Sorption of Ni on Na-rectorite studied by batch and spectroscopy methods

Sorption of Ni²⁺ on Na-rectorite as a function of contact time, temperature, pH and fulvic acid (FA)/humic acid (HA) was studied under ambient conditions. A pseudo-second-order rate equation was used to simulate the kinetic sorption. The removal of Ni²⁺ increased with increasing pH. The presence of FA/HA enhanced the sorption of Ni²⁺ at low pH values, whereas no drastic effect of FA/HA on Ni²⁺ uptake to rectorite was found at high pH values. The diffuse layer model (DLM) fitted the experimental data of Ni²⁺ sorption in the absence and presence of FA/HA very well with the aid of FITEQL 3.2. The Langmuir, Freundlich and Dubinin–Radushkevich (D–R) models were used to simulate the sorption isotherms of Ni²⁺ at different temperatures. The thermodynamic data (ΔH⁰, ΔS⁰, ΔG⁰) were calculated from the temperature dependent sorption isotherms and the results suggested that the sorption process of Ni²⁺ on rectorite was spontaneous and endothermic. The sorption and species of Ni²⁺ on rectorite in the presence and absence of FA/HA was also investigated and characterized by XPS. The spectroscopic analysis indicated no drastic structural changes of Na-rectorite and the sorption of Ni²⁺ mainly occurred on the surface and at the edge position of Na-rectorite.     

Origin and evolution of alkali basaltic magma in the Okinawa Trough

I~IOXThe Okinawa Trough is an extending back--arc basin between the East China Sea Shelf andthe Ry'Ukyu Island Arc of Japan. There are widespreadly distributing acid pumice in the troughand a little basalt just in some area of the extending center. There have been some detailed rePOrtsabout the mineralogy and petrochemical feature of the subalkali tholeiite and alkali trachyte in thetrough (Zhai and Gan, 1995; Li et al., 1997; Qin and Zhai, 1988). This paper mainly reportselectron mic…     

基于BSP-15下低码率实时H.264编码器的实现

根据低码率实时应用领域的特点,对H.264的新编码特性进行了分析选择,提出了一套合适的编码方案,在编码性能和编码复杂度之间平衡;利用BSP-15 DSP芯片硬件的特点,设计了H.264编码器,并在DSP上实现.实验结果表明,H.264编码器对CIF大小的图像实现了实时编码.     

地震波混合阶褶积算法模拟

基于正反傅立叶变换,提出了地震波模拟的混合阶褶积算法。该方法原理简单、易于实现,结合了有限差分与伪谱法的优点,具有较高的精度和计算效率,适用于地震波场的正演计算,同时还给出了二维地震波场的理论计算实例。计算结果表明,此算法模拟结果正确、精度高、速度快、能适应较为复杂地质模型,并且易于推广到各向异性介质中去。     

山东车镇凹陷东部古近系沙河街组成岩作用

车镇凹陷沙河街组的沉积体系受控于盆地内的构造、物源供给以及沉积时的气候环境。以岩石学特征为基础，描述了成岩过程中压实与压溶作用、胶结作用、溶解作用与次生孔隙的特征，以及次生孔隙带在本区的分布。论述了碳酸盐胶结物与粘土矿物胶结作用的特点。粘土矿物蒙脱石-伊利石转变具有明显的渐变与突变交替的演化程式，其演化经历了蒙脱石带、渐变带、迅速转化带和伊利石带以及蒙脱石向伊利石的转变带。沙河街组的成岩作用划分为早期成岩阶段（A期、B期）和晚期成岩阶段（A期、B期、C期），并提出了成岩阶段的划分标志。     

全谱直读等离子发射光谱法直接测定天然矿泉水中的SO2-4

采用全谱直读等离子发射光谱(ICP-AES)直接测定天然矿泉水中SO2-4的方法在优化工作条件下SO42-的测定下限为0.09mgL-1,方法简便,快速,适用于批量生产.     

GIS支持下青海湖地区草地蝗虫发生的地形分析

草地蝗虫发生的地形分析是建立草地蝗虫发生预报模型的基础，以青海湖地区为实验区，在Arc/Info和ArcView地理信息系统的支持下，进行草地蝗虫发生与各地形变量（包括海拔高度、坡度与坡向）的叠置分析，提取草地蝗虫发生的地形信息数据库，然后，分别采用T－检验（对连续变量－海拔高度和坡度）和卡方（Chisquare)检验（对类变量－坡向类型）进行各地形变量对草地蝗虫发生的差异显著性检验，结果表明，海拔高度和坡度对草地蝗虫发生的影响极为显著（显著性水平p=0.000)，而坡向地草地蝗虫发生的影响不是特别明显（显著性水平p=0.039)。     

Water discharge changes of the Changjiang River downstream Datong during dry season

Based on hydrometric data and extensive investigations on water-extracting projects, this paper presents a preliminary study on water discharge changes between Datong and Xuliujing during dry season. The natural hydrological processes and human factors that influence the water discharge are analyzed with the help of GIS method. The investigations indicate that the water-extracting projects downstream from Datong to Xuliujing had amounted to 64 in number by the end of 2000, with a water-extracting capacity up to 4,626 m3/s averaged in a tidal cycle. The water extraction from the Changjiang River has become the most important factor influencing the water discharge downstream Datong during dry season. The potential magnitude in water discharge changes are estimated based on historical records of water extraction and a water balance model. The computational results were calibrated with the actual data. The future trend in changes of water discharge into the sea during dry season was discussed by taking into consideration of newly built hydro-engineering projects. The water extraction downstream Datong in dry season before 2000 had a great influence on discharges into the sea in the extremely dry year like 1978-1979. It produced a net decrease of more than 490 m3/s in monthly mean discharges from the Changjiang into the sea. It is expected that the water extraction will continually increase in the coming decades, especially in dry years, when the net decrease in monthly mean water discharge will increase to more than 1000 m3/s and will give a far-reaching effect on the changes of water discharge from the Changjiang into the sea.     

陕西省地下水水质监测发展探析

本文针对陕西省地下水水质监测控制范围局限于农灌区，监测项目单一的现状，通过分析研究，提出水质监测的发展思路，剖析实现新思路的相关条件。     

2001年7月27日临汾区域性暴雨天气过程分析

本文应用数值预报产品，常规天气图，卫星云图及大气探测等资料，对2001年7月27日临汾区域性暴雨天气过程产生的环流形势，水汽和热力条件及动力机制进行了分析和研究，进一步揭示临汾市暴雨发生的环境流场和物理量场的特征。