The double solid reactant method: II. An application to the shallow groundwaters of the Porto Plain,Vulcano Island (Italy)

This paper presents an example of application of the double solid reactant method (DSRM) of Accornero and Marini (Environmental Geology, 2007a), an effective way for modeling the fate of several dissolved trace elements during water–rock interaction. The EQ3/6 software package was used for simulating the irreversible water–rock mass transfer accompanying the generation of the groundwaters of the Porto Plain shallow aquifer, starting from a degassed diluted crateric steam condensate. Reaction path modeling was performed in reaction progress mode and under closed-system conditions. The simulations assumed: (1) bulk dissolution (i.e., without any constraint on the kinetics of dissolution/precipitation reactions) of a single solid phase, a leucite-latitic glass, and (2) precipitation of amorphous silica, barite, alunite, jarosite, anhydrite, kaolinite, a solid mixture of smectites, fluorite, a solid mixture of hydroxides, illite-K, a solid mixture of saponites, a solid mixture of trigonal carbonates and a solid mixture of orthorhombic carbonates. Analytical concentrations of major chemical elements and several trace elements (Cr, Mn, Fe, Ni, Cu, Zn, As, Sr and Ba) in groundwaters were satisfactorily reproduced. In addition to these simulations, similar runs for a rhyolite, a latite and a trachyte permitted to calculate major oxide contents for the authigenic paragenesis which are comparable, to a first approximation, with the corresponding data measured for local altered rocks belonging to the silicic, advanced argillic and intermediate argillic alteration facies. The important role played by both the solid mixture of trigonal carbonates as sequestrator of Mn, Zn, Cu and Ni and the solid mixture of orthorhombic carbonates as scavenger of Sr and Ba is emphasized.

溴素的有机化学──Ⅴ.溴代脂肪酸—2,3,5,6—四溴—1,4—苯二酯的合成

以1，4—苯二酚和不同的短链脂肪酸为基本原料，经溴代、加成、形成酰卤和酰化等反应，合成了六种新的溴化脂肪酸—2，3，5，6—四溴—1，4—苯二酯。通过对产物的碳、氢、溴等元素的定量分析，以及红外吸收光谱和氢核磁共振谱的研究，验证了化合物的结构。     

动态基准实时测量系统的开发与应用

介绍了动态基准实时测量系统的硬件组成、站点上全站仪棱镜组合安装与检测方法、系统软件的开发及特点，最后对系统在广州地铁某地铁站结构变形自动监测中的应用情况进行了阐述。通过实际应用表明该系统能应用在自动化、高精度的变形监测领域。     

6-DMAP诱导缢蛏三倍体的研究

用6-DMAP抑制受精卵第二极体排放的方法诱导缢蛏三倍体的试验．结果表明：6-DMAP在100～500μmol／dm^3处理浓度范围内均可以诱导出三倍体，随着药物处理浓度和处理时间的提高，三倍体倍化率和D形幼虫畸形率有不同程度的提高，而D形幼虫孵化率会随之下降．综合来看，在30％卵子受精并出现第一极体，6-DMAP浓度为300μmol／dm^3和处理持续时间为20min时的处理组的处理效果优于其他处理组组合．     

不同生长期坛紫菜多糖中组分含量的变化

于１９９０－１９９１年，运用＾１３Ｃ－ＮＭＲ和化学分析方法研究南方产和移植北方养殖的不同生长发育阶段坛紫菜多糖的组分变化，结果表明，随着藻体生长发育，坛紫菜琼胶中３，６－内醚－Ｌ－半乳糖和６－ＯＣＨ３－Ｄ－半乳糖的含量逐渐增加，而硫酸基的含量呈现先增加后减少的规律；北移坛紫菜琼胶中３，６－内醚－Ｌ－半乳糖的含量高于南方坛紫菜，而硫酸基和６－ＯＣＨ３－Ｄ－半乳糖的含量低于南方坛紫菜。     

溴素的有机化学──I．2，4，6－三溴苯甲酸溴代和非溴代芳酯的合成

用ｍ－氨基苯甲酸作原料，经溴代、重氮化、还原脱氨、酰氯化和酯化反应等步骤，合成了六种新型的三溴苯甲酸的溴代和非溴代芳酯，即；双（２，４，６－三溴苯甲酸）－２＇，３＇，５＇，６＇－四溴－１＇，４＇－苯二酯，２，４，６－三溴苯甲酸－２＇，３＇，４＇，５＇，６＇－五溴苯酯，２，４，６－三溴苯甲酸－２＇，４＇，６＇－三溴苯酯，２，４，６－三溴苯甲酸－４＇－溴苯酯，２，４，６－三溴苯甲酸－４＇－甲基苯酯和２，４，６－三溴苯甲酸苯酯．通过对产物中碳、氢、溴元素的定量分析以及红外吸收光谱和氢核磁共振谱的研究，验证了合成产物的结构。     

4-溴苯甲酸-2,3,4,5,6-五溴苯酯的合成(英文)

以苯酚和4—溴苯甲酸为原料,合成一种尚未见文献记载的新化合物——4—溴苯甲酸—2,3,4,5,6—五溴苯酯,用无水三氯化铝催化苯酚的全溴化。此产物可望在阻燃剂方面得到应用。     

基于放样原理的特种罐内测法容量计量技术

特种罐在能源的储备和运输中具有重要意义,在研究特种罐现有容量计量技术的基础上,自主创新提出了基于放样原理和测量机器人实现特种罐容量快速和精密计量的原理和方法。将特种罐容量计量转化为点位放样问题,较好地克服了全站仪现有测量技术的缺点,并利用软件实现了特种罐容量计量的数据采集、数据计算、数据修正和报表输出的一体化。通过实际测量数据,分析了该方法的测量精度和测量效率。     

Study on the connectivity of heavy oil reservoirs by ultraviolet spectrum technique in the western part of the QHD32-6 oilfield

As a new method, the ultraviolet spectrum technique is applied to studying the connectivity of biode-gradable heavy oil reservoirs. The similarity of crude oils can be judged according to the extinction coefficient （E） because aromatic hydrocarbons and non-hydrocarbons have conjugated bonds and obvious absorption in the ultraviolet range, and different materials have different characteristics and additives. The relationship diagram is made in terms of the extinction coefficients （E） of the samples by taking E as the Y-axis and wavelength as the X-axis. The connectivity of oil reservoirs is estimated according to the curve positions and characteristic fingerprints of the sampies. The connectivity of part of the reservoirs in the western part of the QHD32-6 oilfield was studied with this method. The results showed that the connectivity of samples from wells F7 and F8 in the Nm-2 oil reservoir zone is good, that of samples from wells F17 and F20 in the Nm-1 oil reservoir zone also is good, and that of samples from wells F17, F19, and F20 is poor.