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1.
Summary ?A single-crystal X-ray investigation was performed on crystals of P21/c natural pigeonite with varying Ca and Fe* ( = Fe2+ + Mn2+) contents, in order to verify the effect of microtextural disorder on structure refinements and to constrain the crystal
chemistry of pigeonite. Antiphase domains and exsolution lamellae affect differently the refinement results. In a crystal
free of exsolution the structure obtained after refinement with all reflections is an average of that of the antiphase domains
and of their boundaries, whereas in an exsolved crystal it represents only the structure of the prevailing pigeonite lamellae.
The refinement using only h + k odd reflections seems to give the structure of the Ca-free pigeonite characteristic of the antiphase domains rather than
that of Ca-rich domain walls. The ratio of the scale factors in refinements with all reflections and with only h + k odd reflections allows the ratios of the exsolved augite and pigeonite phases to be estimated.
The crystal chemistry of the investigated samples follows the trends outlined by data on Ca-free and Fe-free synthetic samples.
In particular, it is shown that Ca and Fe* substitution for Mg induce similar changes in the average structure, i.e. both induce an expansion in the M1 polyhedron and
decrease the difference between the M2–O3 distances.
Received October 18, 2001; revised version accepted February 15, 2002 相似文献
2.
At first-order of approximation a sea-state may be considered as an infinite sum of Airy components with angular frequencies ωi and wave-number vectors ki. A second-order analysis shows the co-existence of long waves appearing at the difference frequencies ωi—ωj with wave-number vectors ki—kj. In shallow water they become appreciable in amplitudes and may induce slow-drift motion of moored structures.For small values of ωi—ωj,ki—kj may take all kinds of directions for an angular-spread wave system. Then it may be questioned how the in-line and transverse second-order accelerations compare to those obtained for a mono-directional wave-system.This analysis is carried out here by relating the spectra of the second-order horizontal accelerations to the directional wave-spectrum. Numerical applications are first performed for deep water. They show that at low frequencies, even for very narrowly spread wave systems, the transverse component is larger than the in-line component. In shallow water both components are dratically reduced as compared to the mono-directional case. As a consequence one may question the validity of model-testings or numerical models which take no account of the directionality of the wave-system. 相似文献
3.
Summary The crystal-chemistry of clinopyroxene from a suite of Sunda arc volcanic rocks was investigated by X-ray structure refinement and microprobe analysis. Relationships with clinopyroxene from volcanic rocks of the intraplate environment were highlighted.Sunda clinopyroxenes were distinguished into two groups. The first consists of clinopyroxene from SiO2-saturated rock types and crystal rim from SiO2-undersaturated rock types, the second of crystal core from SiO2-undersaturated rock types. The crystal chemical behaviour of the two groups differs significantly, mainly in the geometrical relationships between M2 and T sites. While in the first group M2-O3 and T-O3 bond lengths shorten and lengthen respectively due to Ca and AlIV increase, in the second group in which M2 site is almost fully coordinated by Ca, -O3 bond lengths are forced to lengthen in spite of low AlIV content, in order to mantain the local charge balance around the O3 oxygens.It is noteworthy that Sunda clinopyroxene shows strong analogies with that from basaltic rocks from the Ethiopian plateau and K-rich lavas from the Roman Province respectively, reflecting similarities between the composition and mineralogical assemblages of the host rocks, although they all came from different tectonic environments. A relationship between intracrystalline Mg-Fe 2+ disorder and the explosive character of the volcanism is demonstrated.
Kristallchemie von Klinopyroxenen aus Gesteinen des Vulkanbogens der Sunda-Inseln
Zusammenfassung Die Kristallchemie von Klinopyroxenen aus einer Serie von vulkanischen Gesteinen des Sunda-Bogens wurde mit Röntgen-Strukturverfeinerungen und Mikrosonden-analysen untersucht. Beziehungen zu Klinopyroxenen vulkanischer Gesteine aus intra-Plattenpositionen werden beleuchtet. Die Sunda-Klinopyroxene wurden in zwei Gruppen eingeteilt. Die erste umfaßt Klinopyroxene SiO2-gesättigter Gesteinstypen und Kristallsäume SiO2-untersättigter Gesteinstypen, die zweite Kristallkerne SiO2-untersättigter Gesteinstypen. Das kristallchemische Verhalten der beiden Gruppen unterscheidet sich beträchtlich, hauptsächlich in den geometrischen Beziehungen zwischen den M2 und T Positionen. Während in der ersten Gruppe die M2-O3 und T-O3 Bindungsldngen durch Zunahme von Ca und AlIV kleiner bzw. größer werden, sind in der zweiten Gruppe die T-O3 Bindungslängen trotz niedrigen AlIV Gehaltes zu einer Vergrößerung gezwungen, damit um die O3 Atome der lokale Ladungsausgleich erhalten bleibt.Es ist bemerkenswert, daß die Sunda-Klinopyroxene große Analogien zu denen aus basaltischen Gesteinen des Abessinischen Plateaus und aus K-reichen Laven sowohl der Römischen Provinz als auch des Westafrikanischen Grabens zeigen. Dies spiegelt Ähnlichkeiten zwischen Zusammensetzung und Mineralbestand der Muttergesteine wider, obwohl sie all aus tektonisch unterschiedlichen Positionen kommen.Eine Beziehung zwischen intrakristalliner Mg-Fe2+ Unordnung und dem explosiven Charakter des Vulkanismus wird aufgezeigt.相似文献
4.
Estuaries act as an organic matter and nutrient filter in the transition between the land, rivers and the ocean. In the past, high nutrient and organic carbon load and low oxygen concentration made the Elbe River estuary (NW Europe) a sink for dissolved inorganic nitrogen. A recent reduction in loads and subsequent recovery of the estuary changed its biogeochemical function, so that nitrate is no longer removed on its transition towards the coastal North Sea. Nowadays in the estuary, nitrification appears to be a significant nitrate source. To quantify nitrification and determine actively nitrifying regions in the estuary, we measured the concentrations of ammonium, nitrite and nitrate, the dual stable isotopes of nitrate and net nitrification rates in the estuary on five cruises from August 2012 to August 2013. The nitrate concentration increased markedly downstream of the port of Hamburg in summer and spring, accompanied by a decrease of nitrate isotope values that was clearest in summer exactly at the location where nitrate concentration started to increase. Ammonium and nitrite peaked in the Hamburg port region (up to 18 and 8 μmol L?1, respectively), and nitrification rates in this region were up to 7 μmol L?1 day?1. Our data show that coupled re-mineralization and nitrification are significant internal nitrate sources that almost double the estuary’s summer nitrate concentration. Furthermore, we find that the port of Hamburg is a hot spot of nitrification, whereas the maximum turbidity zone (MTZ) only plays a subordinate role in turnover of nitrate. 相似文献
5.
Active tectonic morphology and submarine deformation of the northern Gulf of Eilat/Aqaba from analyses of multibeam data 总被引:1,自引:0,他引:1
Gideon Tibor Tina M. Niemi Zvi Ben-Avraham Abdallah Al-Zoubi Ronnie A. Sade John K. Hall Gal Hartman Emad Akawi Abdelrahmem Abueladas Rami Al-Ruzouq 《Geo-Marine Letters》2010,30(6):561-573
A high-resolution marine geophysical study was conducted during October-November 2006 in the northern Gulf of Aqaba/Eilat,
providing the first multibeam imaging of the seafloor across the entire gulf head spanning both Israeli and Jordanian territorial
waters. Analyses of the seafloor morphology show that the gulf head can be subdivided into the Eilat and Aqaba subbasins separated
by the north-south-trending Ayla high. The Aqaba submarine basin appears starved of sediment supply, apparently causing erosion
and a landward retreat of the shelf edge. Along the eastern border of this subbasin, the shelf is largely absent and its margin
is influenced by the Aqaba Fault zone that forms a steep slope partially covered by sedimentary fan deltas from the adjacent
ephemeral drainages. The Eilat subbasin, west of the Ayla high, receives a large amount of sediment derived from the extensive
drainage basins of the Arava Valley (Wadi ’Arabah) and Yutim River to the north–northeast. These sediments and those entering
from canyons on the south-western border of this subbasin are transported to the deep basin by turbidity currents and gravity
slides, forming the Arava submarine fan. Large detached blocks and collapsed walls of submarine canyons and the western gulf
margin indicate that mass wasting may be triggered by seismic activity. Seafloor lineaments defined by slope gradient analyses
suggest that the Eilat Canyon and the boundaries of the Ayla high align along north- to northwest-striking fault systems—the
Evrona Fault zone to the west and the Ayla Fault zone to the east. The shelf–slope break that lies along the 100 m isobath
in the Eilat subbasin, and shallower (70–80 m isobaths) in the Aqaba subbasin, is offset by approx. 150 m along the eastern
edge of the Ayla high. This offset might be the result of horizontal and vertical movements along what we call the Ayla Fault
on the east side of the structure. Remnants of two marine terraces at 100 m and approx. 150 m water depths line the southwest
margin of the gulf. These terraces are truncated by faulting along their northern end. Fossil coral reefs, which have a similar
morphological appearance to the present-day, basin margin reefs, crop out along these deeper submarine terraces and along
the shelf–slope break. One fossil reef is exposed on the shelf across the Ayla high at about 60–63 m water depth but is either
covered or eroded in the adjacent subbasins. The offshore extension of the Evrona Fault offsets a fossil reef along the shelf
and extends south of the canyon to linear fractures on the deep basin floor. 相似文献
6.
Eric J.E. Molin Harmen Oppewal Harry J.P. Timmermans 《Journal of Geographical Systems》2002,4(4):343-358
In this paper, two approaches for measuring residential group preferences, based on the method of Hierarchical Information
Integration (HII), are compared. In particular, the hypothesis that group-based preference models estimated from integrated
HII experiments better predict group preferences than part individual-based group models estimated from classical HII experiments
is tested. To that effect, the models' ability to predict group preferences for new residential alternatives is compared in
a study of residential preferences of co-ops. Results indicate that integrated HII group experiments indeed result in better
predictions of residential preferences. 相似文献
7.
镇江市古运河边岸滑坡干扰了城市交通、航运和河道整治工程的正常运行。本文研究了城市边岸的工程环境、滑坡形态、特有的城市地质环境恶化所诱发的边岸破坏机制及其稳定性,它对我同城市水陆交通发展所导致的斜坡地质灾害及其治理有实用价值。 相似文献
8.
利用树轮宽度重建黄河源区1618—2009年5—6月最高气温 总被引:1,自引:0,他引:1
利用采集自青海省雪山乡的祁连圆柏建立树轮宽度标准年表,将标准年表与黄河源区内4个气象站各气象要素作相关分析,结果显示整个源区5—6月最高气温与标准年表相关性最显著,相关系数为-0.65。根据相关分析结果,重建了黄河源区1618—2009年5—6月最高气温距平序列,重建方程经过逐一剔除检验,方差解释量达42.2%,具有一定的可靠性。重建序列在近400年间先后经历了8个较暖时间段和8个较冷时间段,暖期时段有1644—1656、1727—1746、1786—1797、1817—1835、1860—1885、1916—1934、1952—1968和1992—2005年,冷期的时段分别为1632—1643、1657—1696、1747—1764、1798—1816、1836—1859、1898—1915、1935—1951和1969—1991年。对比本次重建序列与杂多、青藏高原东部以及长江源的气温重建序列,发现以上序列在公共时段变化趋势一致,另外,一些文献和历史记载也证实了此次重建的可靠性。 相似文献
9.
Deep-sea corals have been shown to be useful archives of rapid changes in ocean chemistry during the last glacial cycle. Their aragonitic skeleton can be absolutely dated by U-Th data, freeing radiocarbon to be used as a water-mass proxy. For certain species of deep-sea corals, the growth rate allows time resolution that is comparable to ice cores. An additional proxy is needed to exploit this opportunity and turn radiocarbon data into rates of ocean overturning in the past.Neodymium isotopes in seawater can serve as a quasi-conservative water-mass tracer and initial results indicate that deep-sea corals may be reliable archives of seawater Nd isotopes. Here we present a systematic study exploring Nd isotopes as a water-mass proxy in deep-sea coral aragonite. We investigated five different genera of modern deep-sea corals (Caryophyllia, Desmophyllum, Enallopsamia, Flabellum, Lophelia), from global locations covering a large potential range of Nd isotopic compositions. Comparison with ambient seawater measurements yields excellent agreement and suggests that deep-sea corals are reliable archives for seawater Nd isotopes.A parallel study of Nd concentrations in these corals yields distribution coefficients for Nd between seawater and coral aragonite of 1-10, omitting one particular genus (Enallopsamia). The corals and seawater did however not come from exactly the same location, and further investigations are needed to reach robust conclusions on the incorporation of Nd into deep-sea coral aragonite.Lastly, we studied the viability of extracting the Nd isotope signal from fossil deep-sea corals by carrying out stepwise cleaning experiments. Our results show that physical removal of the ferromanganese coating and chemical pre-cleaning have the highest impact on Nd concentrations, but that oxidative/reductive cleaning is also needed to acquire a seawater Nd isotope signal. 相似文献
10.
Stratified cultural remains from the Early Roman/Nabataean to Byzantine periods in the coastal zone of Aqaba, Jordan, and analyses of thirteen sediment cores provide evidence for changes in the depositional environment during the Holocene. The overall trend in subsurface sediments is a basal marine transgressive layer overlain by a regressional sequence of embayment lagoonal sediments identified from microfossil analyses, and backshore pond, alluvium, and eolian deposits until the 1st century B.C., when mudbrick structures appear. Based on two radiocarbon dates, a brackish water coastal embayment formed prior to ca. 5900–5700 B.C. and was subsequently filled by siltation. Local tectonic subsidence along faults of the Dead Sea transform may have helped form the lagoon. Freshwater Candona sp. ostracods found in sand layers in the lagoon facies show signs of having been transported and redeposited. These data indicate that lakes or marshes were likely located inland of the study area. Supporting faunal and floral evidence for wetter climatic conditions, wetland habitats, and extensive water diversion and agricultural terraces has been excavated at late Chalcolithic (4000–3500 B.C.) sites in the Aqaba region (Khalil & Schmidt, 2009 ). By the 8th century B.C., the depositional environment along the coastal plain of Aqaba was dominated by distal alluvial fan and eolian sedimentation and the shoreline had prograded about 400m seaward. The migration of human settlements since the 8th century B.C. from the center of the valley toward the southeast may be driven by the changing course of Wadi Yutim and conditions along the coastal plain. © 2010 Wiley Periodicals, Inc. 相似文献