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排序方式: 共有326条查询结果,搜索用时 46 毫秒
1.
Variation of reactivity of particulate and sedimentary organic matter along the Zhujiang River Estuary 总被引:3,自引:0,他引:3
To investigate organic matter source and reactivity in the Zhujiang River (Pearl River)Estuary and its adjacent areas, particulate organic carbon (POC), particulate hydrolysable amino acids (PHAA), and Chl a during two cruises in July 1999 and July 2000 were measured. The highest POC and PHAA concentration was observed in the waters with maximum Chl a. The spectra distribution,relative content (dry weight in milligram per gram), PHAA-C% POC and other indicators such as the ratios of amino acids vs. amino sugars (AA/AS) and glucosamine vs. galactosamine (Glum/Gal) suggested that particulate amino acids in the water column and sediments in the Zhujiang River Estuary were mainly derived from biogenic processes rather than transported from terrestrial erosion. In inner estuary where high turbidity was often observable, organic matter was mainly contributed by re-suspension of bottom sediments with revealed zooplankton, microbial reworked characteristics, which suggest that these organic matters were relatively “old“. In the estuarine brackish region, organic matter in water column is mainly contributed by relatively fresh, easily degradable phytoplankton derived organic matter.During physical - biological processes within the eastuary, organic matter derived from phytoplankton was subjected to alteration by zooplankton grazing and bacterial reworking. 相似文献
2.
Elizabeth B. Kujawinski Rossana Del Vecchio Neil V. Blough Geoffrey C. Klein Alan G. Marshall 《Marine Chemistry》2004,92(1-4):23
Molecular-level characterization of natural organic matter (NOM) has been elusive due to the inherent complexity of natural organic mixtures and to the fact that individual components are often polar and macromolecular. Electrospray ionization (ESI) is a “soft” ionization technique that ionizes polar compounds from aqueous solution prior to injection into a mass spectrometer. The highest resolution and mass accuracy of compounds within NOM have been achieved when ESI is combined with an ultrahigh-resolution mass spectrometer such as the Fourier transform ion cyclotron resonance mass spectrometer (FT-ICR MS). With this technique, individual molecules within a variety of natural organic mixtures can be detected and their elemental composition can be determined. At low mass-to-charge (m/z) ratio, the resolution is high enough to assign exact molecular formulas allowing specific components of these mixtures to be identified. In addition to molecular identification, we can now use ESI FT-ICR MS to examine molecular-level changes in different organic mixtures as a function of relevant geo-processes, such as microbial alterations and photochemistry. Here we present the results from the application of ESI FT-ICR MS to two geochemical questions: (1) the effect of photoirradiation on the molecular composition of fulvic acids and (2) the role of protozoan grazers in the modification of DOM in aquatic systems. 相似文献
3.
Mucous macroaggregates, recently observed in the northern Adriatic in summer of 1997 and late spring of 2000, are primarily the product of phytoplankton (diatom) exudates during favourable environmental conditions in late spring, and can be viewed as macrogels. The FT-IR and 1H-NMR spectra of macroaggregate samples from the northern Adriatic, collected in different formation stages in July 1997, August 1997, September 1997 and June 2000, as well as of cultured diatom Skeletonema costatum, showed that they are similar and composed of aliphatic components and polysaccharides bonded through carboxylic and amide groups, and organosilicon compounds. The stability of macrogels of macroaggregates is, according to FT-IR and X-ray analyses, most probably enhanced by interactions with entrapped particles of calcite, quartz and clay minerals. These organic-mineral associations seem to be important for mucous phenomena. According to 1H-NMR spectra, the temporal differences in macroaggregate composition show a relative increasing percentage of organosilicon compounds and aliphatic components bonded to carbohydrates through ester and amide groups, and an increasing ratio between aliphatic structures and carbohydrates. This indicates that aliphatic chains bonded to Si and carbohydrates may contribute to the persistence and stability of macroaggregates in the summer stratified waters in the northern Adriatic, while the temporal decrease of carbohydrate content is most probably due to microbial and photochemical degradation of algal reserve polysaccharides. 相似文献
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5.
基于GDI+的GML可视化模型设计 总被引:1,自引:0,他引:1
本文介绍了基于GML地理数据的可视化模型设计方法。利用文档对象模型(DOM)对GML进行解析,以及通过对GD I+自身特性的分析,展示了在.NET环境下采用GD I+类库进行可视化模型设计的优良特性,为实现GML数据可视化提供了一个切实可行的方案。 相似文献
6.
SPOT-5影像的高分辨率和高信息量的性质,使其得到了广泛的应用,特别是在全国第二次土地利用调查中得到了更加深入的应用。而数字正射影像的制作是SPOT-5遥感影像应用的关键所在。本文在介绍DOM制作的基础上,依据当前获取GCP主要的三种途径采用ERDAS遥感图像处理软件进行了实验,并对最终的结果精度进行分析,总结了DOM制作过程的相关问题。 相似文献
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8.
The kinetics of conversion of iron(III) (hydr)oxides to ferrous iron mediated by fulvic acid have been investigated in order to improve the understanding of the redox cycling of iron at the oxic-anoxic boundary in natural waters. Under the conditions similar to natural waters, fulvic acid is able to reduce the iron(III) (hydr)oxide. The kinetics of the reaction depend on the reactivity of iron(III) (hydr)oxides and the reducing power of the fulvic acid. The rate of reaction is 60 nm/h obtained under following conditions: total concentration of Fe(III) 1.0 × 10–4 M, pH 7.5, fulvic acid 5 mg/L. The rate is considered as a net result of reduction and oxidation in the > FeIII-OH/Fe(II) wheel coupled with fulvic acid. In a real natural water system, reductants other than fulvic acid may be of importance. The results obtained in the laboratory, however, provide evidence that the Fe(OH)3(s)/Fe(II) redox couple is able to act as an electron-transfer mediator for the oxidation of natural organic substances, such as fulvic acid by molecular oxygen either in the absence of microorganisms or as a supplement to microbial activity. 相似文献
9.
基于SVG的地理信息编码与DOM交互解析实现 总被引:4,自引:0,他引:4
SVG作为新兴的基于XML的矢量图形描述规范,在很多方面与地理信息系统中的基本概念表述一致。在对地理信息进行SVG编码的基础上,利用DOM对地理信息SVG编码文档进行解析,实现了基于SVG的Web地理信息发布实例。实验表明,采用SVG技术的通用性好、矢量显示质量高、响应速度快的优点来开发地理信息的Web应用,也是顺应Web地理信息发布发展需要的。 相似文献
10.
Characterizing the properties of dissolved organic matter isolated by XAD and C-18 solid phase extraction and ultrafiltration 总被引:1,自引:0,他引:1