Hydrogeochemical evolution of groundwater in a Mediterranean coastal aquifer, Mersin-Erdemli basin (Turkey)

In this study, hydrogeologic and hydrochemical information from the Mersin-Erdemli groundwater system were integrated and used to determine the main factors and mechanisms controlling the chemistry of groundwaters in the area and anthropogenic factors presently affecting them. The PHREEQC geochemical modeling demonstrated that relatively few phases are required to derive water chemistry in the area. In a broad sense, the reactions responsible for the hydrochemical evolution in the area fall into four categories: (1) silicate weathering reactions; (2) dissolution of salts; (3) precipitation of calcite, amorphous silica and kaolinite; (4) ion exchange. As determined by multivariate statistical analysis, anthropogenic factors show seasonality in the area where most contaminated waters related to fertilizer and fungicide applications that occur during early summer season.     

Biosorption optimization and equilibrium isotherm of industrial dye compounds in novel strains of microscopic fungi

The aim of this study was to evaluate the biosorption capacity of selected strains of microscopic fungi. We optimized the biosorption process and used the Freundlich isotherm for three strains: H. haematococca BwIII43, K37 and T. harzianum BsIII33 to describe the biosorption equilibrium of anthraquinone dye, Alizarin Blue Black B (ABBB) and alkali lignin (AL). In optimal conditions (1 g of mycelium biomass, pH = 7.0, 28 °C) for ABBB and AL sorption, the live biomass of H. haematococca BwIII43 was characterized by a higher sorption capacity, amounting to 247.47 and 161.00 mg g^?1, respectively. The highest sorption properties toward anthraquinone dye (K _F = 19.96 mg g^?1) were shown for the biomass of H. haematococca K37. In the presence of alkali lignin, the highest sorption capacity and bond strength exhibited the biomass of H. haematococca BwIII43 (K _F = 28.20 mg g^?1, n = 3.46). Effective decolorization of ABBB and AL by the selected strains of microscopic fungi indicated that the biosorption process additionally enhanced the removal of color compounds from the solution.     

Composition of barian mica in multiphase solid inclusions from orogenic garnet peridotites as evidence of mantle metasomatism in a subduction zone setting

Multiphase solid inclusions in minerals formed at ultra-high-pressure (UHP) provide evidence for the presence of fluids during deep subduction. This study focuses on barian mica, which is a common phase in multiphase solid inclusions enclosed in garnet from mantle-derived UHP garnet peridotites in the Saxothuringian basement of the northern Bohemian Massif. The documented compositional variability and substitution trends provide constraints on crystallization medium of the barian mica and allow making inferences on its source. Barian mica in the multiphase solid inclusions belongs to trioctahedral micas and represents a solid solution of phlogopite KMg₃(Si₃Al)O₁₀(OH)₂, kinoshitalite BaMg₃(Al₂Si₂)O₁₀(OH)₂ and ferrokinoshitalite BaFe₃(Al₂Si₂)O₁₀(OH)₂. In addition to Ba (0.24–0.67 apfu), mica is significantly enriched in Mg (X_Mg ~ 0.85 to 0.95), Cr (0.03–0.43 apfu) and Cl (0.04–0.34 apfu). The substitution vector involving Ba in the I-site which describes the observed chemical variability can be expressed as BaFe^IVAlClK_?1Mg_?1Si_?1(OH)_?1. A minor amount of Cr and ^VIAl enters octahedral sites following a substitution vector ^VI(Cr,Al)₂□^VI(Mg,Fe)_?3 towards chromphyllite and muscovite. As demonstrated by variable Ba and Cl contents positively correlating with Fe, barian mica composition is partly controlled by its crystal structure. Textural evidence shows that barian mica, together with other minerals in multiphase solid inclusions, crystallized from fluids trapped during garnet growth. The unusual chemical composition of mica reflects the mixing of two distinct sources: (1) an internal source, i.e. the host peridotite and its garnet, providing Mg, Fe, Al, Cr, and (2) an external source, represented by crustal-derived subduction-zone fluids supplying Ba, K and Cl. At UHP–UHT conditions recorded by the associated diamond-bearing metasediments (c. 1100 °C and 4.5 GPa) located above the second critical point in the pelitic system, the produced subduction-zone fluids transporting the elements into the overlying mantle wedge had a solute-rich composition with properties of a hydrous melt. The occurrence of barian mica with a specific chemistry in barium-poor mantle rocks demonstrates the importance of its thorough chemical characterization.     

塔里木盆地西北缘二叠系礁灰岩的时空分布特征及其油气地质意义

对塔里木盆地西北缘二叠系礁灰岩的岩石、岩相、沉积演化和油气地质特征的分析表明,生物礁主要发育于中二叠统栖霞阶昆克拉契组和巴立克立克组,以亮晶藻粘结灰岩为主,具有堤礁的特点。二叠系礁灰岩较大的厚度表明,当时礁体生长速率与礁基沉降（或水体加深）的速率匹配较好,具有进积型沉积的特点,这与当时塔里木地块内部的退积型沉积特点是不一致的。礁灰岩的原生孔隙较小,可以作为中等烃源岩,在哈拉峻盆地的东南侧和乌什凹陷北缘的覆盖区之下可能构成与礁灰岩相关的油气远景区。     

Über die echographische Aufzeichnung des Verhaltens von Meeresfischen während der Sonnenfinsternis vom 30. Juni 1954

Summary Echo records from the Atlantic west of the Faroe Islands are presented which, for the first time, give evidence of the influence exerted by day on the vertical movement of pelagic fishes by a considerable reduction of luminous intensity (solar eclipse). This phenomenon corresponds with the fact well known since some years from investigations in the North Sea which prove that by night pelagic fishes move in a vertical direction according to the variation in luminous intensity.

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Sur des enregistrements ultra-sonores caractérisant le comportement des poissons pélagiques pendant l'éclipsé de soleil au 30 juin 1954

Résumé On présente des enregistrements ultra-sonores faits en océan Atlantique à l'ouest de l'archipel de Færoé. Ces enregistrements font, pour la première fois, preuve de l'influence exercée de jour sur le mouvement vertical des poissons pélagiques par une réduction sensible de l'intensité lumineuse (éclipse de soleil). Ce phénomène correspond avec le fait bien connu depuis quelques ans par des recherches dans la mer du Nord. Suivant ces recherches, les poissons pélagiques se meuvent nuitamment dans la direction verticale suivant la variation de l'intensité lumineuse.

     

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