Comparison between the Chile and Mexico triple junction areas substantiates slab window development beneath northwestern Mexico during the past 12-10 Myr

When combined with the Miocene-Recent volcanic record of Baja California, a parallel drawn between the Chile and Mexico triple junction areas substantiates slab window development beneath northwestern Mexico during the past 12-10 Myr. The slab-free zone manifestations challenge the notion that ridge subduction has not occurred beneath the southern Baja California peninsula. The geochemically distinctive rocks from the Santa Clara volcanic field of west-central Baja California, including coeval adakites and niobium-enriched basalt, are commonly inferred to signal partial melting of the subducting plate at shallow depths and relatively high temperatures, before slab dehydration occurs. Such PT conditions for slab melting have only been observed in association with spreading-ridge subduction. We propose that slab window development beneath southern Baja California and mainland Mexico (30° to 18°N) resulted from subduction of the East Pacific rise.     

智利科皮亚波GV地区侵入岩地球化学及年代学研究

智利北中部科皮亚波GV地区位于中生代铁氧化物铜金(IOCG)矿床与斑岩铜矿过渡带。侵入岩体主要为辉长闪长岩、闪长岩、闪长斑岩、黑云母花岗岩、斑状花岗岩和二长岩。岩石地球化学特征说明该侵入岩体属于钙碱性、I型或磁铁矿系列,来源于深部上地幔。推测这些岩浆岩岩石组合形成于洋壳俯冲带,局部扩张与挤压转换导致弧后盆地萎缩封闭并快速抬升。岩浆侵入具有多期次活动,形成了多期次热液活动中心,并发育面型与脉带型蚀变矿化分带,地表具有寻找大型IOCG矿床前景。地表泥化-绿泥石-多孔状硅化网脉和含金银多金属铁锰碳酸盐化网脉发育,含金银多金属网脉状-带状和面型蚀变区揭示地表有浅成低温热液型金银多金属矿床;深部具有寻找隐伏斑岩型铜金矿床前景。今后需在该区加强蚀变矿化分带规律研究,进行深部找矿预测。     

高精度磁测在IOCG型铁矿勘查中的应用——以智利英格瓦塞铁矿为例

IOCG型（铁氧化物铜金型）矿床富含铁氧化物,且常缺失硫化物,高精度磁测是寻找IOCG矿床重要的有效手段之一。英格瓦塞铁矿位于智利中北部IOCG型矿床成矿带,前期地质工作程度较低。在智利英格瓦塞铁矿矿区地质特征调查基础上,重点针对中部矿区的7个磁异常区,利用RGIS对其高精度磁测数据进行面积上延、面积下延、剖面下延及2.5D反演拟合处理,结果表明,本区引起磁异常的磁性地质体整体呈NE向延伸、倾向NW、倾角较陡。除Ⅰ号和Ⅴ号磁异常规模较小外,其他几个磁异常中心找矿前景较大,有规模的磁异常区大多埋深在50~120 m之间,为下一步地质找矿钻探验证提供了有效的基础。同时,该勘查方法可为中国IOCG型铁矿找矿工作提供参考依据。     

A note on “Origin of components in Chilean thermal waters” by

Risacher et al. (2011) have presented voluminous data on thermal waters of Chile that is quite appreciable; however, their work still falls short on several counts. The most notable shortcoming of the work is the presentation and treatment of data. The interpretations are based on questionable premises (viz., extent of seawater intrusion) and considerations (viz., using average chemical composition of rock types for geochemical modeling, considering volcanic rocks as the only rock type in contact with the geothermal fluids) and assumptions not always substantiated by facts (with proper references) could have been corroborated. Use of Cl/Br ratio for discrimination purpose is unconvincing, considering the uncertainty in the measurement of low (<1 mg/L) Br concentration.     

Eutrephoceras subplicatum (Steinmann, 1895) is a junior synonym of Eutrephoceras dorbignyanum (Forbes in Darwin, 1846) (Cephalopoda, Nautiloidea) from the Maastrichtian Quiriquina Formation of Chile

Nautilus subplicatusSteinmann, 1895 is a latest Cretaceous species of nautiloid which is common in southern South America (Chile, Argentina) and the Antarctic Peninsula and which is best assigned to the genus EutrephocerasHyatt, 1894. Nautilus dorbignyanusForbes in Darwin, 1846 and Nautilus valenciennii Hupé in Gay, 1854 are here considered to be senior synonyms which later authors have apparently overlooked. The type material of these two taxa is reillustrated. On the basis of this and additional material it is demonstrated that only a single nautiloid species occurs in the Quiriquina Formation of late Maastrichtian age. For this we propose to use N. dorbignyanus as the oldest available name.     

The nature of the Palaeozoic oceanic basin at the southwestern margin of Gondwana and implications for the origin of the Chilenia terrane (Pichilemu region,central Chile)

The Coastal Accretionary Complex of central Chile constitutes the product of early Carboniferous to Late Triassic subduction at the rear of Chilenia, a continental terrane likely derived from Laurentia and accreted to southwestern margin of Gondwana during the Mid to Late Devonian. The complex contains basaltic metavolcanic sequences of the subducted oceanic lithosphere accreted to the active margin. In this paper, we address the tectonic setting of these rocks by means of a geochemical study in the coastal area of Pichilemu region, central Chile. The accreted fragments of oceanic crust occupy different structural levels, exhibit variable metamorphic grade, and have geochemical fingerprints that reveal a compositional heterogeneity of the subducted oceanic crust. The amphibolites have N to E-MORB compositions. Greenschist units include N-MORB and E-MORB transitional to OIB, and blueschists and greenschists interleaved within a single metavolcanosedimentary sequence have OIB signatures. Neodymium isotopic systematics indicate depleted and enriched mantle sources, whereas strontium isotopic systematics indicate seawater/rock interaction. The variety of rocks suggests formation in an oceanic setting characterized by shallow and deep mantle sources, such as plume-influenced ridge. Based on the geological, petrological, geochemical, and isotopic characteristics, we propose that the metavolcanic protoliths of the Pichilemu region formed relatively close to the western margin of the Chilenia terrane during the initial stage (late Cambrian–Early Devonian) of seafloor development and drifting of this continental block. Geochemical similarities with oceanic units accreted to the active margin south of the Pichilemu region indicate a regional pattern of the oceanic crust subducted under the Palaeozoic Chilean margin between, at least, 34°S and 39°S latitude, strongly supporting the activity of a mantle plume. This, in turn, can be correlated with the location of the Pacific plume generation zone in early Palaeozoic era, corroborating a Laurentian origin for the Chilenia terrane.     

Lithospheric Origin of Oligocene-Miocene Magmatism in Central Chile: U-Pb Ages and Sr-Pb-Hf Isotope Composition of Minerals

Establishing the petrogenesis of volcanic and plutonic rocksis a key issue in unraveling the evolution of distinct subduction-relatedtectonic phases occurring along the South American margin. Thisis particularly true for Cenozoic times when large volumes ofmagma were produced in the Andean belt. In this study we havefocused on Oligo-Miocene magmatism in central Chile at 33°S.Our data include field and petrographic observations, whole-rockmajor and trace element analyses, U–Pb zircon dating,and Pb, Sr, and Hf isotope analyses of plagioclase, clinopyroxene,and zircon mineral separates. Combined with earlier dating resultsthe new zircon ages define a 28·8–5·2 Maperiod of plutonic and volcanic activity that ceased as a consequenceof flattening subduction of the Nazca–Farallon plate.Rare earth elements patterns are variable, with up to 92 timeschondrite concentrations for light rare earth elements yielding(La/Yb)_N between 3·6 and 7·0, and an absence ofEu anomalies. Initial Pb isotope signatures are in the rangeof 18·358–19·023 for ²⁰⁶Pb/ ²⁰⁴Pb, 15·567–15·700for ²⁰⁷Pb/ ²⁰⁴Pb and 38·249–39·084 for ²⁰⁸Pb/²⁰⁴Pb. Initial ⁸⁷Sr/ ⁸⁶Sr are mostly in the range of 0·70369–0·70505,with two more radiogenic values at 0·7066. Initial Hfisotopic compositions of zircons yield exclusively positiveHf_i ranging between + 6·9 and + 9·6. The newlydetermined initial isotope characteristics of the Oligo-Miocenemagmas suggest that the mantle source lithologies are differentfrom both those of Pacific mid-ocean ridge basalt and oceanisland basalt, plotting in the field of reference values forsubcontinental lithospheric mantle, characterized by moderatelarge ion lithophile element–high field strengh elementdepletion and high ²³⁸U/ ²⁰⁴Pb. A Hf model age of 2 Ga is estimatedfor the formation of the subcontinental mantle–continentalcrust assemblage in the region, suggesting that the initialSr and Pb isotope ratios inferred for the source of the Oligo-Mioceneparental magmas are the result of later Rb and U enrichmentcaused by mantle metasomatism. A time-integrated model Rb/Srof 0·039 and µ 16 are estimated for the sourceof the parental magmas, consistent with ratios measured in peridotitexenoliths from continental areas. Evolution from predominant(>90%) basaltic–gabbroic to andesitic–dioriticmagmas seems to involve a combination of (1) original traceelement differences in the metasomatized subcontinental mantle,(2) different degrees of partial melting and (3) fractionalcrystallization in the garnet- and spinel-peridotite stabilityfields. The genesis of more differentiated magmas reaching rhyolitic–graniticcompositions most probably also includes additional crystalfractionation at both shallow mantle depths and within the crust,possibly leading to some very minor assimilation of crustalmaterial. KEY WORDS: calc-alkaline magmatism; Oligo-Miocene; U–Pb dating; Sr–Pb–Hf isotopes; central Chile     

Variations in the quantity and composition of seston from an estuary in southern Chile on different temporal scales

Estuaries are characterised by highly variable environmental conditions largely driven by tidal and atmospheric forces. This study investigates variation in the physical environment and the composition of the seston on various temporal scales in the Quempillén estuary, southern Chile. The water column was sampled throughout the tidal cycle at various times of the year. Total particulate matter, particulate inorganic matter, particulate organic matter, particle numbers, total particle volume, proximate biochemical composition and energy content of the seston, chlorophyll a and chloropigments were routinely measured. In each of the months in which sampling took place, two or three tidal cycles were examined. The information not only helps to explain the dynamics of the estuary, but is essential for an understanding of the physiology and ecology of the suspension-feeders which exploit the seston as a food source, the most dominant being the gastropod Crepipatella dilatata. Temperature and salinity were generally highest during summer, but seston quality, defined by energy content and biochemical composition (lipid, protein and carbohydrate) was higher at the end of winter and during spring. Chlorophyll a values were greatest in late spring (November). Many of the variables studied changed frequently according to the phase of the tidal cycle, and in several cases significant differences were observed among tidal cycles from the same month of the same year. In general the variables measured did not exhibit consistent patterns linked to the tidal cycle, possibly because any such patterns were masked by atmospheric conditions (wind and rain) that dominate the region and greatly influence the estuary. The quantity and quality of the seston available to suspension-feeders is largely determined by these atmospheric forces, which cause an influx of terrigenous material from adjacent areas and also resuspend bottom sediment. These effects are magnified by the shallowness of the estuary (<2 m depth). The food supply for C. dilatata and other suspension-feeders therefore varies on temporal scales varying from hourly (tidal cycle) to daily/weekly (atmospheric forces) to monthly (seasonal influences), but inhibition of feeding by low salinity sometimes limits the ability of C. dilatata to exploit fully the available organic matter.     

Spatial and temporal variability of microplankton and detritus, and their export to the shelf sediments in the upwelling area off Concepción, Chile (∼36°S), during 2002-2005

Seasonal variations in diversity and biomass of diatoms, tintinnids, and dinoflagellates and the contribution of microplankton and faecal material to the vertical flux of particulates were investigated at one time series station T (station 18) between 2002 and 2005 and at a grid of stations during November 2004 in the coastal and oceanic area off Concepción (36°S), Chile. The variations were analysed in relation to water column temperature, dissolved oxygen, nutrient concentration, offshore Ekman transport, and chlorophyll-a concentration. Abundance was estimated as cell numbers per litre and biomass in terms of biovolume and carbon units.A sharp decrease with depth was observed in the abundance of both phytoplankton and microzooplankton during the whole annual cycle; over 70% of their abundance was concentrated in the upper 10 m of the water column. Also, a clear seasonality in microplankton distribution was observed at station T, with maxima for diatoms, tintinnids, and dinoflagellates every summer (centred on January) from 2002 to 2005.On the grid of stations, the maximum integrated (0-50 m) micro-phytoplankton abundances (>1 × 10⁹ cells m⁻²) occurred at the coastal stations, an area directly influenced by upwelling. A similar spatial distribution was observed for the integrated (0-200 m) faecal carbon (with values up to 632 mg C m⁻²). Tintinnids were distributed in all the first 300 miles from the coast and dinoflagellates were more abundant in oceanic waters.At station T, the average POC export production (below 50 m depth) was 16.6% (SD = 17%; range 2-67%; n = 16). The biological-mediated fluxes of carbon between the upper productive layer and the sediments of the continental shelf off Concepción depend upon key groups of phytoplankton (Thalassiosira spp., Chaetoceros spp.) and zooplankton (euphausiids) through the export of either cells or faecal material, respectively.     

Seasonal and inter-annual variation of mesozooplankton in the coastal upwelling zone off central-southern Chile

Zooplankton sampling at Station 18 off Concepción (36°30′S and 73°07′W), on an average frequency of 30 days (August 2002 to December 2005), allowed the assessment of seasonal and inter-annual variation in zooplankton biomass, its C and N content, and the community structure in relation to upwelling variability. Copepods contributed 79% of the total zooplankton community and were mostly represented by Paracalanus parvus, Oithona similis, Oithona nana, Calanus chilensis, and Rhincalanus nasutus. Other copepod species, euphausiids (mainly Euphausia mucronata), gelatinous zooplankton, and crustacean larvae comprised the rest of the community. Changes in the depth of the upper boundary of the oxygen minimum zone indicated the strongly seasonal upwelling pattern. The bulk of zooplankton biomass and total copepod abundance were both strongly and positively associated with a shallow (<20 m) oxygen minimum zone; these values increased in spring/summer, when upwelling prevailed. Gelatinous zooplankton showed positive abundance anomalies in the spring and winter, whereas euphausiids had no seasonal pattern and a positive anomaly in the fall. The C content and the C/N ratio of zooplankton biomass significantly increased during the spring when chlorophyll-a was high (>5 mg m⁻³). No major changes in zooplankton biomass and species were found from one year to the next. We concluded that upwelling is the key process modulating variability in zooplankton biomass and its community structure in this zone. The spring/summer increase in zooplankton may be largely the result of the aggregation of dominant copepods within the upwelling region; these may reproduce throughout the year, increasing their C content and C/N ratios given high diatom concentrations.