Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.     

万维望远镜平台下基于ASSURE模式的天文教学研究

随着教学手段和教学方法的现代化,信息技术与课程整合正成为教育改革的研究热点。文章以万维望远镜(WWT)平台为教学媒体,以ASSURE模式为教学设计的理论依据,设计并构建用以指导天文教学准备、实施与评价的教学模式,并将该模式应用于“四季星空”的教学案例中,使用基于信息技术的互动分析编码系统和学生课程反馈调查对教学效果进行分析和评价。研究表明,万维望远镜的使用可以降低教师言语比率,改变传统天文教学中以讲授式为主的教学方式。它适合起点能力较高、对新知识和新技能掌握能力较强的学生,能提高其学习兴趣和积极性,激发其探索宇宙的兴趣,有助于培养学生的科学素养。     

红阳煤田石炭-二叠纪含煤地层的沉积特征

红阳煤田含煤地层太原组与山西组,是一套典型的“海陆交互相”沉积。依据剖面上沉积相序列变化特点,可划分为14个沉积旋回,每个沉积旋回均含有一层煤。有二种聚煤环境:一是海水退出潮坪后形成的泥炭沼泽聚积的煤层;二是扇三角洲平原形成的泥炭沼泽聚积的煤层。     

Preliminary investigation of mercury in bone tissues of skua and penguin in Antarctica using AFS and Synchrotron Radiation X-ray Fluorescence （SR-XRF）

Mercury （Hg） was investigated in bone tissues of skua （ Catharacta maccormick） and penguin （Pygoscelis adeliae） collected in the maritime Antarctic using atomic fluorescence spectrometry （AFS） and synchrotron radiation X-ray fluorescence （SR-XRF） method. The total levels of mercury in bone tissues of penguin and skua are much lower than those in other organs （e. g. , kidney, liver）. The toxic effects of mercury in bone tissues of seabirds in polar region are not known. We have used SR- XRF method to map the distribution of trace levels of mercury in bones. The levels of mercury are found to be enriched somewhere near the periosteal surface and/or endosteal surface. The distribution of mercury shows strongly correlation with that of some essential elements and probably poses negative effect on the bone metabolism inferring from the relationship of mercury with the other elements. These studies represent a first step toward understanding the toxic effects of mercury on bone of polar animals by suggesting the possible microscopic investigation.     

Bacterial productivity in the Prydz Bay and its adjacent waters,Antarctic

1　IntroductionBacteriaandtheiractivitiesplayanimportantroleintheelementalbiogeochemicalcyclesandenergytransformingintheocean (Zhenetal.1 997) .DortchandPackard(1 989) proposedthatfoodwebsintheeutrophicwatersaredominatedbythebiomassofprimaryproducerswhilefoodwebsintheoligotrophicwatersaredominatedbythebiomassofmicrobes.Heterotrophicbacteriahadbeenshowntoplayanimportantroleinthedecompositionoflarge ,rapidlysinkingorganicparticleswithinandbelowtheeuphot iczone ,andfurthertoaffecttheelementaldyn…     

Dust supply from river floodplains: the case of the lower Huang He (Yellow River) recorded in a loess–palaeosol sequence from the Mangshan Plateau

The Mangshan Plateau is located on the south bank of the Huang He (Yellow River) just west of the city of Zhengzhou, well outside the Loess Plateau in central China. Mixing models of the grain‐size data indicate that the loess deposits are mixtures of three loess components. Comparison of the mixing model with existing models established for a series of loess–palaeosol sequences from the Loess Plateau indicates that the Mangshan loess has been supplied from a proximal dust source, the Huang He floodplain, during major dust outbreaks. The high accumulation rates, the composition of the loess components, and especially the high proportions of a sandy loess component support this. Owing to the exceptionally high accumulation rates, the Mangshan grain size, magnetic susceptibility and carbonate records provide a high‐resolution archive of environmental and climate change. Copyright © 2008 John Wiley & Sons, Ltd.     

An approximate method for evaluating the shear band thickness in saturated soils

A formula for the thickness of a shear band formed in saturated soils under a simple shear or a combined stress state has been proposed. It is shown that the shear band thickness is dependent on the pore pressure properties of the material and the dilatancy rate, but is independent of the details of the combined stress state. This is in accordance with some separate experimental observations. Copyright © 2004 John Wiley & Sons, Ltd.     

Evolution of Electric Currents Associated with Two M-Class Flares

Using one-minute cadence vector magnetograms from Big Bear Solar Observatory (BBSO), we analyze the temporal behavior of derived longitudinal electric currents associated with two flares on July 26, 2002. One of the events is an M1.0 flare which occurred in active region NOAA 10044, while the other is an M8.7 flare in the adjacent region 10039. Rapid changes of magnetic fields in the form of flux emergence are found to be associated with both of these events. However, the temporal behavior of electric currents are very different. For the M1.0 flare, the longitudinal electric current density drops rapidly near the flaring neutral line; while for the M8.7 flare, the current density rapidly increases, confirming the picture of the current-carrying flux emergence. We offer a possible explanation for such a difference: magnetic reconnection at different heights for the two events, near the photosphere for the M1.0 flare, and higher up for the M8.7 flare.