Water quality data for Fall Creek,New York,USA: 1972–1995

The 33 086 ha mixed land use Fall Creek watershed in upstate New York is part of the Great Lakes drainage system. Results from more than 3500 water samples are available in a data set that compiles flow data and measurements of various water quality analytes collected between 1972 and 1995 in all seasons and under all flow regimes in Fall Creek and its tributaries. Data is freely accessible at https://ecommons.cornell.edu/handle/1813/8148 and includes measurements of suspended solids, pH, alkalinity, calcium, magnesium, potassium, sodium, chloride, nitrate nitrogen (NO3-N), sulphate sulphur (SO4-S), phosphorus (P) fractions molybdate reactive P (MRP) and total dissolved P (TDP), percent P in sediment, and ammonium nitrogen (NH4-N). Methods, sub-watershed areas, and coordinates for sampling sites are also included. The work represented in this data set has made important scientific contributions to understanding of hydrological and biogeochemical processes that influence loading in mixed use watersheds and that have an impact on algal productivity in receiving water bodies. In addition, the work has been foundational for important regulatory and management decisions in the region.     

Fully coupled elastoplastic hydro-mechanical analysis of unsaturated porous media using a meshfree method

This paper presents the first application of an advanced meshfree method, ie, the edge-based smoothed point interpolation method (ESPIM), in simulation of the coupled hydro-mechanical behaviour of unsaturated porous media. In the proposed technique, the problem domain is spatially discretised using a triangular background mesh, and the polynomial point interpolation method combined with a simple node selection scheme is adopted for creating nodal shape functions. Smoothing domains are formed on top of the background mesh, and a constant smoothed strain, created by applying the smoothing operation over the smoothing domains, is assigned to each smoothing domain. The deformation and flow models are developed based on the equilibrium equation of the mixture, and linear momentum and mass balance equations of the fluid phases, respectively. The effective stress approach is followed to account for the coupling between the flow and deformation models. Further coupling among the phases is captured through a hysteretic soil water retention model that evolves with changes in void ratio. An advanced elastoplastic constitutive model within the context of the bounding surface plasticity theory is employed for predicting the nonlinear behaviour of soil skeleton. Time discretisation is performed by adopting a three-point discretisation method with growing time steps to avoid temporal instabilities. A modified Newton-Raphson framework is designed for dealing with nonlinearities of the discretised system of equations. The performance of the numerical model is examined through a number of numerical examples. The state-of-the-art computational scheme developed is useful for simulation of geotechnical engineering problems involving unsaturated soils.     

Wetland hydroperiod classification in the western prairies using multitemporal synthetic aperture radar

Wetlands represent one of the world's most biodiverse and threatened ecosystem types and were diminished globally by about two‐thirds in the 20th century. There is continuing decline in wetland quantity and function due to infilling and other human activities. In addition, with climate change, warmer temperatures and changes in precipitation and evapotranspiration are reducing wetland surface and groundwater supplies, further altering wetland hydrology and vegetation. There is a need to automate inventory and monitoring of wetlands, and as a study system, we investigated the Shepard Slough wetlands complex, which includes numerous wetlands in urban, suburban, and agricultural zones in the prairie pothole region of southern Alberta, Canada. Here, wetlands are generally confined to depressions in the undulating terrain, challenging wetlands inventory and monitoring. This study applied threshold and frequency analysis routines for high‐resolution, single‐polarization (HH) RADARSAT‐2, synthetic aperture radar mapping. This enabled a growing season surface water extent hyroperiod‐based wetland classification, which can support water and wetland resource monitoring. This 3‐year study demonstrated synthetic aperture radar‐derived multitemporal open‐water masks provided an effective index of wetland permanence class, with overall accuracies of 89% to 95% compared with optical validation data, and RMSE between 0.2 and 0.7 m between model and field validation data. This allowed for characterizing the distribution and dynamics of 4 marsh wetlands hydroperiod classes, temporary, seasonal, semipermanent, and permanent, and mapping of the sequential vegetation bands that included emergent, obligate wetland, facultative wetland, and upland plant communities. Hydroperiod variation and surface water extent were found to be influenced by short‐term rainfall events in both wet and dry years. Seasonal hydroperiods in wetlands were particularly variable if there was a decrease in the temporary or semipermanent hydroperiod classes. In years with extreme rain events, the temporary wetlands especially increased relative to longer lasting wetlands (84% in 2015 with significant rainfall events, compared with 42% otherwise).     

The isotopic signature of monsoon conditions,cloud modes,and rainfall type

This work provides a comprehensive physically based framework for the interpretation of the north Australian rainfall stable isotope record (δ¹⁸O and δ²H). Until now, interpretations mainly relied on statistical relationships between rainfall amount and isotopic values on monthly timescales. Here, we use multiseason daily rainfall stable isotope and high resolution (10 min) ground‐based C‐band polarimetric radar data and show that the five weather types (monsoon regimes) that constitute the Australian wet season each have a characteristic isotope ratio. The data suggest that this is not only due to changes in regional rainfall amount during these regimes but, more importantly, is due to different rain and cloud types that are associated with the large scale circulation regimes. Negative (positive) isotope anomalies occurred when stratiform rainfall fractions were large (small) and the horizontal extent of raining areas were largest (smallest). Intense, yet isolated, convective conditions were associated with enriched isotope values whereas more depleted isotope values were observed when convection was widespread but less intense. This means that isotopic proxy records may record the frequency of which these typical wet season regimes occur. Positive anomalies in paleoclimatic records are most likely associated with periods where continental convection dominates and convection is sea‐breeze forced. Negative anomalies may be interpreted as periods when the monsoon trough is active, convection is of the oceanic type, less electric, and stratiform areas are wide spread. This connection between variability of rainfall isotope anomalies and the intrinsic properties of convection and its large‐scale environment has important implications for all fields of research that use rainfall stable isotopes.     

Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.     

Developing constitutive models from EPR‐based self‐learning finite element analysis

A constitutive model that captures the material behavior under a wide range of loading conditions is essential for simulating complex boundary value problems. In recent years, some attempts have been made to develop constitutive models for finite element analysis using self‐learning simulation (SelfSim). Self‐learning simulation is an inverse analysis technique that extracts material behavior from some boundary measurements (eg, load and displacement). In the heart of the self‐learning framework is a neural network which is used to train and develop a constitutive model that represents the material behavior. It is generally known that neural networks suffer from a number of drawbacks. This paper utilizes evolutionary polynomial regression (EPR) in the framework of SelfSim within an automation process which is coded in Matlab environment. EPR is a hybrid data mining technique that uses a combination of a genetic algorithm and the least square method to search for mathematical equations to represent the behavior of a system. Two strategies of material modeling have been considered in the SelfSim‐based finite element analysis. These include a total stress‐strain strategy applied to analysis of a truss structure using synthetic measurement data and an incremental stress‐strain strategy applied to simulation of triaxial tests using experimental data. The results show that effective and accurate constitutive models can be developed from the proposed EPR‐based self‐learning finite element method. The EPR‐based self‐learning FEM can provide accurate predictions to engineering problems. The main advantages of using EPR over neural network are highlighted.     

Geostatistical features of streambed vertical hydraulic conductivities in Frenchman Creek Watershed in Western Nebraska

This study evaluated the spatial variability of streambed vertical hydraulic conductivity (K_v) in different stream morphologies in the Frenchman Creek Watershed, Western Nebraska, using different variogram models. Streambed K_v values were determined in situ using permeameter tests at 10 sites in Frenchman, Stinking Water and Spring Creeks during the dry season at baseflow conditions. Measurements were taken both in straight and meandering stream channels during a 5 day period at similar flow conditions. Each test site comprised of at least three transects and each transect comprised of at least three K_v measurements. Linear, Gaussian, exponential and spherical variogram models were used with Kriging gridding method for the 10 sites. As a goodness-of-fit statistic for the variogram models, cross-validation results showed differences in the median absolute deviation and the standard deviation of the cross-validation residuals. Results show that using the geometric means of the 10 sites for gridding performs better than using either all the K_v values from the 93 permeameter tests or 10 K_v values from the middle transects and centre permeameters. Incorporating both the spatial variability and the uncertainty involved in the measurement at a reach segment can yield more accurate grid results that can be useful in calibrating K_v at watershed or sub-watershed scales in distributed hydrological models.     

基于噪声谱比法的内蒙古西部地区台站场地响应研究

利用内蒙古西部12个台站的地脉动噪声数据，采用噪声谱比法研究台站的场地响应情况。分析表明，台站场地响应按曲线形态可分为3类，且可能受地形地貌、局部构造和台基状况等条件影响。对比分析噪声谱比法与Moya方法的场地响应结果发现，场地响应曲线形态基本一致，只有极少数台站存在明显差异。结果表明，内蒙古西部区域大部分台站的台基状况总体较好，场地响应曲线较为平坦，无明显频率放大点。     

河外H2O超脉泽源及与其相关的分子谱线的观测和研究

自从在活动星系核NGC4945的视线方向上发现第一个河外H2O超脉泽源以来，迄今为止已发现了19个河外H2O超脉泽源，对与活动星系核成协和河外H2O超脉泽源及分子谱线的观测和研究是探测和研究活动星系核核区中央源，拱核气体和尘埃环性质的非常有效的工具，主要评述对河外H2O超脉泽源及与其相关分子谱线的搜索，观测和理论研究现状。