Trace elements contamination of agricultural soils affected by sulphide exploitation (Iberian Pyrite Belt,Sw Spain)

Agricultural soils of the Riotinto mining area (Iberian Pyrite Belt) have been studied to assess the degree of pollution by trace elements as a consequence of the extraction and treatment of sulphides. Fifteen soil samples were collected and analysed by ICP-OES and INAA for 51 elements. Chemical analyses showed an As–Cu–Pb–Zn association related with the mineralisation of the Iberian Pyrite Belt. Concentrations were 19–994 mg kg⁻¹ for As, 41–4,890 mg kg⁻¹ for Pb, 95–897 mg kg⁻¹ for Zn and of 27–1,160 mg kg⁻¹ for Cu. Most of the samples displayed concentrations of these elements higher than the 90th percentile of the corresponding geological dominium, which suggests an anthropogenic input besides the bedrock influence. Samples collected from sediments were more contaminated than leptosols because they were polluted by leachates or by mining spills coming from the waste rock piles. The weathering of the bedrock is responsible for high concentrations in Co, Cr and Ni, but an anthropogenic input, such as wind-blown dust, seems to be indicative of the high content of As, Cu, Pb and Zn in leptosols. The metal partitioning patterns show that most trace elements are associated with Fe amorphous oxy-hydroxides, or take part of the residual fraction. According to the results obtained, the following mobility sequence is proposed for major and minor elements: Mn, Pb, Cd, > Zn, Cu > Ni > As > Fe > Cr. The high mobility of Pb, Cu and Zn involve an environmental risk in this area, even in soils where the concentrations are not so high.     

Trace elements in groundwater as indicators of anthropogenic impact

The distribution of several minor and trace elements mainly in fresh (dominating TDS 160–400 mg/l) groundwater of Latvia have been investigated by the Inductively Coupled Plasma-Mass Spectrometry (ICP-MS) technique. An evaluation of results of about 700 analyses leads to the conclusion that concentrations of these elements is influenced by: pH–Eh conditions, groundwater residence time and diffuse contamination, whereas the role of water-bearing sediments is of secondary importance. Most trace elements are characterised by low mobility under alkaline and reducing conditions; concentrations in confined aquifers are much smaller than the Maximum Permissible Values for drinking water. The strongest anomalies of REE, Al and P were found in shallow groundwater around the former agrochemical storehouses.     

Regional distribution pattern of groundwater heavy metals resulting from agricultural activities

Contaminations of groundwater by heavy metals due to agricultural activities are growing recently. The objective of this study was to evaluate and map regional patterns of heavy metals (Cd, Zn and Cu) in groundwater on a plain with high agricultural activities. The study was conducted to investigate the concentration of heavy metals and distribution in groundwater in regions of Shush Danial and Andimeshk aquifers in the southern part of Iran. Presently, groundwater is the only appropriate and widely used source of drinking water for rural and urban communities in this region. The region covers an area of 1,100 km² between the Dez and Karkhe rivers, which lead to the Persian Gulf. For this study, the region was divided into four sub-regions A, B, C and D. Additionally, 168 groundwater samples were collected from 42 water wells during the earlier months of 2004. The flame atomic absorption spectrometry (AAS-Flame) was used to measure the concentration of heavy metals in water samples and the Surfer software was used for determination of the contour map of metal distribution. The results demonstrated that in all of the samples, Cd and Zn concentrations were below the EPA MCLG and EPA secondary standard, respectively. However, the Cu contents of 4.8 % of all samples were higher than EPA MCL. It is also indicated that the concentrations of metals were more pronounced at the southern part of the studied region than at the others. The analysis of fertilizers applied for agricultural activities at this region also indicated that a great majority of the above-mentioned heavy metals were discharged into the environment. Absence of confining layers, proximity to land surface, excess agricultural activities in the southern part and groundwater flow direction that is generally from the north to the southern parts in this area make the southern region of the Shush plain especially vulnerable to pollution by heavy metals than by other contaminants.     

Background concentrations of elements in surface soils and their changes as affected by agriculture use in the desert-oasis ecotone in the middle of Heihe River Basin,North-west China

The concentrations of twenty four chemical elements in the surface layer of natural desert soils and the cultivated farmland soils were measured at a desert-oasis ecotone in the middle of Heihe river basin, north-west China. Background values were estimated for (a) major elements (Si 335.3 g kg^− 1, Al 49.4 g kg^− 1, Fe 19.1 g kg^− 1, Ca 29.4 g kg^− 1, Mg 8.9 g kg^− 1, K 20.1 g kg^− 1, Na 17.5 g kg^− 1 and P 0.338 g kg^− 1), (b) heavy metals and non-metals (Cr 55.8 mg kg^− 1, Mn 404.8 mg kg^− 1, Ni 17.7 mg kg^− 1, Cu 5.1 mg kg^− 1, Zn 33.7 mg kg^− 1, Pb 15.5 mg kg^− 1 and As 5.2 mg kg^− 1) and (c) other trace elements (Ti 2.0 mg kg^− 1, V 55.3 mg kg^− 1, Co 5.7 mg kg^− 1, Rb 82.4 mg kg^− 1, Sr 232.9 mg kg^− 1, Y 14.7 mg kg^− 1, Zr 194.9 mg kg^− 1, Nb 7.8 mg kg^− 1 and Ba 720.6 mg kg^− 1). After natural desert soil was cultivated for agricultural use, significant changes in element concentrations occurred under tillage, irrigation and fertilisation management. Compared to natural soil, the for the levels of Si, K, Na, Sr, Zr and Ba decreased, and no changes were observed for Rb, while the values of the other 17 elements increase in agricultural soil from 1.2 to 3.5 times. However, their absolute concentrations are still low, suggesting that the arable soil in this region remains comparatively a clean soil. The increased silt, clay and organic carbon content, under long-term irrigation, enriched the fine-grained materials, and application of fertilisers and manure contributed to the accumulation of most elements in arable soil. The accumulation of elements in agricultural soil increased with increasing cultivation years and extent of soil development.     

Steady Response of a Ventilated Thermocline to Enhanced Ekman Pumping

The steady response of the ventilated thermocline to an increase in Ekman pumping is investigated, focusing on the effect of the mixed layer depth distribution on the subsurface density anomaly. We consider only the subtropical gyre, and the mixed layer is assumed to be deep in the northwest and shallow elsewhere with a narrow transition zone separating the deep and shallow mixed layer regions. At the intersection of this narrow transition zone and the outcrop line, low potential vorticity fluid is subducted into and ventilates the thermocline. In such a situation, an enhancement of the Ekman pumping confined to the northern subtropical gyre leads to pronounced subsurface cold anomalies in the southern subtropics, which is free of anomalous forcing. These density anomalies are much greater than those that occur when either the mixed layer depth is zonally uniform or the Ekman pumping is enhanced in the whole subtropical gyre. They are caused by anomalous changes in the trajectory of the low potential vorticity fluid in response to anomalous Sverdrup flow. This revised version was published online in July 2006 with corrections to the Cover Date.     

吉林省发展绿色食品的农业生态环境优势分析

发展绿色食品生产是吉林省实施“生态省”建设工程的主导产业之一，本文按照绿色食品产地环境质量标准要求，客观评价了吉林省发展绿色食品的产地环境条件，得出吉林省具有发展绿色食品生产的显著农业生态环境优势。基于吉林省良好的农业生态环境质量，结合区域自然条件和资源优势，将全省分为东部山区、中部松辽平原区、西部松嫩平原区和大、中城市郊区四种区域类型，并分别提出了其发展绿色食品生产的宏观策略。     

Regulating Land Use Conflict on the Urban Fringe: Two contrasting case studies from the Australian poultry industry

Land use conflict involving farm externalities represents an increasing policy concern in Australia as agricultural activities intensify and as the nation's metropolitan areas continue to expand outwards. A review of the rural-urban fringe literature reveals a noticeable absence of research exploring the intensity of conflict experienced by farmers. Similarly, inadequate attention has been given to the policies adopted by government to manage conflict. This article contrasts the regulatory system that has been implemented to manage conflict involving poultry farming on the metropolitan fringe of two Australian state capitals: Perth, Western Australia and Sydney, New South Wales. Spatial variation in the nature of government intervention is uncovered. In the discussion that follows reasons are identified to help explain such variation including state ideology, metropolitan growth, industry activism, geographical constraints and farm characteristics. It is concluded that where agricultural industries experience internal political divisions and a geographically dispersed membership it becomes more difficult to influence government policy.     

大气中CO2浓度增加对我国农业生产的影响

本文分析了大气中ＣＯ２浓度增加的事实，原因及其发展趋势，结果认为，大气中ＣＯ２浓度上升对我国农业的发展产生了一定的不利影响。因此，为控制大气中ＣＯ２的上升，必须采取相应的有效对策。     

Conservation tillage and input use

 There continues to be a question as to the overall effectiveness of conservation tillage practices in reducing the impact of agricultural production on the environment. While it is generally recognized that water runoff and soil erosion will decline further, as tillage and mulch tillage systems are not used more extensively on cropland, what will happen to pesticide and fertilizer use remains uncertain. To gain some insight into this, the conservation tillage adoption decision is modelled. On the assumption that the decision to adopt conservation tillage is a two-step procedure, the first decision is whether or not to adopt a conservation tillage production system and the second concerns the extent to which conservation tillage should be used – appropriate models of the Cragg and Heckman (dominance) type are estimated. Based on farm-level data on corn production in the United States for 1987, the profile of a farm on which conservation tillage was adopted is that the cropland had above-average slope and experienced above-average rainfall, the farm was a cash grain enterprise, and it had an above-average expenditure on pesticides and a below-average expenditure on fuel and custom pesticide applications. Additionally, for a farm adopting a no-tillage production practice, an above-average expenditure was made on fertilizer. Received: 18 September 1995 · Accepted: 6 December 1995     

基于RS和GIS的农业土地利用污染分析

农业已被确认为地表和地下水最主要的非点源污染源，而土地利用方式又是影响非点源污染的关键性因素。大规模的土地利用与开发、化肥与农药用量的增加、规模养殖业的发展、生活垃圾的增加等，这些非点污染源严重威胁水体质量，进而影响到人们的生活。为了更好地预测和控制、管理非点源污染，必须研究其负荷定量化问题。本文从以上几方面入手，讨论了非点源污染与农业土地利用方式之间的关系，利用组件GIS技术，以网格为评价单元，实现非点源污染负荷的定量计算及可视化分析。文章最后以上海市松江区作为研究区域，对该区的污染情况进行了分析。