Investigation of the hydrate reservoir production under different depressurization modes

Abstract

Large reserves of natural gas hydrates exist, and the depressurization method has the greatest potential for gas hydrate reservoir recovery. Currently, the most commonly adopted depressurization simulation method is a constant bottom-hole pressure production scheme. This study proposes a new depressurization mode with decreasing bottom-hole pressure. The production characteristic was numerically investigated using this method. The results show the following: (1) As the depressurization exponent (n) decreases, the development effect improves, and production indexes including cumulative gas production/dissociation and gas-water ratio increase. However, the reservoir energy consumption is higher and the hydrate reformation is more severe. (2) Compared to the proposed depressurization mode, the hydrate production index of the constant bottom-hole pressure production (n?=?0) is better. However, the hydrate reservoir energy consumption is higher and the hydrate reformation is more severe using constant bottom-hole pressure production. (3) To achieve a balance between production and reservoir energy consumption during depressurization production, the bottom-hole pressure should be controlled by selecting a suitable depressurization exponent between n_min and n_max, which can be determined through numerical simulations.     

黄茅海河口湾现代动力地貌体系和冲淤过程分析

1980—1993年对黄茅海河口湾进行沉积物采样和水流测定及水深测量。根据水动力和地形条件，冲淤分析及Mclaren模型研究河口湾的动力地貌体系、冲淤特征和现代沉积物运移。结果表明：（1）水下地形主要为下泄流或上溯流控制的“深槽－槽沟－浅滩－湾口”的动力地貌体系，反映了河口湾“东进西出”的水流格局；（2）整个河口湾以淤积为主，只有崖门深槽有较明显的优势冲刷特征，并随着崖门深槽向海推移和河口湾“东进西出”水动力作用，黄茅海落潮三角洲相应向西南进积；（3）应用Mclaren模型揭示了黄茅海河口湾现代沉积物运移规律，同样反映了河口湾具有“东进西出”的运移趋势。     

关于马尾藻代替部分粮食和矿物质饲喂肉鸡的探讨

用含有5％、10％和15％的马尾藻组成的饲料饲喂肉用仔鸡,发现10％以内对肉用仔鸡的生长速度没有不良影响,但10％与15％的马尾藻饲料对饲料利用效率降低。只有5％的马尾藻组与对照组相近,10％和15％的海藻组均比对照组低。用3％的马尾藻粉代替微量元素添加剂,发现其生长速度和饲料利用效率均高于对照组,生长速率提高4.7—7.7％,饲料利用效率比对照组高3.2％—6.0％。马尾藻饲料组对仔鸡的成活率没有影响     

Al hematites prepared by homogeneous precipitation of oxinates: material characterization and determination of the Morin transition

A novel method for synthesis of aluminium hematites, based upon the homogeneous precipitation of Fe and Al oxinates in various proportions, is presented. The precursor precipitates are heated in air at 700?°C. X-ray diffraction, thermal analyses, BET, FTIR, optical reflection analysis, TEM and Mössbauer spectroscopy at room temperature and 80?K of the resulting products indicate that single-phase hematites are formed with structural Al substitution of up to 10 at%. Interestingly, the particle size (>100?nm) is not substantially reduced by the Al content. Although it remains difficult to obtain a homogeneously distributed Al substitution in the final hematite, this processing line offers a unique opportunity to separate the effects of grain size and Al substitution on the Morin transition temperature (T _M) of Al hematite. From the comparison between the present hematites and a series of Al-substituted hematites with lepidocrocite as precursor, it could be shown that the effect on T _M, associated with a change of a factor 10 in grain size, is about 1/3 of the effect caused by a change of 10 in the degree of substitution. Finally, it is suggested that proper thermal treatments under different conditions of the same precursors are likely to produce spinel phases.     

Mixing, sediment accumulation and focusing using 210Pb and 137Cs

The Portil lagoon is a natural freshwater reservoir located at the southwest of Spain, near the coast. In its surroundings an important tourist complex has been developed since the earlier 1970s. This has resulted in increased loads of nutrients, specially during summer months. In order to evaluate the impact from humans on the lagoon caused by anthropogenic activities, we have determined vertical profiles of excess ²¹⁰Pb and ¹³⁷Cs in a sediment core taken from its bottom. Vertical profile of excess ²¹⁰Pb seems to indicate that the sediment core was affected by large-scale mixing processes. Nevertheless this possibility was ruled out based on the shape of the ¹³⁷Cs vertical distribution after modelling the ¹³⁷Cs profile considering large-scale mixing. The chronology developed from ²¹⁰Pb and ¹³⁷Cs has allowed us to calculate the temporal evolution of the mass sedimentation rate during the last century. This mass sedimentation rate increased in 1973: from 0.08(2) g cm^-2 a^-1 in the period 1900-1973 to 0.17(5) g cm^-2 a^-1 in the period 1973-1995. This increase could be related to land-movements in the drainage area and to permitted sewage inputs into the lagoon, both with its origin in the growing/running of the surrounding tourist complex.     

“地球动力学”的研究现状与展望——第32届国际地质大会研究成果综述

第32届国际地质大会通过按地域和构造作用过程等形式划分11个专题会场,展示了地球动力学的研究成果。其成果主要包括特提斯域构造演化及其不同阶段的块体裂解、拼合及后期改造的细节过程,地质历史中的超大陆分布和成因,俯冲—碰撞带深部构造和变质机制,安第斯山(Andes)缓倾角平坦式俯冲过程及其地壳变形和岩浆作用的响应,显微构造对动力作用过程的影响和控制,地壳和上地幔熔融、流变学和动力学意义,大洋岩石圈构造与演化,大陆地盾区构造和再活动,稳定大陆区地震,空间大地测量学和现代板块运动等方面。这些研究成果充分显示了地球动力学研究具有多学科、多手段(如古地磁、超深钻、地球物理、大地测量和GPS等)、多尺度(宏观、微观)和多时期、全面、综合、并逐步接近定时、定位和定量地探索和研究的特点,它从地球(主要为上地幔和地壳)的组成、结构构造入手,逐步认识地球(主要为地球岩石圈)的演化和动力学。     

Bioaccumulation of heavy metals in <Emphasis Type="Italic">Limnobium laevigatum</Emphasis> and <Emphasis Type="Italic">Ludwigia peploides</Emphasis>: their phytoremediation potential in water contaminated with heavy metals

Contamination with heavy metals in surface and groundwater is a threat to human health and ecosystems. Due to this, the need arises to remediate water polluted through ecological and profitable technologies, such as phytoremediation. The objective of the work was to evaluate the concentration of lead (Pb) and zinc (Zn) in the floating macrophytes Limnobium laevigatum and Ludwigia peploides, after being exposed to contaminated water experimentally. In this way to be able to determine if these plants have mechanisms that allow them to accumulate the metals in the roots and to perform the translocation of these to different vegetative organs, L. laevigatum and L. peploides were placed in solutions contaminated with Pb ([Pb]?=?5 mg/l) and Zn ([Zn]?=?20 mg/l). The concentrations of metals in water, root and leaf samples were evaluated as a function of time (0, 1, 2 and 4 days). The determination of the metals was performed by the atomic absorption spectrophotometry technique. After 4 days of exposure to Pb and Zn, the plants showed high metal removal efficiencies of water, more to 70% in all cases. Pb was accumulated fundamentally by roots, while Zn was accumulated more in the leaves. In addition, the bioconcentration and translocation factors for each metal were calculated.     

新疆四顶黑山花岗岩体锆石LA-ICP-MS U-Pb年龄及地质意义

新疆东天山位于中亚造山带南缘,天山—兴安造山系北天山造山带东段,发育大量泥盆纪—石炭纪花岗岩,其形成过程多与觉罗塔格洋的俯冲作用有关。四顶黑山花岗岩体位于东天山觉罗塔格构造岩浆带的东端,岩体在地表呈不规则状产出,侵位于元古界片岩-变火山岩、奥陶系变玄武岩和泥盆系雀儿山群火山岩;主要岩石类型为花岗岩和花岗闪长岩。花岗岩的LA-ICP-MS锆石U-Pb年龄为380.4 Ma±3.7 Ma,表明岩体形成于晚泥盆世。岩石表现出高硅(w(SiO_2)=64.87%~74.71%)、高碱(w(K_2O)=3.35%~4.68%,w(Na_2O)=2.26%~3.85%)、富铝(w(Al_2O_3)=11.82%~14.13%)和低MgO(w(MgO)=0.56%~2.12%)、CaO(w(CaO)=1.68%~3.74%)、TiO_2(w(TiO_2)=0.26%~0.57%)、P_2O_5(w(P_2O5)=0.01%~0.19%)特征,A/CNK=0.83~1.00;富集Ba、K、La、Ce、Nd,亏损Th、Nb、Ta、Sr、Ti,铕负异常较明显(δEu=0.70~0.73);具有岛弧型花岗岩特征。四顶黑山花岗岩体形成于岛弧环境,属于觉罗塔格洋向南俯冲过程中的产物。四顶黑山花岗岩体两侧的镁铁-超镁铁质岩体的形成时代应晚于晚泥盆世。     

Development of groundwater favourability map using GIS-based driven data mining models: an approach for effective groundwater resource management

The development of groundwater favourability map is an effective tool for the sustainability management of groundwater resources in typical agricultural regions, such as southern Perak Province, Malaysia. Assessing the potentiality and pollution vulnerability of groundwater is a fundamental phase of favourability mapping. A geographic information system (GIS)-based Boolean operator of a spatial analyst module was applied to combine a groundwater potentiality map (GPM) model and a groundwater vulnerability to pollution index (GVPI) map, thereby establishing the favourable zones for drinking water exploration in the investigated area. The area GPM model was evaluated by applying a GIS-based Dempster–Shafer–evidential belief function model. In the evaluation, six geoelectrically determined groundwater potential conditioning factors (i.e. overburden resistivity, overburden thickness, aquifer resistivity, aquifer thickness, aquifer transmissivity and hydraulic conductivity) were synthesized by employing the probability-based algorithms of the model. The generated thematic maps of the seven hydrogeological parameters of the DRASTIC model were considered as pollution potential conditioning factors and were analysed with the developed ordered weighted average–DRASTIC index model algorithms to construct the GVPI map. Approximately 88.8 and 85.71% prediction accuracies for the Groundwater Potentiality and GVPI maps were established using the reacting operating characteristic curve method and water quality status–vulnerability zone relationship scheme, respectively. Finally, the area groundwater favourability map (GFM) model was produced by applying a GIS-based Boolean operator on the Groundwater Potentiality and GVPI maps. The GFM model reveals three distinct zones: ‘not suitable’, ‘less suitable’ and ‘very suitable’ zones. The area analysis of the GFM model indicates that more than 50% of the study area is covered by the ‘very suitable’ zones. Results produce a suitability map that can be used by local authorities for the exploitation and management of drinking water in the area. The study findings can also be applied as a tool to help increase public awareness of groundwater issues in developing countries.     

DYYZ-Ⅱ型自动气象站测温故障排除方法与思路

文章通过DYYZ-Ⅱ型自动气象站出现的一次气温、地温数据缺测故障,分析了DYYZ-Ⅱ型自动气象站出现测温故障时的故障排除过程与排除思路,为保障技术人员在处理此类故障时提供了方法和依据。