预防油页岩地层钻进中压差卡钻的措施

分析了油页岩地层钻进中压差卡钻发生的原因,提出了预防压差卡钻的途径及处理方法,并通过工程实例来强调预防为主的重要性。     

寒武系古流体地球化学特征及其对页岩气保存的指示意义 ——以中扬子地区寒武系页岩气发现井宜地2井为例

保存条件是中扬子地区页岩气富集的关键因素之一，宜地2井是中扬子寒武系页岩气发现井，通过对该井全井段岩芯裂缝古流体的地球化学分析，探讨了寒武系古流体成因和对水井沱组页岩气保存条件的指示意义。结果认为：① 覃家庙组膏岩层之上方解石脉缺少Fe2+、Mn2+，且δ13C和δ18O值较围岩偏负，指示其形成于氧化的环境，石牌组方解石脉δ13C偏负，黄铁矿脉δ34S值与膏盐相似，表明其成因与TSR密切相关；水井沱组脉体δ13C和δ18O与围岩相似，形成于封闭的环境。② 方解石脉包裹体群SO42-、Ca2+、Mg2+含量整体上由覃家庙组向上向下分别递减，钠氯系数以水井沱组最低，整体上向上升高，表明覃家庙组是高盐度卤水的主要来源，水井沱组受外来流体影响弱；包裹体水溶液δD和δ18O也指示娄山关组、石牌组方解石脉成因分别与大气水、TSR相关。③ 古流体地球化学研究表明宜昌地区页岩气保存条件整体较好，页岩气散失的主要通道是垂直裂缝，页岩气保存条件好与膏盐盖层发育、后期构造破坏弱、脉体对裂缝的及时封闭以及白垩系盖层等因素密切相关。     

Geochemistry of soils derived from black shale, central Hunan, China

The black shale formed under anoxic conditions usually contains high concentrations of many metals. Weathering of such black shale might cause the emission of many metals. Moreover, soils derived from black shale （SBS） are believed to be affected by black shale weathering. In recent years, many studies such as Lee et al. （2002）, Woo et al. （2002）, Fang et al. （2002）, Pasava et al. （2003）, and Peng et al. （2004） have approached the heavy metal contaminations of SBS, but systematical geochemical study is rare. Presently, the SBS and its corresponding black shales （CBS） were both sampled from central Hunan （China）, and analyzed for a large number of elements, using an Elan6000 ICP-MS/AES machine at Guangzhou Institute of Geochemistry, CAS. In this paper, some preliminary results are reported. The analytical results show that the SBS in central Hunan contains very high concentrations of heavy metals such as Co, Cu, Hg, Mo, Pb, Zn, U, Th, Sb, T1, Cd, Cr, Sc, V, Sn, As, Se, and Ni.     

Attenuation of aqueous metal transport at two natural acid rock drainage occurrences in the Yukon Territory, Canada

Naturally acidic drainage associated with pyritic black shale has been observed in many locations in the Yukon Territory. While not necessarily linked to known mineral deposits, most of these natural acid rock drainage occurrences show elevated dissolved concentrations of trace elements, especially zinc, nickel, copper, cadmium and arsenic. Based on field observations, microbial investigation, chemical analyses and geochemical modeling, the fate and transport of potentially deleterious elements at two natural acid drainage occurrences with slightly different settings are examined. The Macintosh Creek is a small, acidic stream （pH 2.98-3.40）, 2 km long, located in the Macmillan Pass area of east-central Yukon amidst known sedimentary exhalative massive sulfide mineralization but remains undisturbed by exploration activities. Its trace metal content is apparently derived from groundwater discharges, which gave as much as 5.0, 2.5, 0.7, 0.13 and 0.03 mg/L ofZn, Ni, Cu and As, respectively. Interaction and sorption reactions with algal mats, biofilms and iron oxyhydroxides appear to be the dominant mechanisms attenuating aqueous contaminant transport along the stream. Cryogenic precipitation further consolidates the ferricrete formation and reduces the mobility of the sorbed metals. The tributaries of the Engineering Creek along the Dempster Highway in northern Yukon drain through a series of dolomite, phyllite, argillite, limestone, black shale, sandstone and conglomerate with no known concentration of mineralization. In this area, the water chemistry fully reflects the local geology with acidic streams invariably associated with black shale occurrences. Groundwater seeps in the headwaters area of the km-180 Creek completely enclosed in black shale gave pH 3.0 and as much as 148, 39, 2.9 and 9.1 mg/L of Zn, Ni, Cu and As, respectively. Sorption with iron oxyhydroxide and organic matter appear to dominate the attenuation of contaminant transport along the stream. However, once entered into carbonate-dominated terrains, secondary carbonate minerals exercise additional geochemical control on the local water chemistry as a result of neutralization.     

油页岩综合利用对周围环境的影响——以抚顺矿区为例

世界能源日益减少的局面为油页岩的开发应用带来广阔的前景，但油页岩工业所带来的环境影响亦不容忽视。以抚顺油页岩为例，从油页岩综合利用和油页岩工业对环境的影响等方面系统讨论了在我国发展油页岩工业时，如何本着节约能源、保护环境、实现可持续发展的观念，利用现有先进技术，科学发展油页岩工业，降低生产过程中的固、液、气污染物对环境的危害。     

遵义市城区及周边地带制砖页(泥)岩地质特征和开发前景

文章对遵义市城区及周边地带各地质时代的页（泥）岩已有资料进行了系统收集、归纳和适当的野外调研，认为区内制砖页（泥）岩层位可分为三类，第一、二类利用价值小或仅有部分可以利用，第三类则易于露采，大部分可利用，其层位为下奥陶统湄潭组和下三叠统夜郎组九级滩段，是区内可作制砖页（泥）岩利用最有开发前景的层位。同时对页（泥）岩的形成沉积环境作了简要分析，对其资源量进行了概略估算，经优化筛选，提出了10个供制砖厂企设置布局和矿源地选择之前需进行地质勘查的区块。     

民和盆地中侏罗统煤-油页岩层系生油特征

本文简要论述了民和盆地中侏罗统含煤及油页岩层系的生油特征，探讨了盆地独特的石油地质和地球化学条件。原油主要地化特征为:Ｐｒ/Ｐｈ比值偏高（２.６５-３.１５）、甾烷/藿烷比值极低（０.０３）、Ｃ_２７甾烷较丰富、Ｔｓ/Ｔｍ＞１低硫芴/氧芴比值、较高含量的Ｃ_２９降新藿烷及重排藿烷类化合物及相对丰富的长链联苯及烷基四氢萘系列化合物。中侏罗统煤－泥页岩层系含生油潜力明显不同的多类型油页岩，多数油页岩属由藻类和陆生高等植物母质组成的混合型有机质，沉积环境为淡水－微咸水弱氧化条件，其地化特征也表现为高Ｐｒ/Ｐｈ比值（平均为１。９８），低甾烷/藿烷及低硫芴/氧芴比值等特征。某些油页岩富含Ｃ_２９降新藿烷及重排藿烷系列化合物，它们应为主力源岩。油页岩多含再沉积型或沉积改造型有机质。异常地热作用对源岩演化及原油地化特征有重要影响。     

铜陵地区老鸦岭层状钼矿床铅同位素组成研究

安徽铜陵老鸦岭矿床中二叠系大隆组(P2d)顶部的含矿(钼矿化)黑色页岩以及附近(立新煤矿)同一层位不含矿黑色页岩的实测铅同位素组成分别为：^206Pb/^204Pb20.20～22.37,^207Pb/^204Pb15.67～15.82,^208Pb/^204Pb38.47～38.60和^206Pb/204Pb18.83～20.80,^207Pb/^204Pb15.65～15.76,^208Pb/^204Pb38．84～39．22。对137Ma的放射成因Pb进行校正后的铅同位素组成表明，含矿黑色页岩和不含矿黑色页岩均与燕山晚期火成岩无关，老鸦岭含矿黑色页岩可能具沉积成因。对沉积(约250Ma)以来的放射成因Pb进行校正后的铅同位素组成表明：不含矿黑色页岩的Pb源自上地壳，而含矿黑色页岩的Pb(因而推测其他成矿金属)可能源于上地壳物质(与不含矿黑色页岩的Pb源相似)与下地壳物质的混合。     

宁夏中卫县沙坡头地区黑色泥质页岩固沙性能研究

我国西北干旱半干旱地区，生态环境极为脆弱，土地沙漠化问题十分突出。防风固沙，恢复植被，遏制沙漠化，改善生态环境，是我国西部大开发战略和加快西部经济腾飞的主要任务之一。防风治沙首先要解决的问题是固沙保水。文章提出了利用宁夏腾格里沙漠东南缘中卫县沙坡头地区香山北麓的黑色泥质页岩在自然条件下天然胶结成壳作用于固沙的可能性。这类黑色泥质页岩具有遇水则吸水软化，风干则形成薄硬壳之特点。在斜坡坡面上或坡脚风化破碎或构造破碎或人工开挖的黑色泥质页岩碎块堆积的表面常形成1层1～5cm的硬壳。这类黑色泥质页岩在500℃时灼减量高达17．56％，说明具有很高的有机质含量，同时P2O5，和K2O含量也较高，有利于成壤和植物生长。黑色泥质页岩的天然胶结成壳作用与地表破碎的黑色泥质页岩堆积和特定的干旱半干旱气候以及本身成分、结构有关。这一硬壳层不但具有一定的强度和抗风蚀能力，而且还具有一定的吸水性和保水性。因此，借鉴草方格固沙方法，就地取材，充分利用黑色泥质页岩在自然条件下的天然胶结成壳性能，用于沙漠治理中的固沙。进一步对黑色泥质页岩天然胶结成壳的机理进行深入研究，并开展黑色泥质页岩固沙试验研究，有可能为腾格里沙漠治理开辟新的途径。     

Large‐scale poroelastic fractured reservoirs modeling using the fast multipole displacement discontinuity method

An effective approach to modeling the geomechanical behavior of the network and its permeability variation is to use a poroelastic displacement discontinuity method (DDM). However, the approach becomes rather computationally intensive for an extensive system of cracks, particularly when considering coupled diffusion/deformation processes. This is because of additional unknowns and the need for time‐marching schemes for the numerical integration. The Fast Multipole Method (FMM) is a technique that can accelerate the solution of large fracture problems with linear complexity with the number of unknowns both in memory and CPU time. Previous works combining DDM and FMM for large‐scale problems have accounted only for elastic rocks, neglecting the fluid leak‐off from the fractures into the matrix and its influence on pore pressure and stress field. In this work we develop an efficient geomechanical model for large‐scale natural fracture networks in poroelastic reservoirs with fracture flow in response to injection and production operations. Accuracy and computational performance of the proposed method with those of conventional poroelastic DDM are compared through several case studies involving up to several tens of thousands of boundary elements. The results show the effectiveness of the FMM approach to successfully evaluate field‐scale problems for the design of exploitation strategies in unconventional geothermal and petroleum reservoirs. An example considering faults reveals the impact of reservoir compartmentalization because of sealing faults for both geomechanical and flow variables under elastic and poroelastic rocks. Copyright © 2015 John Wiley & Sons, Ltd.