The double solid reactant method: II. An application to the shallow groundwaters of the Porto Plain,Vulcano Island (Italy)

This paper presents an example of application of the double solid reactant method (DSRM) of Accornero and Marini (Environmental Geology, 2007a), an effective way for modeling the fate of several dissolved trace elements during water–rock interaction. The EQ3/6 software package was used for simulating the irreversible water–rock mass transfer accompanying the generation of the groundwaters of the Porto Plain shallow aquifer, starting from a degassed diluted crateric steam condensate. Reaction path modeling was performed in reaction progress mode and under closed-system conditions. The simulations assumed: (1) bulk dissolution (i.e., without any constraint on the kinetics of dissolution/precipitation reactions) of a single solid phase, a leucite-latitic glass, and (2) precipitation of amorphous silica, barite, alunite, jarosite, anhydrite, kaolinite, a solid mixture of smectites, fluorite, a solid mixture of hydroxides, illite-K, a solid mixture of saponites, a solid mixture of trigonal carbonates and a solid mixture of orthorhombic carbonates. Analytical concentrations of major chemical elements and several trace elements (Cr, Mn, Fe, Ni, Cu, Zn, As, Sr and Ba) in groundwaters were satisfactorily reproduced. In addition to these simulations, similar runs for a rhyolite, a latite and a trachyte permitted to calculate major oxide contents for the authigenic paragenesis which are comparable, to a first approximation, with the corresponding data measured for local altered rocks belonging to the silicic, advanced argillic and intermediate argillic alteration facies. The important role played by both the solid mixture of trigonal carbonates as sequestrator of Mn, Zn, Cu and Ni and the solid mixture of orthorhombic carbonates as scavenger of Sr and Ba is emphasized.

岩石破坏前后曲线分类及脆-延转换围压研究——蚀变岩常规三轴压缩试验Ⅰ

蚀变岩是工程中少见的软弱岩类,在西南某重大水电工程中,蚀变岩处于工程的重要部位,为保证工程的长期稳定性,对蚀变岩力学特性进行了深入全面的试验研究.通过对孔隙度不同的饱水蚀变岩进行系统的常规三轴压缩试验和总结分析,提出了蚀变岩三轴压缩下破坏前应力.应变曲线可分为3大类,破坏后应力-应变曲线亦可分为3大类的形态模式.并得出结论:蚀变岩的破坏类型受围压与孔隙度的共同影响,在给定的12 MPa围压下蚀变岩以脆性破坏为主,只有孔隙度大于16%且围压大于4 MPa时才有可能进入脆-延转换状态,且脆-延转换围压随孔隙度增加而降低,临界状态应力比随孔隙度增大而增加.     

海上不同高度风速换算关系的研究

本文用海上石油平台上观测的风梯度资料,计算了在不同风况下海面摩擦速度和粗糙高度。结果表明,海面摩擦速度u_*与海上10m高度处风速u_(10)的关系为u_*=0.055u_(10)-0.058。在4—5级风时,海面平均摩擦速度为50cm/s,粗糙度为0.022m,它相当于陆上的平均粗糙高度。在风速为2—3级时,二者与海上通常采用的数据接近。文中最后给出了上述两种风况下海上不同高度的换算系数。     

斜带髭鲷幼鱼生长和生态转换效率的研究

在实验室内, 22. 5±0. 5℃条件下以去头去骨去鳞片去皮的金色小沙丁鱼的纯肉糜为饵料饲养斜带髭鲷幼鱼,测定体重范围在 4. 6~6. 5g的斜带髭鲷的体重、体长的生长曲线及其生态转换效率和特定生长率.实验结果表明,斜带髭鲷的体重、体长在实验期间直线增长,体重、体长的生长曲线分别为Wt(w.w.湿重,下同 ) =0. 391 7t 5. 766 2(R=0. 999 6)和Lt=0. 105t 6. 265(R=0. 989 9).用胃含物法测定斜带髭鲷的胃排空率、日摄食量、日生长量、生态转换效率和特定生长率.实验得到斜带髭鲷消化道的瞬时排空率Rt= 1. 23 4×10-3 (m/m) /h,日摄食量Cd= 1. 342 9g(w.w. ),生态转换效率Eg=29. 50% ±2. 77% [m/m(w.w. ) ],特定生长率SGR=4. 71%±0. 69% [m/m(w.w. ) ].     

溴素的有机化学──Ⅴ.溴代脂肪酸—2,3,5,6—四溴—1,4—苯二酯的合成

以1，4—苯二酚和不同的短链脂肪酸为基本原料，经溴代、加成、形成酰卤和酰化等反应，合成了六种新的溴化脂肪酸—2，3，5，6—四溴—1，4—苯二酯。通过对产物的碳、氢、溴等元素的定量分析，以及红外吸收光谱和氢核磁共振谱的研究，验证了化合物的结构。     

In situ determination on food consumption and ecological conversion efficiency of a marine fish species, Hyporhamphus sajori

The food consumption and ecological conversion efficiency of a species marine pelagic andsmall size fish, Hyporhamphus sajori, were determined by using in situ stomach content method presented by Eggers. The results showed that: (1) the fish was taken in food all day, so empty-stomach rate was very low, taking up about 4.5% of the total determined fish number. However, the fish still has significant daily feeding rhythm. A feeding peak was found 0:00 o'clock at night, but feeding level was always high in the daytime; (2) relationship between instantaneous food content in stomach and corresponding time could be described as S_t = a ·e ~(-b ·t). There was not significant difference of instantaneous gastric evacuation rate between two determinations, with average value being 0.13 × 10~(-2)g/ (g·d) (wet weight); (3) the daily food consumption tended to change in irregular waving form, with average value being (10.16×l0~(-2)±1.19×l0~(-2) g/ (g·d) (wet weight) or (55.56 × 10~(-2) ±6.51 × 10~(-2) kJ/     

6-DMAP诱导缢蛏三倍体的研究

用6-DMAP抑制受精卵第二极体排放的方法诱导缢蛏三倍体的试验．结果表明：6-DMAP在100～500μmol／dm^3处理浓度范围内均可以诱导出三倍体，随着药物处理浓度和处理时间的提高，三倍体倍化率和D形幼虫畸形率有不同程度的提高，而D形幼虫孵化率会随之下降．综合来看，在30％卵子受精并出现第一极体，6-DMAP浓度为300μmol／dm^3和处理持续时间为20min时的处理组的处理效果优于其他处理组组合．     

不同生长期坛紫菜多糖中组分含量的变化

于１９９０－１９９１年，运用＾１３Ｃ－ＮＭＲ和化学分析方法研究南方产和移植北方养殖的不同生长发育阶段坛紫菜多糖的组分变化，结果表明，随着藻体生长发育，坛紫菜琼胶中３，６－内醚－Ｌ－半乳糖和６－ＯＣＨ３－Ｄ－半乳糖的含量逐渐增加，而硫酸基的含量呈现先增加后减少的规律；北移坛紫菜琼胶中３，６－内醚－Ｌ－半乳糖的含量高于南方坛紫菜，而硫酸基和６－ＯＣＨ３－Ｄ－半乳糖的含量低于南方坛紫菜。     

溴素的有机化学──I．2，4，6－三溴苯甲酸溴代和非溴代芳酯的合成

用ｍ－氨基苯甲酸作原料，经溴代、重氮化、还原脱氨、酰氯化和酯化反应等步骤，合成了六种新型的三溴苯甲酸的溴代和非溴代芳酯，即；双（２，４，６－三溴苯甲酸）－２＇，３＇，５＇，６＇－四溴－１＇，４＇－苯二酯，２，４，６－三溴苯甲酸－２＇，３＇，４＇，５＇，６＇－五溴苯酯，２，４，６－三溴苯甲酸－２＇，４＇，６＇－三溴苯酯，２，４，６－三溴苯甲酸－４＇－溴苯酯，２，４，６－三溴苯甲酸－４＇－甲基苯酯和２，４，６－三溴苯甲酸苯酯．通过对产物中碳、氢、溴元素的定量分析以及红外吸收光谱和氢核磁共振谱的研究，验证了合成产物的结构。