Sorption of Ni on Na-rectorite studied by batch and spectroscopy methods

Sorption of Ni²⁺ on Na-rectorite as a function of contact time, temperature, pH and fulvic acid (FA)/humic acid (HA) was studied under ambient conditions. A pseudo-second-order rate equation was used to simulate the kinetic sorption. The removal of Ni²⁺ increased with increasing pH. The presence of FA/HA enhanced the sorption of Ni²⁺ at low pH values, whereas no drastic effect of FA/HA on Ni²⁺ uptake to rectorite was found at high pH values. The diffuse layer model (DLM) fitted the experimental data of Ni²⁺ sorption in the absence and presence of FA/HA very well with the aid of FITEQL 3.2. The Langmuir, Freundlich and Dubinin–Radushkevich (D–R) models were used to simulate the sorption isotherms of Ni²⁺ at different temperatures. The thermodynamic data (ΔH⁰, ΔS⁰, ΔG⁰) were calculated from the temperature dependent sorption isotherms and the results suggested that the sorption process of Ni²⁺ on rectorite was spontaneous and endothermic. The sorption and species of Ni²⁺ on rectorite in the presence and absence of FA/HA was also investigated and characterized by XPS. The spectroscopic analysis indicated no drastic structural changes of Na-rectorite and the sorption of Ni²⁺ mainly occurred on the surface and at the edge position of Na-rectorite.     

亚热带沿海景观的旅游保护性开发及建设探讨--以福建沿海为例

依据地貌学和风景学的角度,福建沿海景观以闽江口和九龙江口为界可分为3个景观亚区,并具有多样性与复杂性、动态性与脆弱性和关联性与分异性等特征.本文运用景观生态的原理研究沿海景观的构成与格局,在沿海景观的分类和特征概括的基础上,探讨福建沿海景观旅游开发与建设的模式.通过维护沿海景观系统的稳定,优化沿海各景观亚区的分布格局,提高沿海景观的整体舒适性和挖掘文化景观的内涵等应对措施以实现福建沿海旅游的科学发展.     

Origin and evolution of alkali basaltic magma in the Okinawa Trough

I~IOXThe Okinawa Trough is an extending back--arc basin between the East China Sea Shelf andthe Ry'Ukyu Island Arc of Japan. There are widespreadly distributing acid pumice in the troughand a little basalt just in some area of the extending center. There have been some detailed rePOrtsabout the mineralogy and petrochemical feature of the subalkali tholeiite and alkali trachyte in thetrough (Zhai and Gan, 1995; Li et al., 1997; Qin and Zhai, 1988). This paper mainly reportselectron mic…     

黔北遵义团溪铝土矿勘探网密度探讨

以黔北遵义团溪铝土矿后槽矿区一矿块为例,用50m×50m工程间距进行施工成果与100m×50m和100m×100m工程间距施工成果,对其矿体厚度、矿体形态、主要化学成分含量及储量变化进行分析对比,以探寻此类矿床应如何选择工程间距,才能更合理准确地对矿体进行圈定控制,以满足矿山开采设计的要求。通过资料分析对比认为,对黔北喀斯特型沉积铝土矿进行勘查而言,以≤50m×50m工程间距控制矿体并求取储量,效果较为理想。     

基于BSP-15下低码率实时H.264编码器的实现

根据低码率实时应用领域的特点,对H.264的新编码特性进行了分析选择,提出了一套合适的编码方案,在编码性能和编码复杂度之间平衡;利用BSP-15 DSP芯片硬件的特点,设计了H.264编码器,并在DSP上实现.实验结果表明,H.264编码器对CIF大小的图像实现了实时编码.     

地面核磁共振模型约束反演含水层参数

导电模型的地面核磁共振感应电动势是含水量的非线性函数.引入模型约束的迭代反演方法求解该非线性问题的反演.在反演过程中,根据理论公式计算迭代过程中灵敏度矩阵,并采用平坦模型和光滑模型两种约束.对均匀半空间、层状导电模型和实际数据进行了反演模拟,结果表明,模型约束迭代反演方法能从地面核磁共振感应电动势获得含水层较为合理的含水量及分布,且该结果可以从作为初始模型的均匀含水量分布反演得到.对无噪音数据,平坦模型和光滑模型约束对反演的含水量分布影响不大;但当数据存在一定的噪音时,平坦模型约束将比光滑模型约束获得更为精确的含水层参数.     

青藏高原腹地湖泊沉积对第四纪晚期古季风变化的响应

通过对青藏高原腹地的综合科学考察和对中心钻孔岩芯剖面的最新研究,用层序地层学与年代地层学和气候地层学相结合的方法,分辨出可可西里地区湖泊沉积记录(孔深7.25 m)的第四纪晚期距今3万余年以来的古气候变化,沉积物磁化率等因子综合表征的高原古季风变化是波动发展的,发生在仙女木期地质环境事件中的季风活动具有强烈暴发的特点,是高原季风发展中的突变事件,而且地表热点效应对其起到了激发作用。综合分析的研究成果表明,它的变化频谱与激变因子及其运行机制是伴随着青藏高原地质效应的演变而发展的,为研究第四纪冰消期以来的气候变化提供了新的信息。     

松溪县域城镇体系发展研究

城镇体系建设是当今加快城市化进程的重要组成部分。本文通过对松溪县域城镇现状的调查,从城镇体系的等级规模结构、空间布局结构、职能结构3个方面剖析其发展中存在的一些问题。从建设社会主义新农村、改善人居环境的角度出发,提出相应的发展思路和建议,为松溪县“十一五”期间制定城镇发展战略提供一定的参考。     

山东车镇凹陷东部古近系沙河街组成岩作用

车镇凹陷沙河街组的沉积体系受控于盆地内的构造、物源供给以及沉积时的气候环境。以岩石学特征为基础，描述了成岩过程中压实与压溶作用、胶结作用、溶解作用与次生孔隙的特征，以及次生孔隙带在本区的分布。论述了碳酸盐胶结物与粘土矿物胶结作用的特点。粘土矿物蒙脱石-伊利石转变具有明显的渐变与突变交替的演化程式，其演化经历了蒙脱石带、渐变带、迅速转化带和伊利石带以及蒙脱石向伊利石的转变带。沙河街组的成岩作用划分为早期成岩阶段（A期、B期）和晚期成岩阶段（A期、B期、C期），并提出了成岩阶段的划分标志。     

Water discharge changes of the Changjiang River downstream Datong during dry season

Based on hydrometric data and extensive investigations on water-extracting projects, this paper presents a preliminary study on water discharge changes between Datong and Xuliujing during dry season. The natural hydrological processes and human factors that influence the water discharge are analyzed with the help of GIS method. The investigations indicate that the water-extracting projects downstream from Datong to Xuliujing had amounted to 64 in number by the end of 2000, with a water-extracting capacity up to 4,626 m3/s averaged in a tidal cycle. The water extraction from the Changjiang River has become the most important factor influencing the water discharge downstream Datong during dry season. The potential magnitude in water discharge changes are estimated based on historical records of water extraction and a water balance model. The computational results were calibrated with the actual data. The future trend in changes of water discharge into the sea during dry season was discussed by taking into consideration of newly built hydro-engineering projects. The water extraction downstream Datong in dry season before 2000 had a great influence on discharges into the sea in the extremely dry year like 1978-1979. It produced a net decrease of more than 490 m3/s in monthly mean discharges from the Changjiang into the sea. It is expected that the water extraction will continually increase in the coming decades, especially in dry years, when the net decrease in monthly mean water discharge will increase to more than 1000 m3/s and will give a far-reaching effect on the changes of water discharge from the Changjiang into the sea.