillic alteration facies. The important role played by both the solid mixture of trigonal carbonates as sequestrator of Mn, Zn, Cu and Ni and the solid mixture of orthorhombic carbonates as scavenger of Sr and Ba is emphasized.

Solution of an unstable axisymmetric Cauchy–Poisson problem of dispersive water waves for a spectrum with compact support

 It has been known that the axisymmetric Cauchy–Poisson problem for dispersive water waves is well posed in the sense of stability. Thereby time evolution solutions of wave propagation depend continuously on initial conditions. However, in this paper, it is demonstrated that the axisymmetric Cauchy–Poisson problem is ill posed in the sense of stability for a certain class of initial conditions, so that the propagating solutions do not depend continuously on the initial conditions. In order to overcome the difficulty of the discontinuity, Landweber–Fridman's regularization, famous and well known in applied mathematics, are introduced and investigated to learn whether it is applicable to the present axisymmetric wave propagation problem. From the numerical experiments, it is shown that stable and accurate solutions are realized by the regularization, so that it can be applicable to the determination of the ill-posed Cauchy–Poisson problem.     

New basis for the constitutive modelling of aggregated soils

Natural and compacted soils are usually characterized by aggregation of particles. The mechanical behaviour of these materials depends on soil structure. The oedometric compression tests performed on aggregated samples presented here showed that these materials exhibit a yield limit depending not only on stress history and stress state but also on soil structure. Evidence is provided using the neutron tomography technique. These results revealed that soil structure modification occurs together with plastic deformations. The experimental results are used to propose a new state parameter to quantify the soil structure. Based on pore-scale experimental observations, an evolution law for this parameter is proposed as a function of associated plastic strains. Considering both soil fabric and inter-particle bonding effects, a new yield limit depending on stress state, stress history and soil structure is introduced for the aggregated soils. Accordingly, a new constitutive framework consistent with strain hardening plasticity is proposed to consider soil structure effects in the modelling of aggregated soils.     

Generalized Lyapunov exponents indicators in Hamiltonian dynamics: An application to a double star system

The Lyapunov characteristic numbers (LCNs) which are defined as the mean value of the distribution of the local variations of the tangent vectors to the flow (=ln _k ⁱ ) (see Froeschlé, 1984) have been found to be sensitive indicators of stochasticity. So we computed the distribution of these local variations and determined the moments of higher order for the integrable and stochastic regions in a binary star system with =0.5.     

Les failles récentes des Grands-Moulins (Savoie) : un Sackung (tassement gravitaire) majeur dans les Alpes françaises

In Savoy, the Grands-Moulins recent fault scarps, previously interpreted as seismic fault ruptures, are in fact part of a major Sackung (deep seated gravitational spreading) of the French Alps (9 km long). We mapped more than 60 sackung scarps, some of them reaching 1330 m long and 30 m high. These antislope scarps stop the active screes and offset relict Dryassic rock glaciers by 16 m. We present geomorphologic observations attesting for their gravitational origin. This Sackung is primarily due to glacial debuttressing, while seismic shaking could be a triggering mechanism. To cite this article: J.-C. Hippolyte et al., C. R. Geoscience 338 (2006).     

Adaptive Multiscale Permeability Estimation

With multiscale permeability estimation one does not select parameterization prior to the estimation. Instead, one performs a hierarchical search for the right parameterization while solving a sequence of estimation problems with an increasing parameterization dimension. In some previous works on the subject, the same refinement is applied all over the porous medium. This may lead to over-parameterization, and subsequently, to unrealistic permeability estimates and excessive computational work. With adaptive multiscale permeability estimation, the new parameterization at an arbitrary stage in the estimation sequence is such that new degrees of freedom are not necessarily introduced all over the porous medium. The aim is to introduce new degrees of freedom only where it is warranted by the data. In this paper, we introduce a novel adaptive multiscale estimation. The approach is used to estimate absolute permeability from two-phase pressure data in several numerical examples.     

耦合海-气环流模式中双热带辐合带现象及其热收支分析

文中研究了耦合海-气环流模式中的双热带辐合带(Double ITCZ)现象,并对这一现象的成因从海洋热量收支的角度进行了初步分析。Double ITCZ现象是在热带太平洋赤道南北两侧各出现一条ITCZ的现象,这是耦合海-气环流模式中的较为普遍的一种异常现象,与实际气候中出现的Double ITCZ现象并非指同一问题。文中对比观测和模式结果,指出了Double ITCZ现象的主要特征,针对它的出现过程进行细致分析,再利用模式输出的热量收支各项进行统计,得到了从海洋热收支分析得到的海表温度变化原因。与观测到的正常模态相比,Double ITCZ是一个异常的模态,它的特征突出地表现为西太平洋暖池区的降温和东南太平洋10°S附近的升温。海洋热量收支分析表明,暖池区的降温主要是受到扩散的作用,而表层平流的异常增暖在决定异常辐合带区升温过程中占第一位的作用。     

非饱和土中镉离子传输模型参数反演

使用自行设计的的真空实验装置,采用一维实验室土柱实验方法在不同实验条件下进行了15组实验,并基于实验所得的穿透曲线,使用梯度正则化方法反演得到了镉离子在8种葡萄牙土样和1种比利时土样中相应的传输模型参数。同时通过数值模拟实验验证了梯度正则化方法的有效性和可靠性,进而证明所得结果是有效的。