北京奥运会期间CBM-Z化学机制的模拟应用

利用CBM-Z化学机制模拟了中国科学院大气物理研究所气象塔站在北京奥运会期间高臭氧时段O3浓度的日变化,评估了气象条件、北京奥运会加强控制措施以及O3前体物浓度对近地面O3生成的影响。结果表明:(1)CBM-Z化学机制较好地模拟了北京奥运会期间典型时段气象塔站O3、NO、NO2日变化特征。(2)有利于局地高臭氧事件发生的气象条件非常相似;北京奥运会加强控制措施的实施显著减少了NOx及VOCs的排放量,导致近地面O3浓度的明显下降。(3)奥运会期间VOCs和CO是影响气象塔站O3生成量的关键因素。     

Microfacies and diagenesis of older Pleistocene (pre‐last glacial maximum) reef deposits,Great Barrier Reef,Australia (IODP Expedition 325): A quantitative approach

During Integrated Ocean Drilling Program Expedition 325, 34 holes were drilled along five transects in front of the Great Barrier Reef of Australia, penetrating some 700 m of late Pleistocene reef deposits (post‐glacial; largely 20 to 10 kyr bp ) in water depths of 42 to 127 m. In seven holes, drilled in water depths of 42 to 92 m on three transects, older Pleistocene (older than last glacial maximum, >20 kyr bp ) reef deposits were recovered from lower core sections. In this study, facies, diagenetic features, mineralogy and stable isotope geochemistry of 100 samples from six of the latter holes were investigated and quantified. Lithologies are dominated by grain‐supported textures, and were to a large part deposited in high‐energy, reef or reef slope environments. Quantitative analyses allow 11 microfacies to be defined, including mixed skeletal packstone and grainstone, mudstone‐wackestone, coral packstone, coral grainstone, coralline algal grainstone, coral‐algal packstone, coralline algal packstone, Halimeda grainstone, microbialite and caliche. Microbialites, that are common in cavities of younger, post‐glacial deposits, are rare in pre‐last glacial maximum core sections, possibly due to a lack of open framework suitable for colonization by microbes. In pre‐last glacial maximum deposits of holes M0032A and M0033A (>20 kyr bp ), marine diagenetic features are dominant; samples consist largely of aragonite and high‐magnesium calcite. Holes M0042A and M0057A, which contain the oldest rocks (>169 kyr bp ), are characterized by meteoric diagenesis and samples mostly consist of low‐magnesium calcite. Holes M0042A, M0055A and M0056A (>30 kyr bp ), and a horizon in the upper part of hole M0057A, contain both marine and meteoric diagenetic features. However, only one change from marine to meteoric pore water is recorded in contrast with the changes in diagenetic environment that might be inferred from the sea‐level history. Values of stable isotopes of oxygen and carbon are consistent with these findings. Samples from holes M0032A and M0033A reflect largely positive values (δ¹⁸O: ?1 to +1‰ and δ¹³C: +1 to +4‰), whereas those from holes M0042A and M0057A are negative (δ¹⁸O: ?4 to +2‰ and δ¹³C: ?8 to +2‰). Holes M0055A and M0056A provide intermediate values, with slightly positive δ¹³C, and negative δ¹⁸O values. The type and intensity of meteroric diagenesis appears to have been controlled both by age and depth, i.e. the time available for diagenetic alteration, and reflects the relation between reef deposition and sea‐level change.     

北京地区一次强沙尘暴过程的大气边界层结构和湍流通量输送特征

利用中国科学院大气物理研究所北京325 m气象塔的风速和温度平均场观测资料和湍流资料,以及北京市气象台地面常规气象资料和逐日08:00和20:00(北京时间)的探空资料,分析了2002年3月18～22日沙尘暴过境前后北京城市边界层结构特征和湍流输送特征,结果表明:1)在沙尘暴爆发前,边界层中水平风速一直较小;气温较高,大气层结稳定,在边界层上部有强大的逆温层.随着冷锋过境,沙尘暴爆发,边界层中水平风速和平均湍流速度急剧增强;温度也突然变化,先迅速增强后又持续下降,逆温层迅速被破坏.2)沙尘暴初期,280 m上为系统性上升气流,而47和120 m则为系统性的下沉气流.随着沙尘暴爆发,湍流动能、向下传输的动量以及向上传输的感热也迅速增大,并且120 m高度的湍能、动量通量以及感热通量明显高于47和280 m,这与北京的局地环流有关.3)本次沙尘暴过程中,120和47 m层的摩擦速度都明显超过了北京的临界摩擦速度,表明局地起沙也是本次沙尘暴过程中北京沙尘的一个重要沙源.     

北京城市化进程对边界层风场结构影响的研究

随着近10年来北京城市化步伐的加快,城市规模迅速扩大,北京三环以外的地区已由20世纪七、八十年代的城郊非均匀下垫面发展成现在粗糙复杂的城区下垫面,市区建筑物相应增多、增密和增高,导致城区地面动力学粗糙度明显增大.本文统计分析了北京325 m气象塔1994年和1997～2003年夏季平均场观测资料,结果表明:(1)在受下垫面影响最为剧烈的近地层,风向逐年趋于紊乱,现在气象塔周围近地面的流场已经具备了典型城市粗糙下垫面的流场特征;(2)近地面夏季平均风速呈现非常明显的逐年递减的趋势,而且距离地表越近,平均风速逐年递减的趋势也越为显著,这种风速逐年递减的趋势直到63 m左右才不明显,说明现在气象塔47 m以下的观测资料反映的是城市冠层的流场特征,城市冠层厚度约在47～63 m之间;(3)随着北京城市化的发展,城区近地面的平均风速存在逐年递减的趋势,但阵风并不存在相似的递减趋势,表明城市冠层的抬升对阵风的影响并不显著.     

大气应急响应模拟中城市冠层风廓线参数化方法检验

城市冠层内风场的准确模拟或预报是突发性大气污染应急响应措施制定和实施的重要前提和基础。为了合理反映城市冠层的影响, 并满足应急响应时效性的要求, 将MacDonald(2000)提出的城市冠层内风廓线参数化方法耦合于中尺度气象模式MM5, 并利用2010年7月18日至8月6日北京325 m气象塔垂直观测资料进行验证。试验结果表明:(1)城市冠层参数化方法能够较好的模拟各种稳定度条件下冠层内风速廓线垂直变化, 中性、稳定和不稳定层结时的标准平均偏差分别为78%、12%、4%, 标准平均误差分别为78%、52%、21%。(2)城市冠层参数化方法能够较好的模拟冠层内实际风速变化情况, 虽然随高度增加模拟偏差增大, 但8、15、32、47 m高度的模拟风速与观测值依然十分接近, 标准平均偏差分别为2%、-26%、25%、60%, 标准平均误差分别为54%、46%、52%、73%。(3)与传统的Monin-Obukhov相似性边界层参数化方法相比, 城市冠层参数化方法明显提高了冠层风速的模拟能力。中性、稳定、不稳定层结时, Monin-Obukhov相似性边界层参数化方法的标准平均误差高达420%、176%、184%, 城市冠层参数化方法的标准平均误差减小至78%、52%、21%;冠层内8、15、32、47 m高度, Monin-Obukhov相似性边界层参数化方法的标准平均误差分别为283%、184%、227%、167%, 城市冠层参数化方法的标准平均误差减小至54%、46%、52%、73%。