近30年来耕地养老保障功能的时空演变及政策启示

厘清耕地养老保障功能的时空演变,为新时代农村土地保障功能提供科学判断。把拥有承包权的耕地看作农户的一项资产,利用1986—2015年农村固定观察点中近61万份农户资料,分别从全国和省级尺度揭示耕地养老保障功能的演变规律,为完善农村养老保障体系提供参考。结果显示：按1986年不变价,全国层面上,人均耕地养老保障价值从550元/年降至150元/年,研究期内降幅达到72%。20世纪80年代,农民依靠承包耕地能够满足家庭老年居民的养老支出;1994年其价值已无法支撑老年居民消费,此后养老需求的缺口不断扩大。省际层面上,研究期内各省份耕地的养老保障价值均呈现下降趋势,且省际间存在明显差异;养老需求的缺口不断扩大,其中东南沿海、长江沿线地区尤为突出。耕地养老假说已失去其基本论据,依靠耕地无法满足农村老年居民的养老支出。农村养老保障必须建立在公共社会保障体系的基础上,而不能再指望农户家庭拥有的少量耕地,政府应加强农村养老服务的建设。     

Determination of nitrophenols,diaminotoluenes, and chloroaromatics in ammunition wastewater

Methods for the determination of three compound classes, i. e. diaminotoluenes, nitrophenols, and chloroaromatics in groundwater of a former ammunition plant are reported. Diaminotoluenes were extracted by discontinuous liquid/liquid-, nitrophenols by continuous liquid/liquid-extraction using dichloromethane, and chloroaromatics by solid-phase extraction. These compound classes may be analyzed by gas chromatography (GC) or gas chromatography coupled to mass spectrometry (GC/MS) without derivatization or after derivatization with N-methyl-bis(trifluoroacetamide) (MBTFA) or heptafluorobutyric anhydride (HFBA) in the case of diaminotoluenes and HFBA or acetic anhydride in the case of nitrophenols. An atomic emission detector (AED) coupled to a gas chromatograph may be employed for the analysis of chloroaromatics. High selectivity can be achieved using the characteristic wavelengths of chlorine. A variety of these compounds were identified and quantified in a groundwater sample from the former ammunition plant Elsnig (Saxony, Germany). Concentrations were in the lower ppb range. Thus, dichlorobenzenes which may have been used as substituents at the end of World War II could be identified in groundwater samples at this site.     

Laborative Untersuchungen zur Beschreibung des Migrationsverhaltens sprengstofftypischer Verbindungen in Porengrundwasserleitern

Laboratory Experiments for Describing the Migration of Explosives in Sandy Aquifers Leaching the munition residues from the former explosive production site Elsnig in the Upper Elbe Valley (Saxony, Germany) resulted in an undefined plume of groundwater contaminated by nitroaromatics and nitroamines approaching important drinking water resources. Laboratory experiments were carried out to investigate transport and fate phenomena of such substances in aquifer materials. Specific solute storage and migration parameters for modelling the subsurface migration processes were obtained from steady state experiments in soil cores used as 0-dimensional reactors and from dynamic breakthrough curves in soil columns. Using the 0-dimensional reactor tests we focused on isotherm estimation. Sorption was found to be reflected best by Freundlich isotherms for concentrations of nitroaromatics less than 10 mg L^?1 and low organic carbon content in the tested subsurface material. TNT-adsorption was slow and strongly correlated with soil permeability. Preliminary kinetic measurements revealed sorption equilibrium after two days. RDX-adsorption was low. All sorption experiments were conducted under non-sterile and aerobic conditions. Microbial activity was controlled by measuring the enzyme activity and the biomass in water and soil samples. After steady state experiments in the 0-dimensional reactors, products initiated by biodegradation of explosives such as aminonitrotoluenes were found. Based on literature, degradation was estimated and correlated with soil texture. For five components, different retardation was observed depending on soil texture by using native groundwater samples in the columns. Specially designed reactor facilities and soil column installations with temperature and flux control as well as on-line measurements of pH, pE, and conductivity were applied. Concentrations of contaminants were analysed both by high performance liquid chromatography and thin layer chromatography. Photolytic reactions have been prevented. Based on all these laboratory experiments, sorption, degradation, and retardation parameters of trinitrotoluene (TNT), hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX), dinitrobenzene (DNB), dinitrotoluene (DNT), and mononitrotoluene (MNT) in Elsnig sandy aquifers were estimated.     

Heavy Metal Load of Sediments of the River Gurk (Carinthia/Austria) — Merits and Limitations of Sequential Leaching Schwermetallbelastung des Sediments der Gurk in Kärnten — Vorzüge und Einschränkungen sequentieller Löseverfahren

By means of the analysis of sediments cored in the small river Gurk (Carinthia/Austria), the input of Ag, Cd, Ce, Cr, Hg, La, Mo, Ni, V, and W from a chemical industrial plant could be detected. To estimate the actual load, and to obtain data for comparison with other sites, both unsieved fine sediments and sediments sieved to 20 μm were investigated from the same cores. Environmental mobilities of toxic heavy metals (Co, Cr, Cu, Ni, Zn) have been shown by sequential leaching following Tessier/Förstner. In the last step, HNO₃ leaches a purely geogenic fraction, which is fairly constant along the investigated river. Whereas the additional Cr from the input of the chemical plant is mainly found in the oxalate-leachable fraction, short-time-load to unpolluted sediments in the laboratory is found mainly in hydroxylamine/acetic acid. Both is due to the high affinity of Cr to Fe- and Mn-oxides. Adsorption/desorption experiments reveal that the low carbonate content of the Gurk sediments increases the importance of Fe/Mn-oxides for the sorption of Cr compared to other samples containing carbonate. The Ni-load was primarily found in weak-acid-leachable and oxalate-leachable fractions. Similarly, the oxalate-leachable fraction is dominant for adsorption of other metals and phosphorus. Other interelement relationships among the amounts leached, which are attributable partly to carbonate-, silicate-, organic or coating phases, have been found by means of factor analyses together with marker fractions for each type.     

A mapping of the electron localization function for the silica polymorphs: evidence for domains of electron pairs and sites of potential electrophilic attack

The electron localization function, η, evaluated for first-principles geometry optimized model structures generated for quartz and coesite, reveals that the oxide anions are coordinated by two hemispherically shaped η-isosurfaces located along each of the SiO bond vectors comprising the SiOSi angles. With one exception, they are also coordinated by larger banana-shaped isosurfaces oriented perpendicular to the plane centered in the vicinity of the apex of each angle. The hemispherical isosurfaces, ascribed to domains of localized bond-pair electrons, are centered ～0.70 Å along the bond vectors from the oxide anions and the banana-shaped isosurfaces, ascribed to domains of localized nonbonding lone-pair electrons, are centered ～0.60 Å from the apex of the angle. The oxide anion comprising the straight SiOSi angle in coesite is the one exception in that the banana-shaped isosurface is missing; however, it is coordinated by two hemispherically shaped isosurfaces that lie along the bond vectors. In the case of a first-principles model structure generated for stishovite, the oxide anion is coordinated by five hemispherically shaped η-isosurfaces, one located along each of the three SiO bond vectors (ascribed to domains of bonding-electron pairs) that are linked to the anion with the remaining two (ascribed to domains of nonbonding-electron pairs) located on opposite sides of the plane defined by three vectors, each isosurface at a distance of ～0.5 Å from the anion. The distribution of the five isosurfaces is in a one-to-one correspondence with the distribution of the maxima displayed by experimental Δρ and theoretical ??²ρ maps. Isosurface η maps calculated for quartz and the (HO) ₃ SiOSi(OH) ₃ molecule also exhibit maxima that correspond with the (3,?3) maxima displayed by distributions of ??²ρ. Deformation maps observed for the SiOSi bridges for the silica polymorphs and a number of silicates are similar to that calculated for the molecule but, for the majority, the maxima ascribed to lone-pair features are absent. The domains of localized nonbonding-electron pair coordinating the oxide anions of quartz and coesite provide a basis for explaining the flexibility and the wide range of the SiOSi angles exhibited by the silica polymorphs with four-coordinate Si. They also provide a basis for explaining why the SiO bond length in coesite decreases with increasing angle. As found in studies of the interactions of solute molecules with a solvent, a mapping of η-isosurfaces for geometry-optimized silicates is expected to become a powerful tool for deducing potential sites of electrophilic attack and reactivity for Earth materials. The positions of the features ascribed to the lone pairs in coesite correspond with the positions of the H atoms recently reported for an H-doped coesite crystal.     

广州莲花山的人工丹霞地貌和旅游开发

通过实地考察,概述广州番禺莲花山与粤北丹霞山地质地貌的异同,从丹霞地貌角度阐述这座古石矿场“人工无意夺天工”形成的陡崖,岩洞,石墙,石巷,岩湖,石柱,石门,石桥等人工丹霞奇观,并对这座以全国罕有古石矿场为主景的莲花山旅游区的进一步开发,提出了讨论意见。     

新构造运动对吐鲁番地区古遗址的影响

新疆吐鲁番地区新构造运动活跃,但该地区新构造运对古遗址影响的研究还处于发展阶段。结合该地区新构造运动背景,以苏公塔、交河故城为代表性古遗址进行病害调查,对病害成因进行分析,基本查明该地区新构造运动是影响古遗址规划及稳定性的主要因素,即:①交河故城所在的台地、沟谷及街道、房屋墙壁走向基本为NW向、NE向,推测其本身就受到该方向上地质构造的控制;②因受呈100°~110°走向的肯德克逆断裂-背斜影响,苏公塔塔身及交河故城崖体广泛发育NW向裂隙。     

Determination of Polar Organic Pollutants in Aqueous Samples of Former Ammunition Sites in Lower Saxony by Means of HPLC/Photodiode Array Detection (HPLC/PDA) and Proton Nuclear Magnetic Resonance Spectroscopy ( 1H-NMR)

Leachate, ground-, and surface water from former ammunition sites and areas which are known to be contaminated by nitroaromatic compounds in Lower Saxony (Germany) were investigated in order to identify and quantify acidic nitroaromatic compounds (e.g., nitrobenzoic acids, aminonitrobenzoic acids, nitrophenols, and nitrocresols). Acidic and neutral nitroaromatic compounds were enriched by solid-phase extraction (SPE) on a polystyrenedivinylbenzene copolymer and routinely screened for acidic compounds by means of HPLC/photodiode array detection (HPLC/PDA). Qualitative and quantitative results obtained in this way were corroborated by proton nuclear magnetic resonance spectroscopy (¹H-NMR). Validation data for the quantification procedure using this technique are given. The results show that all samples contaminated with 2,4,6-trinitrotoluene (TNT) and related compounds are also contaminated by acidic nitroaromatic compounds (e.g., 2,4-dinitrobenzoic acid, 3,5-dinitrophenol, and especially with 2-amino-4,6-dinitrobenzoic acid) in the μg/L range. This current work shows that 1 H-NMR allows the quantitative determination of protoncarrying analytes in mixtures after solid-phase extraction down to the upper ng/L range after addition of an internal standard to the SPE extract. This is even possible when reference compounds are not commercially available.     

丽江高美古的夜天光亮度

１９９６年１月～１９９８年３月,我们用光电方法测定了丽江高美古在Ｂ、Ｖ两个波段的夜天光亮度。为便于比较,在１９９６年１月还测定了云南天文台凤凰山台址的夜天光亮度。本文给出了观测结果,同时也列出了世界上一些天文台站的数据以供参考。     

丽江高美古大气透明度的测定

１９９６年１月～１９９８年３月,我们用光电方法测定了丽江高美古在Ｂ、Ｖ两个波段的大气消光系数。为便于比较,在１９９６年１月还测定了云南天文台凤凰山台址的大气消光系数。本文给出了观测结果,同时也列出了世界上一些天文台站的数据以供参考。