Identification of physical processes inherent in artificial neural network rainfall runoff models

The emergence of artificial neural network (ANN) technology has provided many promising results in the field of hydrology and water resources simulation. However, one of the major criticisms of ANN hydrologic models is that they do not consider/explain the underlying physical processes in a watershed, resulting in them being labelled as black‐box models. This paper discusses a research study conducted in order to examine whether or not the physical processes in a watershed are inherent in a trained ANN rainfall‐runoff model. The investigation is based on analysing definite statistical measures of strength of relationship between the disintegrated hidden neuron responses of an ANN model and its input variables, as well as various deterministic components of a conceptual rainfall‐runoff model. The approach is illustrated by presenting a case study for the Kentucky River watershed. The results suggest that the distributed structure of the ANN is able to capture certain physical behaviour of the rainfall‐runoff process. The results demonstrate that the hidden neurons in the ANN rainfall‐runoff model approximate various components of the hydrologic system, such as infiltration, base flow, and delayed and quick surface flow, etc., and represent the rising limb and different portions of the falling limb of a flow hydrograph. Copyright © 2004 John Wiley & Sons, Ltd.     

A dated cave sediment record of Pleistocene transgressions on Berry Head,Southwest England

Berry Head, a limestone headland in Torbay, southwest England, exhibits a series of subaerial marine erosion platforms and raised beaches spanning an altitude range of 97 m. Solution caves on the headland show preferred horizontal development at elevations that are correlated with the marine erosion platforms, and developed in a marine/freshwater mixing zone whose position was controlled by high sea-level still-stands. Corbridge Cave in Berry Head Quarry lies below the raised beaches in Torbay, and contains evidence of three marine transgressions in the form of fine-grained marine ponding deposits with a marine microfauna. Uranium-series dating of intercalated speleothems indicates that a transgression during oxygen isotope stage 5e reached an elevation of 5.8 m OD, while an earlier transgression (probably during stage 7) reached at least 7.2 m OD. These findings are used to constrain possible interpretations of the aminostratigraphy of raised beaches in Southwest Britain, and a correlation of the Unnamed Stage of Bowen, Sykes, Reeves, Miller, Andrews, Brew and Hare with oxygen isotope stage 5e is proposed.     

Hysteresis‐based analysis of overland metal transport

Introducing a concept of equivalent mass depth of flow, this study describes the phenomenon of non‐point source pollutant (metal) transport for pavement (or overland) flow in analogy with wave propagation in wide open channels. Hysteretic and normal mass rating curves are developed for runoff rate and mass of 12 dissolved and particulate‐bound metal elements (pollutants) using the rainfall‐runoff and water quality data of the 15 × 20 m² instrumented pavement in Cincinnati, USA. Normal mass rating curves developed for easy computation of pollutant load are found to be of a form similar to Manning's, which is valid for open channel flows. Based on the hysteresis analysis, wave types for dissolution and mixing of particulate‐bound metals are identified. The analysis finds that the second‐order partial‐differential equation normally used for metal transport does not have the efficacy to describe fully the strong non‐linear phenomena such as is described for various metal elements by dynamic waves. In addition, the proportionality concept of the popular SCS‐CN concept is extended for determining the potential maximum metal mass M_p of all the 12 elements transported by a rain storm and related to the antecedent dry period (ADP). For the primary metal zinc element, M_p is found to increase with the ADP and vice versa. Copyright © 2003 John Wiley & Sons, Ltd.     

Environmental impacts from mining at Taojiang Mn ore deposit, central Hunan, China

The Taojiang Mn ore deposit was exploited in the early 1960s, and waste rocks were developed since then. Because the Mn ores were hosted within the metal-enriched black shales （Peng et al., 2004）, the continuous mining has led to the exposure of an immense quality of black shales, which might cause serious impacts on environments. The present study deals with this environmental issue with samples from the waste rocks, and from the surrounding soils and surface water. The mineralogy of the waste rock was studied using EMPA, then a large number of elements in all waste rock, soil, and water samples were analyzed at a wide range of concentrations with high accuracy using an Elan6000 ICP-MS machine at Guangzhou Institute of Geochemistry, Chinese Academy of Sciences. The waste rock is composed mostly of black shales, with minor Mn carbonates. Both black shales and Mn carbonates of the waste rock contain many sulfide minerals, mainly pyrite, with minor galena, sphalerite, chalcopyrite, and others. The waste rocks are enriched in many metals including Sc, V, Cr, Co, Ni, Fe, Mn, Cu, Zn, Pb, Th, U, Mo, Sb, Sn, Tl, and others, and the metals are mostly hosted within the sulfides. Weathering of waste rocks might cause emission of the following metals： V, Cd, Ni, Th, U, Mo, Sb, Tl, Sc, Cr, Cu, Zn, Sn, and minor Co, and Pb. The surrounding soils are highly enriched in Cr, Co, Cu, Zn, Mn, Mo, Cd, Tl, and Pb, with the enrichment factors of 2.67.3.8, 7.26, 7.27, 8.2, 5.7, 13, and 5.4, respectively. The element ratios （Rb/Cs, Fe/Mn, Nb/Zr, Hf/Zr, and Ba/Sr） and REE distribution patterns of the soils are similar to those of the waste rocks and bedrocks.     

Heavy metal contamination in the sediment of the Second Songhua River

The Second Songhua River was subjected to a large amount of untreated effluent from petrochemical industries in Jilin City in the 1960s to the 1970s. The objectives of this study were to investigate the mercury and other heavy metal contamination in the sediment of the river. The river bottom sediment was sampled from the river segment between Jilin City to Haerbin City in 2005. Total concentrations of Hg, Cd, Cu, Cr, Pb, Zn, Ni, As, Sc, and major cations （A1, Fe, Mg, Ca, K, Na） in the sediment were measured by atomic fluorescence spectrometer, ICP-MS, and ICP-OES, respectively, following digestion with various acids. We found the concentrations of most elements in the uncontaminated sediment were significantly correlated to those of Sc.     

An integrated hydrological model for rain‐induced landslide prediction

This paper describes an extension to the Combined Hydrology And Stability Model (CHASM) to fully include the effects of vegetation and slope plan topography on slope stability. The resultant physically based numerical model is designed to be applied to site‐specific slopes in which a detailed assessment of unsaturated and saturated hydrology is required in relation to vegetation, topography and slope stability. Applications are made to the Hawke's Bay region in New Zealand where shallow‐seated instability is strongly associated with spatial and temporal trends in vegetation cover types, and the Mid‐Levels region in Hong Kong, an area subject to a variety of landslide mechanisms, some of which may be subject to strong topographic control. An improved understanding of process mechanism, afforded by the model, is critical for reliable and appropriate design of slope stabilization and remedial measures. Copyright © 2002 John Wiley & Sons, Ltd.     

Momentum transport of wave zero during March: A possible predictor for the Indian summer monsoon

Analysis of monthly momentum transport of zonal waves at 850 hPa for the period 1979 to 1993, between ‡S and ‡N for January to April, using zonal (u) and meridional (v) components of wind taken from the ECMWF reanalysis field, shows a positive correlation (.1% level of significance) between the Indian summer monsoon rainfall (June through September) and the momentum transport of wave zero TM(0) over latitudinal belt between 25‡S and 5‡N (LB) during March. Northward (Southward) TM(0) observed in March over LB subsequently leads to a good (drought) monsoon season over India which is found to be true even when the year is marked with the El-Nino event. Similarly a strong westerly zone in the Indian Ocean during March, indicates a good monsoon season for the country, even if the year is marked with El-Nino. The study thus suggests two predictors, TM(0) over LB and the strength of westerly zone in the Indian Ocean during March.     

黔西南地甲病重病区与环境地球化学关系研究

贵州是我国碘缺乏病严重地区之一，特别是黔西南地区。本根据含碘量的调查，编制了贵州露头地层、地表土壤和地表水中含碘量分布图，并与地甲病患病率分布图进行对比研究。研究表明，地甲病患病率与露头地层中碘含量关系不明显，地表土壤中碘含量与地甲病患病率有一定关系，而地表水中碘含量与地甲病患病率关系较为密切，地表水中含碘量高的地区，地甲病患病率就低，反之则地甲病患病率高。     

A Laboratory and Theoretical Study on the Uptake of SO2 Gas by Large and Small Water Drops Containing Heavy Metal Ions

Laboratory experiments have been carried out to investigate the uptake of sulfur dioxide by water drops containing heavy metal ions where the metal ions serve as catalysts to oxidise the taken up S(IV) into S(VI). During the gas uptake the drops were freely suspended at their terminal velocity in the airstream of the Mainz vertical wind tunnel. Two series of experiments were carried out, one with large millimeter size water drops containing manganese or iron ions, and the other with small water drops containing manganese ions and having radii in hundreds of micron size range. The experimental results were compared against model computations using the Kronig–Brink model and the fully mixed model, modified for the case that heavy metal ions present in the liquid phase act as catalysts for the oxidising process. The results of the model calculations show that there are only small differences between the predicted gas uptake according to the two models. In addition it was found that the experimental obtained results from the uptake of SO₂ by water drops containing heavy metal ions for both, large and small water drops did agree with the model results.