Alteration, evaluation and use of extremaduran granite residues

The necessity of eliminating debris from a granite quarry has awakened an interest in applications of by-products, called “marginal arids”, in different fields, like construction and foundations for roadways, restoration, material for the manufacture of artificial rocks, and artesian products etc. Conclusions obtained from the results of tests carried out by X-ray diffraction of granite quarry by-products in Extremadura, Spain, submitted to different treatments, are established. Test pieces from two quarries are analyzed and compared generally and specifically, for commercial use. Finally, conclusions relating to essays in test pieces and mineral dynamics of marginal arid granite are exposed.     

Geochemical characteristics of mineral air particles emitted inside a clay atomisation plant which introduces waste recycling processes

The objective of this work is to assess the concentrations of three factions of air particles (settable particles, TSP and PM10) and the levels of several toxic elements in a clay atomisation industry through aerosol sampling at several points inside an industrial plant. Mechanical activities, which produce diffuse emissions, are the main process of discharge of particles in both indoor and outdoor workplace environments in the atomisation plant. The levels of As, Cd, Pb, Zn, Ba and Ni increase in the zones with higher concentrations of particles and lower ventilation. The concentrations of As and F are not influenced by the recycling processes. The levels of Cd and Pb do not show great enrichment in air particles collected inside the atomisation plant although the content of both elements is associated with ceramic muck recycling. Finally, the content of B in waste water is mainly transferred in gaseous phase to the atmosphere during the process of drying by atomisation.     

Econometric analysis of the ship demolition market

The topic of ship recycling has obtained considerable attention during the last two decades for a variety of reasons with the likelihood of the adoption of a new international convention under the auspices of the International Maritime Organization (IMO). This study applies econometric modeling to a unique data set to provide insight into the dynamics of the ship recycling market. The data set contains information on 51,112 ships over 100 gt and includes 748,621 events over a period of 29 years. The analysis confirms a negative relationship of earnings and a positive relationship of scrap prices for all locations while Bangladesh seems to be more sensitive to changes in earnings than the other locations and more likely demolishes larger and older vessels. The results for flag and ownership vary across scrapping locations with Malta and Cyprus indicating potential importance from a registry perspective. The overall safety profile of a vessel seems to be less important towards the probability of a ship being scrapped. Possible implementation of the convention at EU level will mostly likely affect Turkey while non-ratification of one of the major flags will most likely affect China or Bangladesh.     

胶北地体地壳演化：玲珑黑云母花岗岩继承锆石U-Pb年龄、微量元素和Hf同位素证据

胶北地体晚侏罗世下地壳重熔的玲珑黑云母花岗岩大面积出露,其中残留有大量继承锆石,记录了多期热事件,为复杂的地壳演化过程提供了重要线索。论文通过分析玲珑黑云母花岗岩中继承锆石的U-Pb年龄、微量元素和Hf同位素组成,探讨了胶北地体的地壳演化历史。结果显示胶北地体前寒武纪经历了~2.9Ga和~2.7Ga两期主要的地壳生长事件,~2.5Ga和2.2~1.8Ga两期地壳重熔改造事件,~2.5Ga和1.95~1.8Ga两期变质事件。~2.9Ga的岩浆作用形成于岛弧环境,~2.7Ga岩浆活动与下地壳基性物质的部分熔融有关,~2.5Ga发生的岩浆和变质事件与地幔柱底侵作用有关,并有同时期的表壳岩组合-胶东岩群形成。~2.1Ga地壳处于拉张状态,伴有与裂谷活动有关的双峰式岩浆作用,荆山群和粉子山群开始沉积,而后1.95~1.8Ga发生碰撞造山运动,胶北所有早前寒武纪岩石单元卷入此次事件,并发生变质作用。自此之后,直至二叠纪末,胶北处于岩浆活动的沉寂期,但于~1.7Ga和~1.0Ga发生沉积作用,形成芝罘群和蓬莱群。二叠纪末扬子板块向北俯冲于华北克拉通之下,并于三叠纪与华北克拉通发生陆陆碰撞作用,致使扬子板块北缘新元古代花岗岩发生超高压变质,形成苏鲁超高压变质带,之后超高压变质岩发生折返。玲珑黑云母花岗岩复杂的继承锆石组成可能表征了前寒武纪岩石卷入陆-陆碰撞事件而发生再循环作用。     

Evidence from kimberlitic zircon for a decreasing mantle Th/U since the Archean

A decoupling in MORB of measured Th/U (κ = 2.5) from that calculated by Pb isotopes (κ = 3.8) for the depleted asthenosphere is well established, and has been referred to as the second Pb paradox (Kramers, J.D., and Tolstikhin, I.N., 1997. Two terrestrial lead isotope paradoxes, forward transport modelling, core formation and the history of the continental crust. Chem. Geol., 139, 75–110.) or the kappa conundrum (Elliott, T., Zindler, A., and Bourdon, B., 1999. Exploring the kappa conundrum: the role of recycling in the lead isotope evolution of the mantle. Earth Planet. Sci. Lett., 169, 129–145.). More controversial has been the cause and timing of this phenomenon, although a higher return flux of U⁶⁺ relative to Th⁴⁺ and(or) the recycling of crustal Pb into the mantle have become the preferred explanations of most workers. Such a combined mechanism effectively operating over the past 2.5 Ga was modelled in plumbotectonics (Zartman, R.E., and Haines, S., 1988. The plumbotectonics model for Pb isotopic systematics among major terrestrial reservoirs—a case for bi–directional transport. Geochim. Cosmochim. Acta, 52, 1327–1339. 709.33.), and found to be quantitatively feasible.A large TIMS, SIMS and LA-ICPMS database of Th and U concentrations for kimberlite-hosted zircon, particularly from Cr-poor megacrystic suites, now exists (Kinny et al., 1989, Berryman et al., 1999, Griffin et al., 2000 and Spetsius et al., 2002; Appendix A and Appendix B, this work). Six suites comprising 10 or more zircon grains with ages between 90 and 2550 Ma reveal consistent patterns when plotted on Th/U vs. U diagrams. We interpret these patterns as resulting from fractional crystallization of a melt with kimberlite affinity presumably derived from the asthenosphere, permitting the extrapolation to an initial Th/U at the time zircon crystallization began. A two-fold decrease is seen in this ratio over the past 2.5 Ga, suggesting that during this time a similar change has occurred in the parent silicate melt. Estimates of Th and U distribution coefficients between zircon and coexisting melt permit calculation of Th/U in the melt, which, for these highly incompatible elements, presumably is the same as for its mantle source rock. Kimberlitic zircon may thus indeed give evidence of a reduction in κ, tentatively calculated as from 4 to 2, since the Archean for the depleted asthenosphere.     

Geology and geochemistry of basaltic lava flows and dikes from the Trans-Koolau tunnel, Oahu, Hawaii

A 200-m section of Koolau basalt was sampled in the 1.6-km Trans-Koolau (T–K) tunnel. The section includes 126 aa and pahoehoe lava flows, five dikes and ten thin ash units. This volcanic section and the physical characteristics of the lava flows indicate derivation from the nearby northwest rift zone of the Koolau shield. The top of the section is inferred to be 500–600 m below the pre-erosional surface of the Koolau shield. Therefore, compared with previously studied Koolau lavas, this section provides a deeper, presumably older, sampling of the shield. Shield lavas from Koolau Volcano define a geochemical end-member for Hawaiian shields. Most of the tunnel lavas have the distinctive major and trace element abundance features (e.g. relatively high SiO₂ content and Zr/Nb abundance ratio) that characterize Koolau lavas. In addition, relative to the recent shield lavas erupted at Kilauea and Mauna Loa volcanoes, most Koolau lavas have lower abundances of Sc, Y and Yb at a given MgO content; this result is consistent with a more important role for residual garnet during the partial melting processes that created Koolau shield lavas. Koolau lavas with the strongest residual garnet signature have relatively high ⁸⁷Sr/⁸⁶Sr, ¹⁸⁷Os/¹⁸⁸Os, ¹⁸O/¹⁶O, and low ¹⁴³Nd/¹⁴⁴Nd. These isotopic characteristics have been previously interpreted to reflect a source component of recycled oceanic crust that was recrystallized to garnet pyroxenite. This component also has high La/Nb and relatively low ²⁰⁶Pb/²⁰⁴Pb, geochemical characteristics which are attributed to ancient pelagic sediment in the recycled crust. Although most Koolau lavas define a geochemical endmember for Hawaiian shield lavas, there is considerable intrashield geochemical variability that is inferred to reflect source characteristics. The oldest T–K tunnel lava flow is an example. It has the lowest ⁸⁷Sr/⁸⁶Sr, Zr/Nb and La/Nb, and the highest ¹⁴³Nd/¹⁴⁴Nd ratio found in Koolau lavas. In most respects it is similar to lavas from Kilauea Volcano. Therefore, the geochemical characteristics of the Koolau shield, which define an end member for Hawaiian shields, reflect an important role for recycled oceanic crust, but the proportion of this crust in the source varied during growth of the Koolau shield. Received: 1 June 1998 / Accepted: 30 August 1998     

陆面过程对气候影响的数值模拟:SSiB与IAP/LASG L9R15 AGCM耦合及其模式性能

利用陆面过程模式 SSi B与 IAP/LASG发展的 L9R1 5AGCM的耦合 1 0 a积分试验 ,研究了全球尺度大气与地表的水分和能量交换以及陆地与大气环流和气候的相互作用。模拟表明 :SSi B模式可模拟出陆地上较为真实的表面通量及其日变化 ,较好地定量描述土壤 -植被 -大气连续体系 ( SPAC)中能量和水分的传输过程。因此 ,将其引入气候模式中能够模拟出比 CTL- AGCM更合理的气候平均状态、水汽分布以及水汽输送的气候特征 ,特别是亚洲夏季风水汽输送独特的地域性 ,再现了大气环流 ,尤其是陆面气候的基本特征。并指出 ,陆面过程参数化的引进及其陆面状况的变化显著地改善了全球陆地上的水分平衡状况。利用改进的再循环降水模式 ,进一步研究了陆面过程参数化明显改进降水模拟的物理机制。指出全球陆地 ,特别是盛夏北半球干旱、半干旱地区的再循环降水率明显减小 ,与陆面上表面潜热通量的显著减小区一致 ,从而克服了许多未耦合陆面过程的 AGCMs因对地表水过程非常简单地参数化导致的普遍存在着整个陆地降水偏高 ,改善了全球陆地上的水分平衡状况。因此 ,在充分耦合的陆气环流模式中模拟的降水分布与实况接近。     

Legal regulation of the shipbreaking industry in Bangladesh: The international regulatory framework and domestic implementation challenges

Shipbreaking is the process of dismantling an obsolete vessel for scrapping or disposal. This activity was not officially declared an industry in Bangladesh until 2006, even though the country is one of the biggest ship-breakers in the world. This industry has dramatically expanded in Bangladesh, at the cost of environmental degradation and severe labour exploitation. Despite environmental and human rights violations, the shipbreaking industry represents a vital source of income for the country and a livelihood for a significant portion of its population. Shipbreaking activities in Bangladesh present both opportunities and challenges for Bangladesh. This article examines the extent to which the existing regulatory framework for dealing with these issues in Bangladesh is congruent with international instruments. This article also examines relevant international instruments which prescribe the core principles for regulating the ship breaking industry and evaluates the legal regulation of the Bangladesh ship breaking industry against these international instruments. The underlying objective of this evaluation is to demonstrate that Bangladeshi instruments could incorporate the core of the international instruments to minimise the environmental damage caused by this industry. This article concludes that Bangladesh should either amend its laws or enact a new legislative scheme that is based on the core values of the Basel Convention. This change is vital if Bangladesh wants to ensure a long lasting industry that could serve its need for iron ore and engage its abundant labour force, without the cost of destroying its coastal line which is one of its most valuable natural assets.     

A material lens on socio-technical transitions: The case of steel in Australian buildings

Steel is a critical material for modern-day societies, and more than half of the world’s steel is used in buildings. As the extraction of iron ore and the production and transport of manufactured steel have significant environmental costs, the fate of steel is important for socio-technical transitions towards more sustainable materials use. Using steel in buildings as a case study socio-technical transition, this paper develops a novel application of the multi-level perspective (MLP) that adopts an explicitly material lens. We focus on the circulation of steel between three key life stages for buildings which are treated as socio-technical regimes as described in the MLP. Drawing on concepts from assemblage theory, we consider the role played by the material and expressive qualities of steel within each of these regimes. Our material focus also requires attention to the spatial dimensions of these three regimes and their implications for socio-technical transitions. We describe the nexus of material affordances and inter-scalar relations that influences the use of steel in buildings and consider the potential for change. The main contribution of this paper is to extend the MLP to incorporate a focus on materiality and, in a related way, spatiality. Based on the analysis presented we consider how steel use in Australian buildings may be rendered more sustainable.     

Assessing phosphate rock depletion and phosphorus recycling options

We analyze global elemental phosphorus flows in 2009 for (1) mining to products, (2) animal and human manure flows, (3) crop harvests and animal production, (4) food production, (5) soil erosion, (6) and crop uptake. Informed by the flow assessment the potential and cost of phosphorus usage reduction and recycling measures are quantified, and fed into a constructed phosphorus supply-demand model with reserve assessment to assess the impact of these measures on phosphate rock resource availability. According to our results in 2009 globally 21.4 Mt elemental phosphorus from rock phosphate was consumed in products of which 17.6 Mt used as fertilizers, fully able to cover erosion losses and outputs in agriculture in aggregate, but insufficient from the perspective of bio-available phosphorus in soils. We find substantial scope for phosphorus use reduction, at potentially 6.9 Mt phosphorus, or 32% of 2009 phosphate rock supply. Another 6.1 Mt, or 28% can technologically be recycled from waterways and wastewater, but at a cost substantially above any foreseeable phosphate rock fertilizer price. The model results suggests phosphate rock reserves are sufficient to meet demand into the 22nd century, and can be extended well into the 23rd century with assessed use reduction and recycling measures.