Evolution of the fogwater composition in Strasbourg (France) from 1990 to 1999

The chemical composition of fogwater has been studied in the city of Strasbourg (France) from 1990 to 1999. During these years, fogwater samples have been collected and analysed for major ions and trace metals. This paper reports on the analysis of the collected dataset. The analysis revealed a significant decrease in acidity of approximately one pH unit over the course of the study. This decrease in acidity appears to be linked to a decrease in SO_2(g) and the resulting SO₄²⁻. Trace metal concentrations have also strongly decreased over the 10-year period. Pb concentrations, following the elimination of leaded gasoline, decreased by more than one order of magnitude.     

Crustal structure of the Ruby Mountains and southern Carlin Trend region, Nevada, from magnetotelluric data

We have collected about 150 magnetotelluric (MT) soundings in northeastern Nevada in the region of the Ruby Mountains metamorphic core complex uplift and southern Carlin mineral trend, in an effort to illuminate controls on core complex evolution and deposition of world-class gold deposits. The region has experienced a broad range of tectonic events including several periods of compressional and extensional deformation, which have contributed to the total expression of electrical resistivity. Most of the soundings reside in three east–west profiles across increasing degrees of core uplift to the north (Bald Mountain, Harrison Pass, and Secret Pass latitudes). One short cross-line was also taken to assess an east–west structure to the north of the northern profile. Model resistivity cross-sections were derived from the MT data using a 2-D inversion algorithm, which damps departures of model parameters from an a priori structure. Geological interpretation of the resistivity combines previous seismic, potential field and isotope models, structural and petrological models for regional compression and extension, and detailed structural/stratigraphic interpretations incorporating drilling for petroleum and mineral exploration. To first order, the resistivity structure is one of a moderately conductive, Phanerozoic sedimentary section fundamentally disrupted by intrusion and uplift of resistive crystalline rocks. Late Devonian and early Mississippian shales of the Pilot and Chainman Formations together form an important conductive marker sequence in the stratigraphy and show pronounced increases in conductance (conductivity–thickness product) from east to west. These increases are attributed to graphitization caused by Elko–Sevier era compressional shear deformation and possibly by intrusive heating. The resistive crystalline central massifs adjoin the host stratigraphy across crustal-scale, steeply dipping fault zones. The zones provide pathways to the lower crust for heterogeneous, upper crustal induced, electric current flow. Resistive core complex crust appears steeply bounded under the middle of the neighboring grabens and not to deepen at a shallow angle to arbitrary distances to the west. The numerous crustal breaks imaged with MT may contribute to the low effective elastic thickness (T_e) estimated regionally for the Great Basin and exemplify the mid-crustal, steeply dipping slip zones in which major earthquakes nucleate. An east–west oriented conductor in the crystalline upper crust spans the East Humboldt Range and northern Ruby Mountains. The conductor may be related to nearby graphitic metasediments, with possible alteration by middle Tertiary magmatism. Lower crustal resistivity everywhere under the profiles is low and appears quasi one-dimensional. It is consistent with a low rock porosity (<1 vol.%) containing hypersaline brines and possible water-undersaturated crustal melts, residual to the mostly Miocene regional extension. The resistivity expression of the southern Carlin Trend (CT) in the Pinon Range is not a simple lineament but rather a family of structures attributed to Eocene intrusion, stratal deformation, and alteration/graphitization. Substantial reactivation or overprinting by core complex uplift or Basin–Range extensional events seems likely. We concur with others that the Carlin Trend may result in part from overlap of the large Eocene Northeast Nevada Volcanic Field with Precambrian–Paleozoic deep-water clastic source rocks thickening abruptly to the west of the Pinon Range, and projecting to the north–northwest.     

Extreme climate events over northern China during the last 50 years

Climate extremes for agriculture-pasture transitional zone, northern China, are analyzed on the basis of daily mean temperature and precipitation observations for 31 stations in the period 1956-2001. Analysis season for precipitation is May-September, i.e., the rainy season. For temperature is the hottest three months, i.e., June through August. Heavy rain events, defined as those with daily precipitation equal to or larger than 50 mm, show no significant secular trend. A jump-like change, however, is found occurring in about 1980. For the period 1980-1993, the frequency of heavy rain events is significantly lower than the previous periods. Simultaneously, the occurring time of heavy rains expanded, commencing about one month early and ending one month later. Long dry spells are defined as those with longer than 10 days without rainfall. The frequency of long dry spells displays a significant (at the 99% confidence level) trend at the value of +8.3%/10a. That may be one of the major causes of the frequent droughts emerging over northern China during the last decades. Extremely hot and low temperature events are defined as the uppermost 10% daily temperatures and the lowest 10% daily temperatures, respectively. There is a weak and non-significant upward trend in frequency of extremely high temperatures from the 1950s to the mid-1990s. But the number of hot events increases as much as twice since 1997. That coincides well with the sudden rise in mean summer temperature for the same period. Contrary to that, the frequency of low temperature events have been decreasing steadily since the 1950s, with a significant linear trend of -15%/10a.     

Water-quality trends in White Rock Creek Basin from 1912-1994 identified using sediment cores from White Rock Lake reservoir, Dallas, Texas

Historical trends in selected water-quality variables from 1912 to 1994 in White Rock Creek Basin were identified by dated sediment cores from White Rock Lake. White Rock Lake is a 4.4-km² reservoir filled in 1912 and located on the north side of Dallas, Texas, with a drainage area of 259 km². Agriculture dominated land use in White Rock Creek Basin before about 1950. By 1990, 72% of the basin was urban. Sediment cores were dated using cesium-137 and core lithology. Major element concentrations changed, and sedimentation rates and percentage of clay-sized particles in sediments decreased beginning in about 1952 in response to the change in land use. Lead concentrations, normalized with respect to aluminum, were six times larger in sediment deposited in about 1978 than in pre-1952 sediment. Following the introduction of unleaded gasoline in the 1970s, normalized lead concentrations in sediment declined and stabilized at about two and one-half times the pre-1952 level. Normalized zinc and arsenic concentrations increased 66 and 76%, respectively, from before 1952 to 1994. No organochlorine compounds were detected in sediments deposited prior to about 1940. Concentrations of polychlorinated biphenyls (PCB) and DDE (a metabolite of DDT) increased rapidly beginning in the 1940s and peaked in the 1960s at 21 and 20 µg kg^-1, respectively, which is coincident with their peak use in the United States. Concentrations of both declined about an order of magnitude from the 1960s to the 1990s to 3.0 and 2.0 µg kg^-1, respectively. Chlordane and dieldrin concentrations increased during the 1970s and 1980s. The largest chlordane concentration was 8.0 µg kg^-1 and occurred in a sediment sample deposited in about 1990. The largest dieldrin concentration was 0.7 µg kg^-1 and occurred in the most recent sample deposited in the early 1990s. Agricultural use of chlordane and dieldrin was restricted in the 1970s; however, both were used as termiticides, and urban use of chlordane continued at least until 1990. Recent use of dieldrin and aldrin, which degrades to dieldrin, has not been reported; however, increasing trends in dieldrin since the 1970s suggest recent urban use could have occurred.     

1984 年以来北京零售业空间发展趋势与特征

在采用虚拟变量对密度函数进行调整的基础上, 借助扩展方法引入时间变量构建计量经济模型测度北京零售业空间发展的分异与趋势, 并利用GIS技术研究了新型零售业的空间布局特征。结果表明:① 1984-2010 年, 近郊区零售业保持着强劲的增长势头, 增速是远郊区的近两倍, 而远郊区快于中心区, 说明中心区零售业地位的相对下降, 类似于20 世纪中期美国大都市区的发展特征。② 2000 年以来, 远郊区零售业增速下降, 近郊区小幅提升, 而中心区发展速度明显回升, 说明部分学者提出的20 世纪90 年代末期旧城区零售业“空洞化”、“边缘化”的发展趋势并未延续。③ 紧随人口的郊区化, 90 年代中期兴起的连锁超市以三环路为基础外向发展, 三、四环路和五、六环路之间数量较多, 而传统百货商店则主要布局在三环路以内。④ 以超市为代表的新型零售业空间布局呈现大分散、小集聚的特征, 没有表现出明显的等级性, 集聚区域既包括近郊人口密集区, 也包括远郊新城和城郊大型居住区。零售业的空间发展趋势与超市的空间特征共同显示, 北京应进一步提升远郊零售业的连锁化水平, 提高服务水平和质量, 促进居住与消费的空间平衡。     

长株潭地区建设用地扩张遥感时空特征分析

利用遥感、GIS一体化技术,获取长沙、株洲、湘潭3市(长株潭地区)2000年、2005年和2010年3期陆地卫星图像,提取建设用地扩张及其空间分布信息。运用扩张速度指数和强度指数分别对2000—2010年间10 a变化以及2005年为界的前后两个5 a区域建设用地时序特征进行分析;利用优势度指数分析了区域建设用地扩张的空间趋向性。结果表明:长株潭地区建设用地在不同时期都处于增长的趋势,其中前5 a建设用地扩张速度和强度都要明显高于后5 a。2000—2010年间建设用地面积增加约3.94万hm2,前后2个时期的扩张面积分别占增加总量的57.30%和42.70%。对长株潭地区建设用地扩张进行时空特征分析,认为建设用地扩张引起区域内耕地和林地在数量和空间格局上的变化,城区周围9~12 km范围内耕地极易转入建设用地;2个时期河流附近耕地流入建设用地随距离变化而呈现不同特征;前5 a城区周围林地转入建设用地强度大,距离交通用地3 km附近的林地易转入建设用地。     

Distinguishing streamflow trends caused by changes in climate,forest cover,and permafrost in a large watershed in northeastern China

Understanding how rivers respond to changes in land cover, climate, and subsurface conditions is critical for sustainably managing water resources and ecosystems. In this study, long‐term hydrologic, climate, and satellite data (1973–2012) from the Upper Tahe River watershed (2359 km²) in the Da Hinggan Mountains of northeast China were analysed to quantify the relative hydrologic effects of climate variability (system input) and the combined influences of forest cover change and permafrost thaw (system characteristics) on average annual streamflow (system response) using 2 methods: the sensitivity‐based method and the Kendall–Theil robust line method. The study period was subdivided into a forest harvesting period (1973–1987), a forest stability period (1988–2001), and a forest recovery period (2002–2012). The results indicated that the combined effects of forest harvesting and permafrost thaw on streamflow (+ 47.0 mm) from the forest harvesting period to the forest stability period was approximately twice as large as the effect associated with climate variability (+20.2 mm). Similarly, from the forest stability period to the forest recovery period, the decrease in average annual streamflow attributed to the combined effects of forest recovery and permafrost thaw (?38.0 mm) was much greater than the decrease due to climate variability (?22.2 mm). A simple method was used to separate the distinct impacts of forest cover change and permafrost thaw, but distinguishing these influences is difficult due to changes in surface and subsurface hydrologic connectivity associated with permafrost thaw. The results highlight the need to consider multiple streamflow drivers in future watershed and aquatic ecosystem management. Due to the ecological and hydrological susceptibility to disturbances in the Da Hinggan Mountains, forest harvesting will likely negatively impact ecohydrological processes in this region, and the effects of forest species transition in the forest recovery process should be further investigated.     

Likely effects of climate change on groundwater availability in a Mediterranean region of Southeastern Spain

Groundwater resources are typically the main fresh water source in arid and semi‐arid regions. Natural recharge of aquifers is mainly based on precipitation; however, only heavy precipitation events (HPEs) are expected to produce appreciable aquifer recharge in these environments. In this work, we used daily precipitation and monthly water level time series from different locations over a Mediterranean region of Southeastern Spain to identify the critical threshold value to define HPEs that lead to appreciable aquifer recharge in this region. Wavelet and trend analyses were used to study the changes in the temporal distribution of the chosen HPEs (≥20 mm day^?1) over the observed period 1953–2012 and its projected evolution by using 18 downscaled climate projections over the projected period 2040–2099. The used precipitation time series were grouped in 10 clusters according to similarities between them assessed by using Pearson correlations. Results showed that the critical HPE threshold for the study area is 20 mm day^?1. Wavelet analysis showed that observed significant seasonal and annual peaks in global wavelet spectrum in the first sub‐period (1953–1982) are no longer significant in the second sub‐period (1983–2012) in the major part of the ten clusters. This change is because of the reduction of the mean HPEs number, which showed a negative trend over the observed period in nine clusters and was significant in five of them. However, the mean size of HPEs showed a positive trend in six clusters. A similar tendency of change is expected over the projected period. The expected reduction of the mean HPEs number is two times higher under the high climate scenario (RCP8.5) than under the moderate scenario (RCP4.5). The mean size of these events is expected to increase under the two scenarios. The groundwater availability will be affected by the reduction of HPE number which will increase the length of no aquifer recharge periods (NARP) accentuating the groundwater drought in the region. Copyright © 2016 John Wiley & Sons, Ltd.     

Pre‐ and post‐impoundment nitrogen in the lower Missouri River

Large water‐sample sets collected from 1899 through 1902, 1907, and in the early 1950s allow comparisons of pre‐impoundment and post‐impoundment (1969 through 2008) nitrogen concentrations in the lower Missouri River. Although urban wastes were not large enough to detectably increase annual loads of total nitrogen at the beginning of the 20^th century, carcass waste, stock‐yard manure, and untreated human wastes measurably increased ammonia and organic‐nitrogen concentrations during low flows. Average total‐nitrogen concentrations in both periods were about 2.5 mg/l, but much of the particulate‐organic nitrogen, which was the dominant form of nitrogen around 1900, has been replaced by nitrate. This change in speciation was caused by the nearly 80% decrease in suspended‐sediment concentrations that occurred after impoundment, modern agriculture, drainage of riparian wetlands, and sewage treatment. Nevertheless, bioavailable nitrogen has not been low enough to limit primary production in the Missouri River since the beginning of the 20^th century. Nitrate concentrations have increased more rapidly from 2000 through 2008 (5 to 12% per year), thus increasing bioavailable nitrogen delivered to the Mississippi River and affecting Gulf Coast hypoxia. The increase in nitrate concentrations with distance downstream is much greater during the post‐impoundment period. If strategies to decrease total‐nitrogen loads focus on particulate N, substantial decreases will be difficult because particulate nitrogen is now only 23% of total nitrogen in the Missouri River. A strategy aimed at decreasing particulates also could further exacerbate land loss along the Gulf of Mexico, which has been sediment starved since Missouri River impoundment. In contrast, strategies or benchmarks aimed at decreasing nitrate loads could substantially decrease nitrogen loadings because nitrates now constitute over half of the Missouri's nitrogen input to the Mississippi. Ongoing restoration and creation of wetlands along the Missouri River could be part of such a nitrate‐reduction strategy. Published 2013. This article is a U.S. Government work and is in the public domain in the USA.