A numerical investigation of the destruction of peroxy radical by Cu ion catalysed reactions on atmospheric particles

To determine if Cu mediated reactions on atmospheric particles are important to HO₂ chemistry in the ambient atmosphere, Cu molalities were calculated from measured Cu aerosol particle concentrations, mass and number size distribution data from a site in central Sweden. A comparison of characteristic times indicates that at low relative humidities the reaction is limited by the mass transport of gas phase HO₂ to the particle surface and not by the chemical kinetics of the aqueous reaction. Comparison of half-lives for particle reactions and the gas phase destruction of HO₂ to form H₂O₂ indicate that heterogeneous reactions on aerosol particles may have important consequences on the chemistry of HO₂ and H₂O₂ in the troposphere.     

气溶胶的光学厚度与反射率比的处理方法

气溶胶光学厚度与气溶胶反射率比都是大气校正所需的重要大气参数，同时也是海洋水色卫星主要的数据产品，它们的测量精度将直接到卫星数据产品正演的精度和卫星数据产品的应用。文章在简述气溶胶光学厚度与气溶胶反射率比的基本测量原理和处理方法的基础上，结合多次试验数据结果进行简要的评价。     

Atmospheric input of trace elements to the western Pacific Ocean and the Kuroshio ocean area

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Roles of Continental Shelves and Marginal Seas in the Biogeochemical Cycles of the North Pacific Ocean

Most marginal seas in the North Pacific are fed by nutrients supported mainly by upwelling and many are undersaturated with respect to atmospheric CO₂ in the surface water mainly as a result of the biological pump and winter cooling. These seas absorb CO₂ at an average rate of 1.1 ± 0.3 mol C m⁻²yr⁻¹ but release N₂/N₂O at an average rate of 0.07 ± 0.03 mol N m⁻²yr⁻¹. Most of primary production, however, is regenerated on the shelves, and only less than 15% is transported to the open oceans as dissolved and particulate organic carbon (POC) with a small amount of POC deposited in the sediments. It is estimated that seawater in the marginal seas in the North Pacific alone may have taken up 1.6 ± 0.3 Gt (10¹⁵ g) of excess carbon, including 0.21 ± 0.05 Gt for the Bering Sea, 0.18 ± 0.08 Gt for the Okhotsk Sea; 0.31 ± 0.05 Gt for the Japan/East Sea; 0.07 ± 0.02 Gt for the East China and Yellow Seas; 0.80 ± 0.15 Gt for the South China Sea; and 0.015 ± 0.005 Gt for the Gulf of California. More importantly, high latitude marginal seas such as the Bering and Okhotsk Seas may act as conveyer belts in exporting 0.1 ± 0.08 Gt C anthropogenic, excess CO₂ into the North Pacific Intermediate Water per year. The upward migration of calcite and aragonite saturation horizons due to the penetration of excess CO₂ may also make the shelf deposits on the Bering and Okhotsk Seas more susceptible to dissolution, which would then neutralize excess CO₂ in the near future. Further, because most nutrients come from upwelling, increased water consumption on land and damming of major rivers may reduce freshwater output and the buoyancy effect on the shelves. As a result, upwelling, nutrient input and biological productivity may all be reduced in the future. As a final note, the Japan/East Sea has started to show responses to global warming. Warmer surface layer has reduced upwelling of nutrient-rich subsurface water, resulting in a decline of spring phytoplankton biomass. Less bottom water formation because of less winter cooling may lead to the disappearance of the bottom water as early as 2040. Or else, an anoxic condition may form as early as 2200 AD. This revised version was published online in July 2006 with corrections to the Cover Date.     

离子色谱分析在黄土和粉尘研究中的应用

黄土中存在着大量的碱金属及碱土金属，以往的测试方法多为原子吸收和ICP—MS，离子色谱法在测试黄土样品的碱金属和碱土金属元素含量中应用不多。将黄土地质标准样品进行消解后用离子色谱进行测试，测试效果良好，重复测试的相对标准偏差小于5％，与推荐值的相对误差小于5％，准确度和精密度符舍相关的质量控制要求。本实验方法测试的离子含量都在仪器响应呈线性的最佳测试范围之内，标准曲线经回归后相关系数均达到0．9999。黄土样品的分析结果与粉尘气溶胶样品的离子分析结果对比表明，此方法对于探讨粉尘起源以及沙尘暴天气的研究具有重要意义。     

Physical and anthropogenic effects on observed long-term nutrient changes in the Irish Sea

The trend in Irish Sea nutrient concentrations over the last four decades has been considered to reflect changes in anthropogenic loading. Comparison of a long-term database for the Menai Strait, North Wales, with an established historic data set for the Cypris station, Isle of Man, indicates that climate also has a significant influence on observations of nutrient concentrations. Data are presented detailing long-term shifts in nitrate, phosphate and silicate measurements since the 1960s at these two fixed sampling sites in the Irish Sea. Broad systematic changes observed in all three nutrients over the decades show a rise from the 1960s through to the 1980s, followed generally by an overall decline in the 1990s. Decadal-scale salinity changes occur in the opposite sense to nutrient changes. Anthropogenic inputs from freshwater cannot fully account for observed nutrient trends, neither is there evidence for shifts in nutrient concentrations in oceanic waters over the past four decades. Climatically forced movement in the geographical position of the freshwater/seawater mixing zone over a decadal time scale could, however, give rise to the observed shifts in nutrient concentration and salinity. This cannot alter nutrient concentration and salinity per se, but causes the measurements taken at fixed sampling sites to fluctuate inversely over this time scale. It is concluded that there is complex interplay between anthropogenic loading and climate affecting the distribution of nutrients in the Irish Sea.     

Vertical distribution of the macrobenthic community and its relationships to trace metals and natural sediment characteristics in the lower Douro estuary, Portugal

Vertical distribution (0–15 cm) of the macrobenthic community and its relationships to natural sediment characteristics and trace metal contents and bioavailability were studied at five locations in the lower Douro estuary, Portugal. An analysis of vertical metal distribution, for the interpretation of anthropogenic impact on the estuarine sediments, was also investigated. Sediment characterisation included organic matter, grain size, metals (Al, Fe, Cu, Pb, Cr, Ni, Cd, Zn and Mn), acid volatile sulphide (AVS) and simultaneously extracted metals (SEM). The macrobenthic community had low diversity (14 species), was dominated by small size opportunists and seemed to be controlled mainly by natural factors such as grain size distribution, Al and Fe contents and sediment depth. The vertically heterogeneous distribution of macrobenthic community appears to affect redox status of the sediments and consequently metal bioavailability. Despite anthropogenic contamination in terms of Zn, Cu, Pb, Cr and Ni having already been detected in the north bank, the analysis of vertical distribution was essential for the identification of current anthropogenic contamination in terms of Zn, Pb and Cd in the south bank.     

南极中山站大气气溶胶的化学组成及其来源的判别

从1998年3月7日至1999年11月23日历时21个月，在南极中山站连续采集89个海洋气溶胶样品，本文提供全部样品的13种化学元素Cu、Pb、Zn、Cd、Fe、Al、Mn、Cr、V、K、Na、Ca、Mg含量的实测值．研究表明中山站气溶胶化学成份的含量具有季节性变化的特征．通过相关分析、因子分析、富集因子等方法判别不同时间段中山站气溶胶化学成份的来源。     

Model simulations of carbon sequestration in the northwest Pacific by patch fertilization

Iron fertilization of nutrient-rich surface waters of the ocean is one possible way to help slow the rising levels of atmospheric CO₂ by sequestering it in the oceans via biological carbon export. Here, I use an ocean general circulation model to simulate a patch of nutrient depletion in the subpolar northwest Pacific under various scenarios. Model results confirm that surface fertilization is an inefficient way to sequester carbon from the atmosphere (Gnanadesikan et al., 2003), since only about 20% of the exported carbon comes initially from the atmosphere. Fertilization reduces future production and thus CO₂ uptake by utilizing nutrients that would otherwise be available later. Effectively, this can be considered as leakage when compared to a control run. This “effective” leakage and the actual leakage of sequestered CO₂ cause a significant, rapid decrease in carbon retention (only 30–45% retained after 10 years and less than 20% after 50 years). This contrasts markedly with the almost 100% retention efficiency for the same duration using the same model, when carbon is disposed directly into the northwest Pacific (Matsumoto and Mignone, 2005). As a consequence, the economic effectiveness of patch fertilization is poor in two limiting cases of the future price path of carbon. Sequestered carbon in patch fertilization is lost to the atmosphere at increasingly remote places as time passes, which would make monitoring exceedingly difficult. If all organic carbon from one-time fertilization reached the ocean bottom and remineralized there, acidification would be about −0.05 pH unit with O₂ depletion about −20 μmol kg⁻¹. These anomalies are probably too small to seriously threaten deep sea biota, but they are underestimated in the model because of its large grid size. The results from this study offer little to advocate purposeful surface fertilization as a serious means to address the anthropogenic carbon problem.     

南极长城站地区现代环境地球化学特征

本文通过环境背景值、风化壳地球化学、对流层(大气气溶胶)地球化学和人为地球化学异常,初步探讨了南极长城站地区的现代环境地球化学特征。分析表明:环境要素固有的地球化学性质、区域环境条件和自然环境演变之间具有深刻的内在联系。