Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.     

沂水崔家峪玻璃用石英砂岩矿地质特征

沂水崔家峪玻璃用石英砂岩矿床赋存于早寒武世李官组砂岩段中．呈近水平的层状产出。因其岩石坚硬．矿体呈环山的平台状分布。矿体厚度大，矿石品级高，特级品矿石二氧化硅平均含量98．47％，铁杂质平均含量0．043％(选矿后，铁杂质含量可降至0．02％以下)，为一优质玻璃硅质原料矿床。矿石为细一中粒石英砂岩，粒度以中粒为主，矿石由碎屑颗粒和胶结物组成，碎屑成分含量为97％～98％．其中绝大部分是石英颗粒．具典型的砂屑结掏。该矿床属滨海陆源沉积矿床。     

海岩小说的几种叙述模式及弊端

海岩的长篇小说《河流如血》再创出版高记录，但作家仍局限于特有的小说叙述模式，这部作品设能做到相应的创新。概言之，模式第一面是“刑侦＋恋爱”；模式第二面是“财子＋佳人”；模式第三面是“道德＋法制”。文学创作需要不断创新，创新的过程也是对创作模式的不断突破过程。作家应该警惕的是，不要让模式成为创作的桎梏。     

Tidal effects on temperature front in the Yellow Sea

Temperature front (TF) is one of the important features in the Yellow Sea, which forms in spring, thrives in summer, and fades in autumn as thermocline declines. TF intensity ⋎S _T ⋎ is defined to describe the distribution of TF. Based on the MASNUM wave-tide-circulation coupled model, temperature distribution in the Yellow Sea was simulated with and without tidal effects. Along 36°N, distribution of TF from the simulated results are compared with the observations, and a quantitative analysis is introduced to evaluate the tidal effects on the forming and maintaining processes of the TF. Tidal mixing and the circulation structure adapting to it are the main causes of the TF. Supported by the National Basic Research Program of China (No. G1999043809) and the National Science Foundation of China (No. 49736190).     

毫秒级快速尖峰辐射事件的时间和频率特性

介绍了太阳22周峰年期间云南天文台米波射电频谱仪的观测结果。主要对1557个单个Spike的时间和频率分布作了统计分析，着重指出太阳快速精细结构的观测特征并定性地指出其产生机制。     

PALEOSOLS OF SANDY LANDS AND ENVIRONMENTAL CHANGES IN THE WESTERN PART OF NORTHEAST PLAIN OF CHINA WESTERN DURING HOLOCENE

ＰＡＬＥＯＳＯＬＳＯＦＳＡＮＤＹＬＡＮＤＳＡＮＤＥＮＶＩＲＯＮＭＥＮＴＡＬＣＨＡＮＧＥＳＩＮＴＨＥＷＥＳＴＥＲＮＰＡＲＴＯＦＮＯＲＴＨＥＡＳＴＰＬＡＩＮＯＦＣＨＩＮＡＷＥＳＴＥＲＮＤＵＲＩＮＧＨＯＬＯＣＥＮＥ￥ＱｉｕＳｈａｎｗｅｎ（裘善文）ＬｉＱｕｓ...     

Remarks on dynamical ellipticity at the Earth's

In this paper, two factors — the redistribution of the density and the variation in the angular velocity of the Earth rotation, that affect the adopted value of the flattening for equidensity surface within the Earth, are discussed. The computational results show that the contribution of the redistribution of the density in the Earth interior (especially in the core) on the change of the flattening at the core-mantle boundary (CMB) is marginal, and that the calculated value of the flattening at the CMB can be in good agreement with the VLBI observed value so long as the fact that the angular velocity of the Earth rotation has undergone the tidal evolution is taken into account. As a result, this paper presents a set of recommended values of the dynamical parameters of the Earth (see Table III) for computing Earth's forced nutation series.     

巴颜喀拉山东段及其邻区大地电磁测深成果地质解释

本文主要依据青海省囊歉至大河坝大地电磁测深成果,并结合重力资料对巴颜喀拉及南北两侧地区的壳幔结构进行了地质解释。指出了该区壳幔存在4个明显的低阻层,并简述了它们的形态特征,推断了其地质含意。认为昆中断裂带与昆南断裂带间是一个巨大的构造混杂岩带,影响深度亦很大。推断该区可能存在太古代地层。划出了8条壳幔断裂带,认为昆中断裂应是塔里木—华北板块与华南板块的分界线。     

5个新发现的X选BL Lac天体

利用ＲＯＳＡＴＶＬＡ方法筛选，从ＲＯＳＡＴＸ射线源中选出了一批新的ＢＬＬａｃ天体和类星体的候选体．１９９６年１２月８日至１７日，利用北京天文台２．１６ｍ望远镜和新从美国引进的ＯＭＲ摄谱仪，对这批新候选体进行了光谱认证．经ＳＵＮ工作站处理，又发现了５个新的Ｘ选ＢＬＬａｃ天体．此外，还对去年作者在ＯＭＲ引进之前发现的ＢＬＬａｃ天体进行了检验，结果发现，去年发现的７个ＢＬＬａｃ天体中，２３２２＋３４３的ＣａＩＩＨ＆Ｋ“Ｂｒｅａｋｓｔｒｅｎｇｔｈ”为２６．９％，稍大于判据２５％，因此，２３２２＋３４３到底是ＢＬＬａｃ天体还是射电星系还有待于进一步测光及偏振观测的验证．     

Simulation of double cold cores of the 35°N section in the Yellow Sea with a wave-tide-circulation coupled model

Based on the MASNUM wave-tide-circulation coupled numerical model, the temperature structure along 35°N in the Yellow Sea was simulated and compared with the observations. One of the notable features of the temperature structure along 35°N section is the double cold cores phenomena during spring and summer. The double cold cores refer to the two cold water centers located near 122°E and 125°E from the depth of 30m to bottom. The formation, maintenance and disappearance of the double cold cores are discussed. At least two reasons make the temperature in the center (near 123°E) of the section higher than that near the west and east shores in winter. One reason is that the water there is deeper than the west and east sides so its heat content is higher. The other is invasion of the warm water brought by the Yellow Sea Warm Current (YSWC) during winter. This temperature pattern of the lower layer (from 30m to bottom) is maintained through spring and summer when the upper layer (0 to 30m) is heated and strong thermocline is formed. Large zonal span of the 35°N section (about 600 km) makes the cold cores have more opportunity to survive. The double cold cores phenomena disappears in early autumn when the west cold core vanishes first with the dropping of the thermocline position. Supported by the National Basic Research Program of China (No. G1999043809) and the National Science Foundation of China (No. 49736190).