The petroleum generation potential and effective oil window of humic coals related to coal composition and age

A worldwide data set of more than 500 humic coals from the major coal-forming geological periods has been used to analyse the evolution in the remaining (Hydrogen Index, HI) and total (Quality Index, QI) generation potentials with increasing thermal maturity and the ‘effective oil window’ (‘oil expulsion window’). All samples describe HI and QI bands that are broad at low maturities and that gradually narrow with increasing maturity. The oil generation potential is completely exhausted at a vitrinite reflectance of 2.0–2.2%R_o or T_max of 500–510 °C. The initial large variation in the generation potential is related to the original depositional conditions, particularly the degree of marine influence and the formation of hydrogen-enriched vitrinite, as suggested by increased sulphur and hydrogen contents. During initial thermal maturation the HI increases to a maximum value, HI_max. Similarly, QI increases to a maximum value, QI_max. This increase in HI and QI is related to the formation of an additional generation potential in the coal structure. The decline in QI with further maturation is indicating onset of initial oil expulsion, which precedes efficient expulsion. Liquid petroleum generation from humic coals is thus a complex, three-phase process: (i) onset of petroleum generation, (ii) petroleum build-up in the coal, and (iii) initial oil expulsion followed by efficient oil expulsion (corresponding to the effective oil window). Efficient oil expulsion is indicated by a decline in the Bitumen Index (BI) when plotted against vitrinite reflectance or T_max. This means that in humic coals the vitrinite reflectance or T_max values at which onset of petroleum generation occurs cannot be used to establish the start of the effective oil window. The start of the effective oil window occurs within the vitrinite reflectance range 0.85–1.05%R_o or T_max range 440–455 °C and the oil window extends to 1.5–2.0%R_o or 470–510 °C. For general use, an effective oil window is proposed to occur from 0.85 to 1.7%R_o or from 440 to 490 °C. Specific ranges for HI_max and the effective oil window can be defined for Cenozoic, Jurassic, Permian, and Carboniferous coals. Cenozoic coals reach the highest HI_max values (220–370 mg HC/g TOC), and for the most oil-prone Cenozoic coals the effective oil window may possibly range from 0.65 to 2.0%R_o or 430 to 510 °C. In contrast, the most oil-prone Jurassic, Permian and Carboniferous coals reach the expulsion threshold at a vitrinite reflectance of 0.85–0.9%R_o or T_max of 440–445 °C.     

泰安市地下水开发利用中的水环境问题及对策

以泰安市为例,论述了地下水开发利用中出现的区域地下水位下降、地下水资源衰竭、地下水水质恶化、地面沉降、地面裂缝和地面塌陷等水环境问题,并提出了保护对策与建议.     

Hydraulic and sedimentary controls on the availability and use of Atlantic salmon (Salmo salar) spawning habitat in the River Dee system, north-east Scotland

The hydraulic and sedimentary characteristics of the spawning habitat of Atlantic salmon (Salmo salar) in tributary and mainstem locations in a river system in north-east Scotland are described. Salmon used spawning sites with a relatively wide range in sediment characteristics, although measures of central tendency were all in the gravel (2–64 mm) size-class. The dominant factor differentiating the sediment characteristics of study sites was the level of fine sediment, which accounted for significant differences between tributary and mainstem samples. The ranges of depth and velocity in areas used for spawning by salmonids were found to be similar in all tributary study sites. However, due to the interdependence of depth and velocity, major differences were observed between tributary and mainstem study sites in that spawning in larger streams tended to be associated with deeper, faster flowing water. Spawning locations were shown to have similar Froude number, despite different sized streams and species of salmonid. Due to its dimensionless nature and significance in characterising flow hydraulics, the Froude number is proposed as a potentially useful variable for describing the habitat of aquatic organisms.     

Qualitätsanforderungen an Oberflächengewässer: Zielvorgaben,Qualitätsziele und chemische Gewässergüteklassifizierung

Quality Requirements for Fresh Waters: Water Quality Targets, Water Quality Objectives, and Chemical Water Quality Classification In the Federal Republic of Germany, water quality requirements for the protection of inland surface waters against hazardous substances are formulated on the basis of a quality targets derivation concept developed jointly by the Federal Government and the Federal States. The quality requirements were termed “water quality targets” in order to make it clear that the values derived are orientational values rather than legally binding limit values. The international comparison of quality requirements for surface waters shows that, on the whole, the national quality targets ensure a high level of protection. According to present scientific knowledge, impairments of uses, such as supply of drinking water, or risks to aquatic communities need not to be expected if the quality targets are complied with. A comparison of water quality data with the water quality targets makes it possible, on the one hand, to identify those substances whose inputs must be further reduced; on the other hand, it also shows that, for a number of substances, there is no need at present for concern over their adversely water quality. A further differentiation of the aquatic hazard potential of pollutants allows a water quality classification system to be developed on the basis of the quality targets derivation concept. The basic elements of this water quality classification system are presented, and its application is explained by way of examples.     

Transformation of arsenic compounds in modern intertidal sediments of Iriomote Island, Japan

The arsenic accumulation process in intertidal sediments of Iriomote Island, Japan, is analyzed as a naturally balanced arsenic-fixation system. Major and minor element chemistry is analyzed by X-ray fluorescence photometry, mineralogy is investigated by X-ray diffractometry, and four arsenic compounds are characterized by hydrogen-generated atomic absorption photometry. It is found that arsenic is accumulated by iron hydroxides/oxides precipitated following the decomposition of humic acids in the shallower sediment, and is subsequently incorporated into iron sulfide minerals at depth. The arsenic is immobile during incorporation into arsenic-bearing phases, suggesting that arsenic is unlikely to be released into the porewater under natural conditions in early diagenesis. The formation and decomposition of arsenic-bearing organic compounds appear to be associated with the formation and decomposition of arsenic in oxyhydroxides/oxides, suggesting that microbial activity may play an important role in controlling the behavior of arsenic and arsenic-bearing phases in the sediment column.     

世界水产品绿色养殖比较研究及对中国启示

当前全球渔业捕捞量已接近顶峰局势,水产养殖发展面临巨大环境压力,水产品绿色养殖能满足消费者对优质蛋白需求的同时,还能有效缓解生态问题,保证食品质量安全。水产品养殖绿色发展已成为世界各国的共识,渔业发达国家在一定程度上已形成较完善的绿色水产养殖体系。文章基于全球水产业发展现状和趋势,通过研究欧盟、美国和日本水产品绿色养殖的相关经验,最后结合中国水产养殖业发展现状,提出在建立严格认证标准的基础上,国内政府应加强对“绿色水产品”消费的正确引导;借鉴别国对渔业可持续发展的政策和管理制度;注重关键科学技术的研发,做到产学结合;保障资金的有效投入等相关政策建议。     

池塘养殖刺参安全度夏技术研究

文章概述夏季池塘养殖刺参死亡症状和灾情特点,分析刺参死亡原因主要包括池水盐度骤降、池水温度升高、池水pH值下降、池水分层、有机污染和刺参自身原因。在此基础上,提出池塘养殖刺参安全度夏的技术措施,主要包括科学合理选择养殖地址、规范池塘建设、做好度夏前准备工作、水质管理、及时清除水草和大型藻类、采取降温措施以及补充营养等,涉及大量具体操作方法,具有科学性和实用性。     

Sunlight Degradation of Aquatic Humic Substances Abbau von Huminstoffen unter dem Einfluß von Sonnenlicht

Coloured bog water and an aqueous solution of fulvic acid were exposed to natural sunlight. Up to 67% reduction in colour and 32% reduction in DOC concentration were measured after 12 days exposure. Colour bleaching and reduction in ultraviolet light absorbance were independent of added preservatives. The high molecular weight fraction of dissolved organic matter was most reduced in concentration while substances with low molecular weight increased. The reduction in absorbance (λ = 254 nm) per DOC was most significant for substances with high molecular weight. The final concentration of DOC was highest in samples where microbial activity was suppressed.     

Patterns of dissolved organic matter in subarctic peatlands

Samples of water from poor to very rich fens in the Schefferville region of subarctic Quebec revealed strong spatial and temporal variations in dissolved organic carbon (DOC), ranging from 2 to 40 mg 1^?1. Concentrations of DOC tend to increase during the summer and decrease in the autumn, at most sites, which probably reflects increased plant tissue decomposition and higher rates of evapotranspiration. Principal components analysis revealed that DOC is strongly associated with Fe, NO^?₃-N and NO^?₂-N, but essentially independent of other chemical properties of the peat water, such as pH, Ca, Mg, K, P, and NH⁺₄-N. Based on observed concentrations of DOC and estimates of summer runoff (June to September), export of DOC from four peatlands ranges from 1·1 to 4·9 gCm^?2, with the lowest values for peatlands underlain by dolomite. Molecular weight fractionation of four samples revealed significant differences in the dissolved organic matter (DOM), with the largest fractions (GF/C to 10 000 nmw) being dominant in the more acid samples. The ratio of absorbance at 400 and 600 nm wavelengths (E₄:E₆) has been used as a simple indicator of differences in DOM type, ranging from 3 to 15. There is a strong seasonal pattern of increasing E₄:E₆ ratio during the summer at many sites, though this ratio is essentially independent of other chemical properties of peat waters.     

云南临沧地区帮卖盆地含铀煤中锗矿的研究

帮卖盆地是一个不对称山间向斜盆地,其基底为海西·燕山期(γ~3_4-γ~2_5)花岗岩体。盖层为新第三纪的含煤碎屑岩。锗矿体大部分存在于N_1~2煤层中。含铀煤主要为变质程度低的褐煤,属于半暗-半亮煤、暗亮煤及亮暗煤。锗在煤中的存在形式:1.主要为腐植酸锗络合物及锗的有机化合物;2.一部分呈吸附状态;3.极少数呈类质同象。