A reassessment of models for hydrocarbon generation in the Khibiny nepheline syenite complex, Kola Peninsula, Russia

Although hydrocarbon-bearing fluids have been known from the alkaline igneous rocks of the Khibiny intrusion for many years, their origin remains enigmatic. A recently proposed model of post-magmatic hydrocarbon (HC) generation through Fischer-Tropsch (FT) type reactions suggests the hydration of Fe-bearing phases and release of H₂ which reacts with magmatically derived CO₂ to form CH₄ and higher HCs. However, new petrographic, microthermometric, laser Raman, bulk gas and isotope data are presented and discussed in the context of previously published work in order to reassess models of HC generation. The gas phase is dominated by CH₄ with only minor proportions of higher hydrocarbons. No remnants of the proposed primary CO₂-rich fluid are found in the complex. The majority of the fluid inclusions are of secondary nature and trapped in healed microfractures. This indicates a high fluid flux after magma crystallisation. Entrapment conditions for fluid inclusions are 450–550 °C at 2.8–4.5 kbar. These temperatures are too high for hydrocarbon gas generation through the FT reaction. Chemical analyses of rims of Fe-rich phases suggest that they are not the result of alteration but instead represent changes in magma composition during crystallisation. Furthermore, there is no clear relationship between the presence of Fe-rich minerals and the abundance of fluid inclusion planes (FIPs) as reported elsewhere. δ¹³C values for methane range from − 22.4‰ to − 5.4‰, confirming a largely abiogenic origin for the gas. The presence of primary CH₄-dominated fluid inclusions and melt inclusions, which contain a methane-rich gas phase, indicates a magmatic origin of the HCs. An increase in methane content, together with a decrease in δ¹³C isotope values towards the intrusion margin suggests that magmatically derived abiogenic hydrocarbons may have mixed with biogenic hydrocarbons derived from the surrounding country rocks.     

Polarization-mode separation and the emission geometry of pulsar 0823 + 26: A new pattern of pulsar emission?

We explore the detailed polarization behaviour of pulsar 0823 + 26 using the technique of constructing partial ‘mode-separated’ profiles corresponding to the primary and secondary polarization modes. The characteristics of the two polarization modes in this pulsar are particularly interesting, both because they are anything but orthogonal and because the secondary mode exhibits a structure seen neither in the primary mode nor in the total profile. The new leading and trailing features in the secondary mode, which appear to represent a conal component pair, are interpreted geometrically on the basis of their width and the associated polarization-angle traverse as an outer cone. If the secondary-mode features are, indeed, an outer cone, then questions about the significance of the pulsar’s postcursor component become more pressing. It seems that 0823 + 26 has a very nearly equatorial geometry, in that both magnetic poles and the sightline all fall close to the rotational equator of the star. We thus associate the postcursor component with emission along those bundles of field lines which are also equatorial and which continue to have a tangent in the direction of our sight line for a significant portion of the star’s rotation cycle. It seems that in all pulsars with postcursor components, this emission follows the core component, and all may thus have equatorial emission geometries. No pulsars with precursors in this sense — including the Crab pulsar — are known. The distribution of power between the primary and secondary modes is very similar at both 430 and 1400 MHz. Our analysis shows that in this pulsar considerable depolarization must be occurring on time scales that are short compared to the time resolution of our observations, which is here some 0.5–1.0 milliseconds. One of the most interesting features of the modeseparated partial profiles is a phase offset between the primary and secondary modes. The secondary-mode ‘main pulse’ arrives some 1.5 ± 0.1‡ before the primary-mode one at 430 MHz and some 1.3 +0.1 ‡ at 21 cm. Given that the polar cap has an angular diameter of 3.36‡, we consider whether this is a geometric effect or an effect of differential propagation of the two modes in the inner magnetosphere of the pulsar.     

The topology and polarization of subbeams associated with the 'drifting' subpulse emission of pulsar B0943+10 – V. A new look at the low-frequency burst-mode emission

This paper reports new observations of pulsar B0943+10 carried out at the Pushchino Radio Astronomy Observatory (PRAO) at the low radio frequencies of 42, 62 and 112 MHz. B0943+10 is well known for its exquisitely regular burst-mode (B-mode) drifting subpulses as well as its weaker and chaotic quiescent mode. Earlier Arecibo investigations at 327 MHz have identified remarkable, continuous changes in its B-mode subpulse drift rate and integrated-profile shape with durations of several hours. These PRAO observations reveal that the changes in profile shape during the B-mode lifetime are strongly frequency dependent – namely the measured changes in the component amplitude ratio are more dramatic at 327 and 112 MHz as compared with those at 62 and 42 MHz. The differences, however, are most marked during the first several tens of minutes after B-mode onset; after an hour or so the profile shape changes tend to be more similar at all four frequencies. We also have found that the linear polarization of the integrated profile increases continuously throughout the lifetime of the B mode, going from hardly 10 per cent just after onset to some 40–50 per cent after several hours. Pulsar B0943+10's B mode thus provides a unique new opportunity to investigate continuous systematic changes in the plasma flow within the polar flux tube. While refraction in the pulsar's magnetosphere may well play some role, we find that the various frequency-dependent effects, both between and within the two modes, can largely be understood geometrically. If the modes and B-mode decay reflect systematic variations in the carousel-'spark' radius and emission height then a specific set of profile and linear polarization changes would be expected.     

Fluid-rock interaction during progressive migration of carbonatitic fluids, derived from small-scale trace element and Sr, Pb isotope distribution in hydrothermal fluorite

Associated with the Cretaceous Okorusu carbonatite complex (Namibia) is a hydrothermal fluorite mineralization hosted in Pan-African country rock marbles, which resulted from fluid-rock reaction between the marbles and orthomagmatic, carbonatitic fluids expelled from the carbonatite. Yellow fluorite I was deposited in veins up to 5 cm away from the wallrock contact, followed by purple and colorless fluorite II, smoky quartz and barite, a Mn-rich crust on early calcite, and pure calcite. This clear-cut sequence of mineral growth allows an investigation into fluid-rock interaction processes between the marble and the migrating carbonatitic fluid, and element fractionation patterns between the fluid and subsequent hydrothermal precipitates.Fluorite I shows a progressive change in color from dark yellow to colorless with purple laminations over time of deposition. Subsequent fluorite I precipitates show an increase in Ca, and a continuous decrease in F, Sr, REE, Y, Th, U and Pb contents. The ratios (Eu/Eu*)_cn, Th/Pb and U/Pb increase whereas Y/Ho, Th/U and (La/Yb)_cn decrease. The Sr-isotopic composition remains constant at ⁸⁷Sr/⁸⁶Sr = 0.70456-0.70459, but with varying, highly radiogenic Pb (²⁰⁶Pb/²⁰⁴Pb = 32-190, ²³⁸U/²⁰⁴Pb = 7-63). Fluorite II has ⁸⁷Sr/⁸⁶Sr = 0.70454-0.70459, ²⁰⁶Pb/²⁰⁴Pb = 18.349, and ²⁰⁷Pb/²⁰⁴Pb = 15.600, and a chemical composition similar to youngest fluorite I. The Mn-rich crust on early calcite accumulated REE, Ba, Pb, Zr, Cs, Th and U, developing into pure calcite with a prominent negative Ce anomaly and successively more radiogenic Sr. The calculated degrees of fluid-rock interaction, f = weight fraction of fluid/(fluid + marble), decrease from fluorite I and most fluorite II (f = 0.5) to calcite (f = 0.2-0.3) and hydrothermal quartz (f ? 0.1). A crush-leach experiment for fluid inclusions in the hydrothermal quartz yielded a Rb-Sr isochron age of 103 ± 12 Ma. Crush-leach analysis for the carbonatitic fluid trapped in the wallrock yielded a trend from the fluid leachate to the host quartz (²⁰⁶Pb/²⁰⁴Pb = 18.224 and 18.602, ²⁰⁷Pb/²⁰⁴Pb = 15.616 and 15.636, respectively) extending from carbonatite towards crustal rocks.Calculated trace element distribution coefficients fluorite/fluid are below unity throughout, and increase from La to Yb. Elements largely excluded from fluorite (Ba, Pb, LREE relative to HREE) were incorporated later into the Mn-rich crust on calcite. The trace element patterns of the hydrothermal minerals are related to changing aCO₂ and aF⁻ in the fluid during continued fluid-marble reaction. A predominance of carbonate over fluoride complexing in the fluid as reactions proceeded controlled the Y/Ho, Th/U and REE patterns in the fluid and the crystallizing phases. Deviations from these trends indicate discontinuous processes of fluid-rock reaction.     

Periodic nulls in the pulsar B1133+16

Numerous studies of the brightest Cambridge pulsar, B1133+16, have revealed little order in its individual pulses, apart from a weak 30-odd-rotation-period fluctuation feature and that some 15 per cent of the star's pulsars are 'nulls'. New Arecibo observations confirm this fluctuation feature and that it modulates all the emission, not simply the 'saddle' region. By replacing each pulse with a scaled version of the average profile, we were able to quench all subpulse modulation and thereby demonstrate that the star's 'null' pulses exhibit a similar periodicity. A subbeam carousel model with a sparse and irregular 'beamlet' population appears to be compatible with these characteristics.     

Nonlinear field line resonances. Effect of Hall term on plasma compression: 1D Hall-MHD modeling

A model is presented that describes the excitation of small-scale density perturbations and electromagnetic fields by standing shear Alfvén waves in a Cartesian geometry. The model includes the effects of plasma betas and the Hall term effects. The characteristics of magnetospheric density cavities and the formation of the significant peak in density are discussed in the paper.