Size and shape evolution of pores in a viscoplastic matrix under compression

The frequent use of soils and earth materials for hydraulic capping and for geo‐environmental waste containment motivated our interest in detailed modelling of changes in size and shape of macro‐pores to establish links between soil mechanical behaviour and concurrent changes in hydraulic and transport properties. The objective of this study was to use finite element analysis (FEA) to test and extend previous analytical solutions proposed by the authors describing deformation of a single macro‐pore embedded in linear viscoplastic soil material subjected to anisotropic remote stress. The FEA enables to consider more complex pore geometries and provides a detailed picture of matrix yield behaviour to explain shortcomings of approximate analytical solutions. Finite element and analytical calculations agreed very well for linear viscous as well as for viscoplastic materials, only limited for the case of isotropic remote stress due to the simplifications of the analytical model related to patterns and onset of matrix‐yielding behaviour. FEA calculations were compared with experimental data obtained from a compaction experiment in which pore deformation within a uniform modelling clay sample was monitored using CAT scanning. FEA predictions based on independently measured material properties and initial pore geometry provided an excellent match with experimentally determined evolution of pore size and shape hence lending credence to the potential use of FEA for more complex pore geometries and eventually connect macro‐pore deformation with hydraulic properties. Copyright © 2006 John Wiley & Sons, Ltd.     

Multi-bioindicator study of a small estuary in Vendée (France)

Surficial sediment (about 5 mm) was scraped off in 15 stations selected in the Vie Estuary, a small estuary on the French Atlantic coast. The samples, prepared using the suitable methods, were used for comparing the behaviour of periphytic algae, sporopollinic and other palynologic material, ostracoda and foraminifera for proposing a synthetic evaluation of the information provided by each of them. Dinoflagellate cysts, which are found in an almost monospecific assemblage in low-salinity water, are dispersed by tidal currents, but the location of tintinnids in only the lower reaches shows a limited inward transport. Sporopollinic material is clearly related to the adjacent vegetation, indicating a local origin, and then little influence of transport on the microbenthos, even if fragments of freshwater crustaceans and of Pediastrum alga are found down to the mouth in the sporopollinic deposits. This limited transport of microbenthos allows the use of periphytic algae, benthic ostracoda and benthic foraminifera as indicators of local environmental conditions. It was then possible to determine the extent of marine influence in the estuary, to discriminate between the main channel and adjacent basins, and between different stages of evolution of the basins, from a recently dug basin to a eutrophicated one.     

泥晶灰岩地层孔壁坍塌掉块现象及处理

在灰岩地区钻探施工过程中，常见孔壁坍塌、掉块现象，尤其在含泥晶灰岩地层分布区钻进过程中，这种现象尤为突出，轻则影响钻探施工效率，重则造成钻探孔内事故。针对孔内坍塌、掉块现象的征兆及特点，提出了相对应的处理办法。     

Monitoring of Over Cutting Area and Lubrication Distribution in a Large Slurry Pipe Jacking Operation

Slurry pipe jacking was firmly established as a special method for the non-disruptive construction of the underground pipelines of sewage systems. Pipe jacking, in its traditional form, has occasionally been used for short railways, roads, rivers, and other projects. Basically the system involves the pushing or thrusting of concrete pipes into the ground by a number of jacks. In slurry pipe jacking, during the pushing process, mud slurry and lubricant are injected into the face and the over cutting area that is between the concrete pipes and the surrounding soil. Next, the slurry fills voids and the soil stabilizes due to the created slurry cake around the pipes. Fillings also reduce the jacking force or thrust during operation. When the drivage and pushing processes are finished, a mortar injection into the over cutting area is carried out in order to maintain permanent stability of the surrounding soil and the over cutting area. Successful lubrication around the pipes is extremely important in a large diameter slurry pipe jacking operation. Control of lubrication and gaps between pipes and soil can prevent hazards such as surface settlement and increases in thrust. Also, to find voids around the pipes after the jacking process, in order to inject mortar for permanent stabilizing, an investigation around the pipes is necessary. To meet these aims, this paper is concerned with the utilization of known methods such as the GPR (Ground Penetrating Radar) system and borehole camera to maintain control of the over cutting area and lubricant distribution around the pipes during a site investigation. From this point of view, experiments were carried out during a tunnel construction using one of the largest cases of slurry pipe jacking in Fujisawa city, Japan. The advantages and disadvantages of each system were clarified during the tests.     

环境矿物材料治理镉（Cd^2＋）污染研究进展

近年来,环境矿物材料以其经济、有效、无二次污染等特点,在重金属废水处理和土壤修复方面显示出了众多优势,可替代传统的镉污染处理方法。本文综述了国内外环境矿物材料在处理镉污染方面的研究进展,并对今后应用环境矿物材料治理镉污染提出了一些建议。     

某地平板玻璃原料用石英砂的提纯研究

某地石英矿砂通过磁选分离法、稀酸浸泡法处理后，矿砂不同程度地降低了铁、铝、钙镁的含量；采用磁选分离 稀酸浸泡法联合处理后，使该地石英砂的化学成分达到了优质的生产平板玻璃用硅质原料的国家标准。     

Estimation of regional material yield from coastal landslides based on historical digital terrain modelling

High‐resolution historical (1942) and recent (1994) digital terrain models were derived from aerial photographs along the Big Sur coastline in central California to measure the long‐term volume of material that enters the nearshore environment. During the 52‐year measurement time period, an average of 21 000 ± 3100 m³ km^?1 a^?1 of material was eroded from nine study sections distributed along the coast, with a low yield of 1000 ± 240 m³ km^?1 a^?1 and a high of 46 700 ± 7300 m³ km^?1 a^?1. The results compare well with known volumes from several deep‐seated landslides in the area and suggest that the processes by which material is delivered to the coast are episodic in nature. In addition, a number of parameters are investigated to determine what influences the substantial variation in yield along the coast. It is found that the magnitude of regional coastal landslide sediment yield is primarily related to the physical strength of the slope‐forming material. Coastal Highway 1 runs along the lower portion of the slope along this stretch of coastline, and winter storms frequently damage the highway. The California Department of Transportation is responsible for maintaining this scenic highway while minimizing the impacts to the coastal ecosystems that are part of the Monterey Bay National Marine Sanctuary. This study provides environmental managers with critical background data on the volumes of material that historically enter the nearshore from landslides, as well as demonstrating the application of deriving historical digital terrain data to model landscape evolution. Published in 2005 by John Wiley & Sons, Ltd.     

A Compilation of Silicon,Rare Earth Element and Twenty‐One other Trace Element Concentrations in the Natural River Water Reference Material SLRS‐5 (NRC‐CNRC)

The natural river water certified reference material SLRS‐5 (NRC‐CNRC) was routinely analysed in this study for major and trace elements by ten French laboratories. Most of the measurements were made using ICP‐MS. Because no certified values are assigned by NRC‐CNRC for silicon and 35 trace element concentrations (rare earth elements, Ag, B, Bi, Cs, Ga, Ge, Li, Nb, P, Rb, Rh, Re, S, Sc, Sn, Th, Ti, Tl, W, Y and Zr), or for isotopic ratios, we provide a compilation of the concentrations and related uncertainties obtained by the participating laboratories. Strontium isotopic ratios are also given.     

山东地区黄土研究综述

山东地区黄土开始堆积时期普遍较晚,目前已见的剖面中,以青州傅家庄剖面堆积厚度最大(30 m以上),起始堆积时间最早,出露的最老层位为L9,TL测年时间约为0.8 Ma B.P.。山东地区黄土成因类型多样,物质来源广泛,其岩性特征与其他地区的黄土有明显的差别;在本地区内部,黄土的差异也比较明显,大体可分为两大成因分布区:渤海湾滨海与岛屿区和鲁中山前区。前者黄土粒度较粗,且普遍含有海相微体化石,其物质来源主要为末次冰期时期出露的渤海陆架物质,西北气流携带而来的内陆远源物质占次要地位。而后者黄土类型成因多样,东部的潍坊、青州黄土分布区,受到末次冰期时强劲冬季风的影响,物质来源主要为北部出露的渤海湾,向西至淄博、济南地区则已逐渐过渡为西北内陆风尘物质成分占据主导。     

铜镍硫化物铼-锇标准物质定值的溯源性讨论及总不确定度评估

对按国家一级标准物质技术规范研制的铜镍硫化物Re-Os标准物质定值的溯源性及其总不确定度进行讨论与评估。铜镍硫化物标准物质样品采用Carius管溶解,高精度的TRITON同位素质谱仪、MAT-262热电离质谱仪、四极杆等离子体质谱仪、多接收器等离子体质谱仪和高分辨四极杆等离子体质谱仪测量Re、Os含量和Os同位素比值,其中Re-Os含量可以溯源至基准物质,而187Os/188Os同位素比值可以溯源至国际纯粹与应用化学联合会(IUPAC)。在定值数据误差计算时,采用国际通用的ISOPLOT软件利用加权的方法对数据进行处理;在合成总不确定度时,考虑了物质的均匀性和稳定性,同时考虑了稀释剂标定和同位素丰度以及称量误差等影响测定因素的不确定度。标准值的不确定度由三部分组成:第一部分是通过所有参与定值数据,采用ISOPLOT软件,利用加权的方法对数据进行计算处理得到的不确定度;第二部分是物质的均匀性和稳定性的不确定度;第三部分是影响测定其他因素的不确定度。