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1.
地下水资源可持续利用的一个急待解决的重要问题,是对地下水补给和更新能力的评价.利用环境同位素技术研究地下水的补给和可更新性是当前较为新颖的方法之一.在西北干旱、半干旱的隐伏岩溶地区,地下水埋藏条件复杂,常规的地质勘探方法所能提供的水文地质信息有限,环境同位素方法在研究地下水的补给及可更新能力方面发挥了优势,可对传统方法进行补充和验证.其结果表明,研究区隐伏岩溶水形成较早,且有大量现代水的混入,平均混入量为54%.说明区内隐伏岩溶水的补给和更新能力较好.环境同位素分析结果还显示,大岔河隐伏岩溶水为一相对独立、半开放的水文地质单元,其补给来源部分为流域内大气降水、地表水的补给,部分为东南部三道沟岩溶地下水的补给;根据环境同位素EPM模型计算,地下水的滞留时间为36 a.地下水储存量为1.314×108 m3; 储水系数为7.29×10-3.这一结果与传统勘探方法的计算结果基本吻合,说明环境同位素方法的实用性. 相似文献
2.
浙江省现有地下水开采潜力的分析与评价方法存在着不足,本文结合乐清市地下水资源开发利用规划实例,浅析浙江省地下水资源开采潜力分析与评价的综合影响因素. 相似文献
3.
APPLICATION OF GEOGRAPHICAL PARAMETER DATABASE TO ESTABLISHMENT OF UNIT POPULATION DATABASE 总被引:1,自引:1,他引:0
Now GIS is turning into a good tool in handling geographical, economical, and population data, so we can obtain more and more information from these data. On the other hand, in some cases, for a calamity, such as hurricane, earthquake, flood, drought etc., or a decision-making, such as setting up a broadcasting transmitter, building a chemical plant etc., we have to evaluate the total population in the region influenced by a calamity or a project. In this paper, a method is put forward to evaluate the population in such special region. Through exploring the correlation of geographical parameters and the distribution of people in the same region by means of quantitative analysis and qualitative analysis, unit population database (1km× 1km) is established. In this way, estimating the number of people in a special region is capable by adding up the population in every grid involved in this region boundary. The geographical parameters are obtained from topographic database and DEM database on the scale of 相似文献
4.
Aimed at promoting regional coalitions and expanding the approach to economic links, this paper puts forward some new concepts
such as link intensity and receiving coefficient, expounds the indexes of quantitative analysis of economic links and establishes
the quantitative-analysis model of economic links. With help of the model, this paper calculates the values of the link intensities
between Su-Xi-Chang (Suzhou-Wuxi-Changzhou) region and Shanghai, and analyzes the regional difference of the economic links. 相似文献
5.
本文作者利用IOS近似模型,计算了星际分子云条件下A型CH3CN-H2含超精细能级的碰撞跃迁速率系数。温度范围是20K-140K。为研究分子云与恒星形成区的物理、化学性质提供了有用的基础分子数据。 相似文献
6.
This study explores garnet coronas around hedenbergite, which were formed by the reaction plagioclase + hedenbergite→garnet + quartz, to derive information about diffusion paths that allowed for material redistribution during reaction progress. Whereas quartz forms disconnected single grains along the garnet/hedenbergite boundaries, garnet forms ~20‐μm‐wide continuous polycrystalline rims along former plagioclase/hedenbergite phase boundaries. Individual garnet crystals are separated by low‐angle grain boundaries, which commonly form a direct link between the reaction interfaces of the plagioclase|garnet|hedenbergite succession. Compositional variations in garnet involve: (i) an overall asymmetric compositional zoning in Ca, Fe2+, Fe3+ and Al across the garnet layer; and (ii) micron‐scale compositional variations in the near‐grain boundary regions and along plagioclase/garnet phase boundaries. These compositional variations formed during garnet rim growth. Thereby, transfer of the chemical components occurred by a combination of fast‐path diffusion along grain boundaries within the garnet rim, slow diffusion through the interior of the garnet grains, and by fast diffusion along the garnet/plagioclase and the garnet/hedenbergite phase boundaries. Numerical simulation indicates that diffusion of Ca, Al and Fe2+ occurred about three to four, four and six to seven orders of magnitude faster along the grain boundaries than through the interior of the garnet grains. Fast‐path diffusion along grain boundaries contributed substantially to the bulk material transfer across the growing garnet rim. Despite the contribution of fast‐path diffusion, bulk diffusion through the garnet rim was too slow to allow for chemical equilibration of the phases involved in garnet rim formation even on a micrometre scale. Based on published garnet volume diffusion data the growth interval of a 20‐μm‐wide garnet rim is estimated at ~103–104 years at the inferred reaction conditions of 760 ± 50 °C at 7.6 kbar. Using the same parameterization of the growth law, 100‐μm‐ and 1‐mm‐thick garnet rims would grow within 105–106 and 106–107 years respectively. 相似文献
7.
The uptake and release of trace metals (Cu, Ni, Zn, Cd, and Co) in estuaries are studied using river and sea end-member waters
and suspended particulate matter (SPM) collected from the Changjiang Estuary, China. The kinetics of adsorption and desorption
were studied in terms of environmental factors (pH, SPM loading, and salinity) and metal concentrations. The uptake of the
metals studied onto SPM occurred mostly within 10 h and reached an asymptotic value within 40 h in the Changjiang Estuary.
As low pH river water flows into the high pH seawater and the water become more alkaline as it approaches to the seaside of
estuary, metals adsorb more on SPM in higher pH water, thus, particulate phase transport of metal become increasingly important
in the seaward side of the estuary. The percentage of adsorption recovery and the distribution coefficients for trace metals
remained to be relatively invariable and a significant reduction only occurred in very high concentrations of metals (>0.1 mg L−1). The general effect of salinity on metal behavior was to decrease the degree of adsorption of Cu, Zn, Cd, Co, and Ni onto
SPM but to increase their adsorption equilibrium pH. The adsorption–desorption kinetics of trace metals were further investigated
using Kurbatov adsorption model. The model appears to be most useful for the metals showing the conservative behavior during
mixing of river and seawater in the estuary. Our work demonstrates that dissolved concentration of trace metals in estuary
can be modeled based on the metal concentration in SPM, pH and salinity using a Kurbatov adsorption model assuming the natural
SPM as a simple surfaced molecule. 相似文献
8.
Mauro Lo Cascio Yan Liang Nobumichi Shimizu Paul C. Hess 《Contributions to Mineralogy and Petrology》2008,156(1):87-102
The grain-scale processes of peridotite melting were examined at 1,340°C and 1.5 GPa using reaction couples formed by juxtaposing
pre-synthesized clinopyroxenite against pre-synthesized orthopyroxenite or harzburgite in graphite and platinum-lined molybdenum
capsules. Reaction between the clinopyroxene and orthopyroxene-rich aggregates produces a melt-enriched, orthopyroxene-free,
olivine + clinopyroxene reactive boundary layer. Major and trace element abundance in clinopyroxene vary systematically across
the reactive boundary layer with compositional trends similar to the published clinopyroxene core-to-rim compositional variations
in the bulk lherzolite partial melting studies conducted at similar P–T conditions. The growth of the reactive boundary layer takes place at the expense of the orthopyroxenite or harzburgite and
is consistent with grain-scale processes that involve dissolution, precipitation, reprecipitation, and diffusive exchange
between the interstitial melt and surrounding crystals. An important consequence of dissolution–reprecipitation during crystal-melt
interaction is the dramatic decrease in diffusive reequilibration time between coexisting minerals and melt. This effect is
especially important for high charged, slow diffusing cations during peridotite melting and melt-rock reaction. Apparent clinopyroxene-melt
partition coefficients for REE, Sr, Y, Ti, and Zr, measured from reprecipitated clinopyroxene and coexisting melt in the reactive
boundary layer, approach their equilibrium values reported in the literature. Disequilibrium melting models based on volume
diffusion in solid limited mechanism are likely to significantly underestimate the rates at which major and trace elements
in residual minerals reequilibrate with their surrounding melt.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
9.
D. J. Cherniak 《Physics and Chemistry of Minerals》2008,35(4):179-187
Self-diffusion of Si under anhydrous conditions at 1 atm has been measured in natural zircon. The source of diffusant for
experiments was a mixture of ZrO2 and 30Si-enriched SiO2 in 1:1 molar proportions; experiments were run in crimped Pt capsules in 1-atm furnaces. 30Si profiles were measured with both Rutherford backscattering spectrometry (RBS) and nuclear reaction analysis with the resonant
nuclear reaction 30Si(p,γ)31P. For Si diffusion normal to c over the temperature range 1,350–1,550°C, we obtain an Arrhenius relation D = 5.8 exp(−702 ± 54 kJ mol−1/RT) m2 s−1 for the NRA measurements, which agrees within uncertainty with an Arrhenius relation determined from the RBS measurements
[62 exp(−738 ± 61 kJ mol−1/RT) m2 s−1]. Diffusion of Si parallel to c appears slightly faster, but agrees within experimental uncertainty at most temperatures
with diffusivities for Si normal to c. Diffusion of Si in zircon is similar to that of Ti, but about an order of magnitude faster than diffusion of Hf and two
orders of magnitude faster than diffusion of U and Th. Si diffusion is, however, many orders of magnitude slower than oxygen
diffusion under both dry and hydrothermal conditions, with the difference increasing with decreasing temperature because of
the larger activation energy for Si diffusion. If we consider Hf as a proxy for Zr, given its similar charge and size, we
can rank the diffusivities of the major constituents in zircon as follows: D
Zr < D
Si << D
O, dry < D
O, ‘wet’. 相似文献
10.