Stochastic modelling of groundwater flow and solute transport in aquifers

This paper presents an introductory overview of recently developed stochastic theories for tackling spatial variability problems in predicting groundwater flow and solute transport. Advantages and limitations of the theories are discussed. Lastly, strategies based on the stochastic approaches to predict solute transport in aquifers are recommended.     

Spatial measurements of stream baseflow,a relevant method for aquifer characterization and permeability evaluation. Application to a hard‐rock aquifer,the Oman ophiolite

The structure, functioning and hydrodynamic properties of aquifers can be determined from an analysis of the spatial variability of baseflow in the streams with which they are associated. Such analyses are based on simple low‐cost measurements. Through interpreting the hydrological profiles (Q = f(A)) it is possible to locate the aquifer(s) linked to the stream network and to determine the type of interrelated flow, i.e. whether the stream drains or feeds the aquifer. Using an analytical solution developed for situations with a positive linear relationship, i.e. where the baseflow increases linearly with increasing catchment size, it is also possible to estimate the permeability of the aquifer(s) concerned at catchment scale. Applied to the hard‐rock aquifers of the Oman ophiolite, this method shows that the ‘gabbro’ aquifer is more permeable than the ‘peridotite’ aquifer. As a consequence the streams drain the peridotites and ‘leak’ into the gabbro. The hydrological profiles within the peridotite are linear and positive, and indicate homogeneity in the hydrodynamic properties of these formations at the kilometre scale. The permeability of the peridotite is estimated at 5 · 10^?7 to 5 · 10^?8 m/s. Copyright © 2004 John Wiley & Sons, Ltd.     

One zone modeling of irregular variability of stellar convective envelope

One zone modeling of the irregular variability of red super-giants is intended with regard to the nonlinear coupling of finite amplitude pulsation with convection. The nonlocal mixing length is employed for the evaluation of the convective flux, the turbulent pressure and the turbulent power of temperature fluctuations. The radial pulsation and the Boussinesq convection are assumed for simplicity. The one zone is defined as the layer having the entropy maximum and the minimum at the bottom and at the top, respectively. The quasi-adiabatic approximation is consistent with this definition in fixing the zone to the same mass range. The spatial derivatives are evaluated under the assumption of homologous changes with the equilibrium homologous parameters. Then, a set of 6 simultaneous first order nonlinear ordinary differential equations are obtained as the one zone representation of the irregular variability of the convective envelope.     

APPLICATION OF MAP AND FILE INFORMATIONVISUALIZATION SYSTEM TO COMPREHENSIVEDIVISION OF NATURAL DISASTERS- Takingthe ChangjiangValleg as an Example

In recent years，scholars at home and abroad have method，and that vanous disasters would be analyzed assynthetically studied natural dlsaste‘theoretically and an Integral．SHI Peilun（1991）putforwad a scientificmethodologlcally，as well as its cases analys。s（CND，term—regional disaster system，which Indicates that1987； MA et al，1990； MARBLE，1990； NE et al，the situation of a disaster（calamity loss）results from1999； PATAK et al，1982； SHI，1991；VAN et al，h…     

陕西秦巴山区农业自然资源开发利用

农业自然资源据其在农业利用过程中的地位可分为两类:一类是生成农业自然资源的环境,另一类为可资直接利用的自然生成物(即狭义的农业自然资源)。陕西秦巴山区自然环境的主要特点是:复合山体高峻庞大,地跨暖温带和北亚热带,垂直分异明显。区内有:森林、草场、野生生物、林特产与农作物等多种农业自然资源。据此,提出了本区农业自然资源的开发利用途径。     

CygX—1硬态高能光子的时延

硬X射线和软射线光子的时延时研究主能辐射的一个重要方面，傅里叶交叉谱常常被用于教育处硬软光子之间的时延，但是交叉说示能在高于30Hz的傅里叶频率上从CygX-1测量到有统计意义的快速光变，由李惕培在时域上发展的交叉相关函方法能有效测量不同时间尺度上的时延，利用此交叉相关分析方法，讨论了不同观测时期CygX-1硬态高能光子时延 的性质，分析结果表明，CygX-1硬态在短的尺度（＜0．1秒）上存存在有意义的时间延迟，并将短时间尺度上的观测结果和各种CygX-1硬态模型进行了比较讨论。     

Is IRAS 03134 + 5958 a Herbig-Haro object?

The source IRAS 03134 + 5958 identified by Iyengar & Verma (1984) on the Palomar Observatory Sky Survey (POSS) prints with a nonstellar optical object with [P – R]≃ 5.3 ± 1.5 is near the edge of Lynds dark cloud No. 1384 and is either embedded in or behind the cloud. The galactic latitude of this source (b ^II = 2‡.3), its positionvis-a-vis the Lynds dark cloud, its nonstellar appearance, high [P – R] colour and its far-infrared spectrum, all suggest the possibility of its being a Herbig-Haro (HH) object. To test this possibility we undertook measurements of its proper motion and variability (two of the characteristic properties of HH objects). These yield μ_a = (3.6 ± 2.3) arcsec/century and μ_δ= (−1.2 ± 2.0) arcsec/century for its proper motion. The source reveals large variation in brightness between 1950 and 1954. Optical line studies of the source are required to confirm its classification as an HH object.     

The solubility of iron sulphides in synthetic and natural waters at ambient temperature

A critical evaluation of literature values for the solubility products, K _sp ^NBS = [Fe²⁺][HS^–] Fe²⁺ HS^– (H _NBS ⁺ )^–1, of various iron sulphide phases results in consensus values for the pKs of 2.95 ± 0.1 for amorphous ferrous sulphide, 3.6 ± 0.2 for mackinawite, 4.4 ± 0.1 for greigite, 5.1 ± 0.1 for pyrrhotite, 5.25 ± 0.2 for troilite and 16.4 ± 1.2 for pyrite.Where the analogous ion activity products have been measured in anoxic freshwaters in which there is evidence for the presence of solid phase FeS, the values lie within the range of 2.6–3.22, indicating that amorphous iron sulphide is the controlling phase. The single value for a groundwater of 2.65 (2.98 considering carbonate complexation) agrees. In seawater four values range between 3.85 to 4.2, indicating that mackinawite or greigite may be the controlling phase. The single low value of 2.94 is in a situation where particularly high fluxes of Fe (II) and S (–II) may result in the preferential precipitation of amorphous iron sulphide. Formation of framboidal pyrite in these sulphidic environments may occur in micro-niches and does not appear to influence bulk concentrations. Calculations show that the formation of Fe₂S₂ species probably accounts for very little of the iron or sulphide in most natural waters. Previously reported stability constants for the formation of Fe (HS)₂ and (Fe (HS)₃)^– are shown to be suspect, and these species are also thought to be negligible in natural waters. In completely anoxic pore waters polysulphides also have a negligible effect on speciation, but in tidal sediments they may reach appreciable concentrations and lead to the direct formation of pyrite. Concentrations of iron and sulphide in pore waters can be controlled by the more soluble iron sulphide phase. The change in the IAP with depth within the sediment may reflect ageing of the solid phase or a greater flux of Fe (II) and S (–II) nearer the sediment surface. This possible kinetic influence on the value of IAPs has implications for their use in geochemical studies involving phase formation.     

Coupled and complex: Human-environment interaction in the Greater Yellowstone Ecosystem, USA

Complexity theory has received considerable attention over the past decade from a wide variety of disciplines. Some who write on this topic suggest that complexity theory will lead to a unifying understanding of complex phenomena; others dismiss it as a passing and disruptive fad. We suggest that for the analysis of coupled natural/human systems, the truth emerges from the middle ground. As an approach focused as much on the connections among system elements as the elements themselves, we argue that complexity theory provides a useful conceptual framework for the study of coupled natural/human systems. It is, if nothing else, a framework that leads us to ask interesting questions about, for example, sustainability, resilience, threshold events, and predictability.In this paper we attempt to demystify the ongoing discussions on complexity theory by linking its evocative and overloaded terminology to real-world processes. We illustrate how a shift in focus from system elements to connections among elements can lead to meaningful insight into human-environment interactions that might otherwise be overlooked. We ground our discussion in ongoing interdisciplinary research surrounding Yellowstone National Park’s northern elk winter range; a tightly coupled natural/human system that has been the center of debate, conflict, and compromise for more than 135 years.     

无机盐类对天然矿物低温催化混合酯生烃反应的影响

脂肪酸酯是一类重要的生烃母质。选择了十四烷酸甲酯、十六烷酸甲酯和十八烷酸甲酯的混合酯为模型反应物,以方解石、白云石、伊利石、钙蒙脱石和黄铁矿为催化剂,分别考察了氯化钾、氯化镁、氯化钠、硫酸钠以及混合盐对天然矿物低温催化混合酯生烃反应的影响。结果表明,无机盐类对矿物催化下混合酯的生烃反应均有不同程度的影响,硫酸钠具有反催化作用,其它盐类具有正催化作用。且在各无机盐存在下,不同的矿物表现出不同的催化活性。