Source rates and ion recycling rates for Na and K in Mercury's atmosphere

The supply rates of Na and K to the atmosphere of Mercury by processes acting on the extreme surface—thermal vaporization, photon-stimulated desorption (PSD), and ion-sputtering—are limited by the rates at which atoms can be supplied to the extreme surface by diffusion from inside the regolith grains. Supply rates to the atmosphere are further regulated by ion retention and by gardening rates that supply new grains to the surface. We consider the limits on supply of sodium and potassium atoms to the atmosphere, and rates of photoion recycling to the surface. Thermal vaporization rates are severely limited by the ability of atoms to diffuse to the surface of the grain. Therefore, the diffusion-limited thermal vaporization rates on Mercury's surface are comparable to or less than the PSD rates. Ion sputtering is primarily due to highly ionized heavy ions, even though they represent a small fraction of the solar wind. We have shown that up to 60% of the Na photoions are deposited on the surface of Mercury. Ion recycling to the surface can have a long-term effect on the regolith abundance if an average recycling pattern persists such that more ions return to a particular area than are launched there. It is unknown whether the formation of latitude bands of >100% ion retention persist on average despite a rapidly changing magnetosphere. The total exospheric column of sodium observed at Mercury between 1997 to 2003 varied by a factor of 2-3 from perihelion to aphelion.     

HCN fluorescence on Titan

The HCN emission features near 3 μm recently detected by Geballe et al. (2003, Astrophys. J. 583, L39) are analyzed with a model for fluorescence of sunlight in the ν₃ band of HCN. The emission spectrum is consistent with current knowledge of the atmospheric temperature profile and the HCN distribution inferred from millimeter-wave observations. The spectrum is insensitive to the abundance of HCN in the thermosphere and the thousand-fold enhancement relative to photochemical models suggested by Geballe et al. (2003, Astrophys. J. 583, L39) is not required to explain the observations. We find that the spectrum can be matched with temperatures from 130 to 200 K, with slightly better fits at high temperature, contrary to the temperature determination of 130±10 K of Geballe et al. (2003, Astrophys. J. 583, L39). The HCN emission spectrum is sensitive to the collisional de-excitation probability, P₁₀, for the ν₃ state and we determine a value of 10⁻⁵ with an accuracy of about a factor of two. Analysis of absorption lines in the C₂H₂ν₃ band near 3 μm, detected in the same spectrum, indicate a C₂H₂ mole fraction near 0.01 μbar of 10⁻⁵ for P₁₀=10⁻⁴. The derived mole fraction, however, is dependent upon the value adopted for P₁₀ and lower values are required if P₁₀ at Titan temperatures is less than its room temperature value.     

Mesoscale linear streaks on Mars: environments of dust entrainment

Variable surface albedo features on Mars are likely caused by the entrainment and deposition of dust by the wind. Most discrete markings are associated with topographic forms or with regional slopes that serve to alter the effective wind shear stress on the surface. Some of the largest variable features, here termed mesoscale linear streaks, are up to 400 km in length and repeatedly occur in one of the smoothest regions of Mars: Amazonis Planitia. Their orientations and apparent season of variability as observed by Viking and Mars Orbiter cameras indicate linear streak formation by enhanced surface wind stresses during regional or local dust storms and during the initial stages of global dust storms. They provide an example of the ability of large-scale winds, without significant local enhancement, to initiate dust motion on Mars. The sizes and spacing of the linear streaks may be controlled by boundary layer rolls. The repetitive formation of these streaks, over a span of more than 11 Mars years, gives one measure of the stability of Mars’ eolian processes.     

DEVELOPMENT STRATEGIES OF WATER AND LAND RESOURCES IN THE HEXI REGION,CHINA

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PALEOSOLS OF SANDY LANDS AND ENVIRONMENTAL CHANGES IN THE WESTERN PART OF NORTHEAST PLAIN OF CHINA WESTERN DURING HOLOCENE

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Loss of water from Mars:: Implications for the oxidation of the soil

The evolution of the martian atmosphere with regard to its H₂O inventory is influenced by thermal loss processes of H, H₂, nonthermal atmospheric loss processes of H⁺, H₂⁺, O, O⁺, CO₂, and O₂⁺ into space, as well as by chemical weathering of the surface soil. The evolution of thermal and nonthermal escape processes depend on the history of the intensity of the solar XUV radiation and the solar wind density. Thus, we use actual data from the observation of solar proxies with different ages from the Sun in Time program for reconstructing the Sun's radiation and particle environment from the present to 3.5 Gyr ago. The correlation between mass loss and X-ray surface flux of solar proxies follows a power law relationship, which indicates a solar wind density up to 1000 times higher at the beginning of the Sun's main sequence lifetime. For the study of various atmospheric escape processes we used a gas dynamic test particle model for the estimation of the pick up ion loss rates and considered pick up ion sputtering, as well as dissociative recombination. The loss of H₂O from Mars over the last 3.5 Gyr was estimated to be equivalent to a global martian H₂O ocean with a depth of about 12 m, which is smaller than the values reported by previous studies. If ion momentum transport, a process studied in detail by Mars Express is significant on Mars, the water loss may be enhanced by a factor of about 2. In our investigation we found that the sum of thermal and nonthermal atmospheric loss rates of H and all nonthermal escape processes of O to space are not compatible with a ratio of 2:1, and is currently close to about 20:1. Escape to space cannot therefore be the only sink for oxygen on Mars. Our results suggest that the missing oxygen (needed for the validation of the 2:1 ratio between H and O) can be explained by the incorporation into the martian surface by chemical weathering processes since the onset of intense oxidation about 2 Gyr ago. Based on the evolution of the atmosphere-surface-interaction on Mars, an overall global surface sink of about 2×10⁴² oxygen particles in the regolith can be expected. Because of the intense oxidation of inorganic matter, this process may have led to the formation of considerable amounts of sulfates and ferric oxides on Mars. To model this effect we consider several factors: (1) the amount of incorporated oxygen, (2) the inorganic composition of the martian soil and (3) meteoritic gardening. We show that the oxygen incorporation has also implications for the oxidant extinction depth, which is an important parameter to determine required sampling depths on Mars aimed at finding putative organic material. We found that the oxidant extinction depth is expected to lie in a range between 2 and 5 m for global mean values.     

Monte-Carlo simulation of Mercury's exosphere

Because of its proximity to the Sun and its small size, Mercury has not been able to retain its atmosphere and only a thin exosphere surrounds the planet. The exospheric pressure at the planetary surface is approximately 10⁻¹⁰ mbar, set by the Mariner 10 occultation experiment. The existence of gaseous species H, He, and O has been established by Mariner 10. In addition Na, K, and Ca have been observed by ground based instrumentation. Other elements are expected to be found in Mercury's exosphere since the total pressure of the known species is almost two orders of magnitude less than the exospheric pressure.It is intended to measure these exospheric particle densities in situ with an instrument on board of ESA's BepiColombo Mercury Planetary Orbiter (MPO) spacecraft. Since the expected exospheric densities are very small we developed a Monte-Carlo computer model to investigate if such a measurement is feasible along the MPO spacecraft orbit. We model energy and ejection angle distributions of the particles at the surface, with the emission process determining the actual distribution functions. Our model follows the trajectory of each particle by numerical integration until the particle hits Mercury's surface again or escapes from the calculation domain. Using a large set of these trajectories bulk parameters of the exospheric gas are derived, e.g., particle densities for various atomic and molecular species. Our study suggests that a mass spectrometric measurement is feasible and, at least at MPO's periherm, all species that are released from the surface will be observed.     

Titan's atmospheric engine: an overview

Heating occurs in Titan's stratosphere from the absorption of incident solar radiation by methane and aerosols. About 10% of the incident sunlight reaches Titan's surface and causes heating there. Thermal radiation redistributes heat within the atmosphere and cools to space. The resulting vertical temperature profile is stable against convection and a state of radiative equilibrium is established. Equating theoretical and observed temperature profiles enables an empirical determination of the vertical distribution of thermal opacity. A uniformly mixed aerosol is responsible for most of the opacity in the stratosphere, whereas collision-induced absorption of gases is the main contributor in the troposphere. Occasional clouds are observed in the troposphere in spite of the large degrees of methane supersaturation found there. Photochemistry converts CH₄ and N₂ into more complex hydrocarbons and nitriles in the stratosphere and above. Thin ice clouds of trace organics are formed in the winter and early spring polar regions of the lower stratosphere. Precipitating ice particles serve as condensation sites for supersaturated methane vapor in the troposphere below, resulting in lowered methane degrees of supersaturation in the polar regions. Latitudinal variations of stratospheric temperature are seasonal, and lag instantaneous response to solar irradiation by about one season for two reasons: (1) an actual instantaneous thermal response to a latitudinal distribution of absorbing gases, themselves out of phase with the sun by about one season, and (2) a sluggish dynamical response of the stratosphere to the latitudinal transport of angular momentum, induced by radiative heating and cooling. Mean vertical abundances of stratospheric organics and aerosols are determined primarily by atmospheric chemistry and condensation, whereas latitudinal distributions are more influenced by meridional circulations. In addition to preferential scavenging by precipitating ice particles from above, the polar depletion of supersaturated methane results from periodic scavenging by short-lived tropospheric clouds, coupled with the steady poleward march of the continuously drying atmosphere due to meridional transport.     

中国东部第四纪自然环境演化及庐山“冰碛层”堆积时期的自然环境研究

根据第四纪地层内孢粉组合和动物群等新资料恢复了我国东部各大区域第四纪各个时期的自然环境特征,其温暖期与干冷期的交替与深海沉积O~(18)温度变化趋势大致对应。庐山三次“冰期冰碛层”内孢粉组合表明均为温暖湿润针阔叶混交林景观,而不是寒冷的冰川环境。     

A numerical investigation of the destruction of peroxy radical by Cu ion catalysed reactions on atmospheric particles

To determine if Cu mediated reactions on atmospheric particles are important to HO₂ chemistry in the ambient atmosphere, Cu molalities were calculated from measured Cu aerosol particle concentrations, mass and number size distribution data from a site in central Sweden. A comparison of characteristic times indicates that at low relative humidities the reaction is limited by the mass transport of gas phase HO₂ to the particle surface and not by the chemical kinetics of the aqueous reaction. Comparison of half-lives for particle reactions and the gas phase destruction of HO₂ to form H₂O₂ indicate that heterogeneous reactions on aerosol particles may have important consequences on the chemistry of HO₂ and H₂O₂ in the troposphere.