Urban geology: Glasgow's hidden industrial heritage

The growth of Glasgow from a small town into a heavily industrialised conurbation depended greatly on its local geological riches. Extensive mining and quarrying of a range of minerals took place from the 18th century onwards. The early underground stoop and room (pillar and stall) workings, and the backfilled quarries, together with variably consolidated natural superficial deposits, have bequeathed to the city a heritage of unwanted engineering problems which cannot easily be quantified. Recent work by the British Geological Survey (BGS) illustrates the scale of both geological and man-made problems.     

A sedimentary record from a deep Quaternary valley in the southern Lillebælt area, Denmark: Eemian and Early Weichselian lithology and chronology at Mommark

A unique sequence of Late Saalian, Eemian and Early Weichselian strata is exposed in a coastal outcrop at Mommark in the western Baltic. The sedimentary facies and faunas reflect palaeoenvironmental changes from an initial freshwater lake followed by marine transgression and interglacial deposition in a palaeo-Baltic sea. The upper part of the Eemian marine record indicates regression followed by lacustrine sedimentation and deposition of Early Weichselian aeolian sediments, which are truncated by an erosional unconformity overlain by a till bed. The lower and middle parts of the sequence have previously been correlated with the European glacial-interglacial stratigraphy on the basis of pollen analysis, while the upper part has been dated for the present study using optically stimulated luminescence (OSL) of samples from the aeolian and glacial deposits. A similar complete glacial-interglacial-glacial succession has not previously been recorded from this area. The Mommark sequence of conformable strata has been subjected to lateral compression, evidenced by folding and low-angle reverse faults. Seismic records from the adjacent waters in the western Baltic reveal a system of buried Quaternary valleys in the area. It is suggested that the interglacial deposition took place in a basin within one of these valleys and that a slab constituting the Mommark sequence, originating from the margin of a valley, has been glaciotectonically displaced northwestwards to the present location.     

Intriguing climatic shifts in a 90 kyr old lake record from northern Russia

A 22 m long sediment core from Lake Yamozero on the Timan Ridge in northern Russia has provided evidence of intriguing climatic shifts during the last glacial cycle. An overall shallowing of the lake is reflected in the lower part of the cores, where pollen indicates a transition from glacial steppe vegetation to interstadial shrub-tundra. These beds are capped by a well-defined layer of compact clay deposited in relatively deep water, where pollen shows surrounding spruce forests and warmer-than-present summer temperatures. The most conservative interpretation is that this unit represents the last interglacial period. However, a series of Optical Stimulated Luminescence (OSL) dates suggests that it corresponds with the Early Weichselian Odderade interstadial (MIS 5a). This would imply that the Odderade interstadial was just as warm as a normal interglacial in this continental part of northern Europe. If correct, then pollen analysis, as a correlation tool, is less straightforward and the definition of an interglacial is more complex than previously thought. We discuss the validity and possible systematic errors of the OSL dates on which this age model is based, but conclude they really indicate a MIS 5a age for the warm period. Above the clay is an unconformity, most likely reflecting a period of subaerial exposure implying dry conditions. Deposition of silt under fluctuating cold climates in the Middle Weichselian continued until a second gap in the record at c . 40 kyr BP. The lake basin started to fill up again around 18 kyr BP.     

New evidence of the Littorina transgressions in the Kattegat: Optically Stimulated Luminescence dating of a beach ridge system on Anholt, Denmark

Recent geomorphological and sedimentological investigation of the raised beach ridge plain on Anholt in the Kattegat Sea, Denmark, has demonstrated how these deposits, when combined with Optically Stimulated Luminescence (OSL) dating, can provide information about past changes in relative sea level. The southwest–northeast trending plain is divided into three topographic levels, one of which has been surveyed using Ground-Penetrating Radar (GPR). Samples retrieved from the survey line indicate that the initial part of the beach ridge plain formed about 7700 years ago in response to a mid-Holocene Littorina transgression. The raised marine deposits document a subsequent rise in relative sea level of about 9 m, and OSL dates indicate that this transgression took place about 6650 years ago. The flooding of the Kattegat Sea 7700 years ago might possibly be related to a rapid global sea-level rise peaking around 7500 years ago.     

Distribution of Ferric Iron in some Upper-Mantle Assemblages

The distribution of ferric iron among the phases of upper-mantlerocks, as a function of pressure (P), temperature (T) and bulkcomposition, has been studied using ⁵⁷Fe Mssbauer spectroscopyto determine the Fe³⁺/Fe ratios of mineral separates from 35peridotite and pyroxenite samples. The whole-rock Fe³⁺ complementof a peridotite is typically shared approximately evenly amongthe major anhydrous phases (spinel and/or garnet, orthopyroxeneand clinopyroxene), with the important exception of olivine,which contains negligible Fe³⁺. Whole-rock Fe³⁺ contents areindependent of the T and P of equilibration of the rock, butshow a well-defined simple inverse correlation with the degreeof depletion in a basaltic component. Fe³⁺ in spinel and inboth pyroxenes from the spinel Iherzolite facies shows a positivecorrelation with temperature, presumably owing to the decreasein the modal abundance of spinel. In garnet peridotites, theFe³⁺ in garnet increases markedly with increasing T and P, whereasthat in clinopyroxene remains approximately constant. The complexnature of the partitioning of Fe³⁺ between mantle phases resultsin complicated patterns of the activities of the Fe³⁺ -bearingcomponents, and thus in calculated equilibrium f_O2, which showlittle correlation with whole-rock Fe³⁺ or degree of depletion.Whether Fe³⁺ is taken into account or ignored in calculatingmineral formulae for geothermobarometry can have major effectson the resulting calculated T and P. For Fe-Mg exchange geothermometers,large errors must occur when applied to samples more oxidizedor reduced than the experimental calibrations, whose f_O2 conditionsare largely unknown. Two-pyroxene thermometry is more immuneto this problem, and probably provides the most reliable P—Testimates. Accordingly, the convergence of P—T valuesderived for a given garnet peridotite assemblage may not necessarilybe indicative of mineral equilibrium. The prospects for thecalculation of accurate Fe³⁺ contents from electron microprobeanalyses by assuming stoichiometry are good for spinel, uncertainfor garnet, and distinctly poor for pyroxenes. KEY WORDS: mantle; oxidation; partitioning; peridotite; thermobarometry ^*Corresponding author. Present address: School of Earth and Ocean Sciences, University of Victoria, P.O. Box 1700, Victoria, B.C., V8W 2Y2, Canada     

Multiple Isotopic Components in Quaternary Volcanic Rocks of the Cascade Arc near Crater Lake, Oregon

Quaternary lavas and pyroclastic rocks of Mount Mazama, CraterLake caldera, and the surrounding area have variable Sr, Nd,and Pb isotopic compositions. High-alumina olivine tholeiites(HAOT) have ⁸⁷Sr/⁸⁶Sr ratios of 0.70346–0.70364; basalticandesite, 0–70349–0.70372; shoshonitic basalticandesite, 0.70374–0.70388; and andesite, 0.70324–0.70383.Dacites of Mount Mazama have ⁸⁷Sr/⁸⁶Sr ratios of 0.70348–0.70373.Most rhyodacites converge on 0.7037. However, rhyodacite ofthe caldera-forming, climactic eruption has ⁸⁷Sr/⁸⁶Sr=0.70354because of an admixed low-⁸⁷Sr/⁸⁶Sr component. Andesitic tomafic-cumulate scoriae of the climactic eruption, and enclavesin preclimactic rhyodacites, cluster in two groups but shownearly the entire ⁸⁷Sr/⁸⁶Sr range of the data set, confirmingpreviously suggested introduction of diverse parental magmasinto the growing climactic chamber. Pb and Nd isotope ratiosdisplay less variation (²⁰⁶Pb/²⁰⁴Pb= 18.838–18.967, ²⁰⁷Pb/²⁰⁴Pb=15.556–15.616,²⁰⁸Pb/²⁰⁴Pb=38.405–38.619; _Nd= +3.9 to +6.1) and generallycovary with ⁸⁷Sr/⁸⁶ Sr ratios. Radiogenic isotope data fromCrater Lake plot with published data for other Cascade volcanoeson isotope ratio correlation diagrams. The isotopic data for the Crater Lake area require sources ofprimitive magmas to consist of depleted mantle and a subductioncomponent, introduced in variable quantity to the depleted mantlewedge. Variable degrees of melting of this heterogeneous mantle,possibly at different depths, produced the diversity of isotopiccompositions and large-ion lithophile element (LILE) abundancesin primitive magmas. Trace element ratios do not indicate presenceof an ocean island basalt (OIB) source component that has beenreported in lavas of some other Cascade volcanoes. Crustal contamination may have affected isotope ratios and LILEconcentrations in evolved HAOT, where initial LILE concentrationswere low. Contamination is more difficult to detect in the calcalkalinelavas because of their higher LILE concentrations and the smallisotopic contrast with likely contaminants, such as mid- tolower-crustal rocks thought to be equivalents of igneous rocksof the Klamath Mountains and associated lower crust. Crustalassimilation appears to be required for calcalkaline rocks onlyby ¹⁸O values, which vary from lows of +5.6 to + 6.0% in HAOTand primitive basaltic andesites to a high of +7.0% in dacite,a range that is too high to be explained by plagioclase-dominatedclosed-system fractional crystallization. Elevated ¹⁸O valuesof differentiated lavas may be attributed to interaction withrelatively ¹⁸O-rich, ⁸⁷Sr-poor crustal rocks. Variably fused granitoid blocks ejected in the climactic eruption,and rarely in late Pleistocene eruptive units, have ¹⁸Opl of–3.4 to +6.5% and ¹⁸O_qz of –2.2 to +8.0% but haveSr, Nd, and Pb isotope ratios similar to volcanic rocks (e.g.⁸⁷Sr/⁸⁶Sr0.7037). Rb and Sr data for glass separates from granodioritessuggest that the source pluton is Miocene. Glass from granodioritehas ⁸⁷Sr/⁸⁶Sr ratios as high as 0.70617. Oxygen isotope fractionationbetween quartz, plagioclase, and glass indicates requilibrationof O isotopes at magmatic temperatures, after ¹⁸O/¹⁶O had beenlowered by exchange with meteoric hydrothermal fluids. Unmeltedgranodiorite xenoliths from pre-climactic eruptive units have¹⁸O values that are consistent with onset of hydrothermal exchangeearly during growth of the climactic magma chamber. Assimilationof such upper-crustal granodiorite apparently lowered ¹⁸O valuesof rhyodacites without significantly affecting their magmaticcompositions in other ways.     

The Little Ice Age glacier maximum in Iceland and the North Atlantic Oscillation: evidence from Lambatungnajökull, southeast Iceland

This article examines the link between late Holocene fluctuations of Lambatungnajökull, an outlet glacier of the Vatnajökull ice cap in Iceland, and variations in climate. Geomorphological evidence is used to reconstruct the pattern of glacier fluctuations, while lichenometry and tephrostratigraphy are used to date glacial landforms deposited over the past ˜400 years. Moraines dated using two different lichenometric techniques indicate that the most extensive period of glacier expansion occurred shortly before c . AD 1795, probably during the 1780s. Recession over the last 200 years was punctuated by re-advances in the 1810s, 1850s, 1870s, 1890s and c . 1920, 1930 and 1965. Lambatungnajökull receded more rapidly in the 1930s and 1940s than at any other time during the last 200 years. The rate and style of glacier retreat since 1930 compare well with other similar-sized, non-surging, glaciers in southeast Iceland, suggesting that the terminus fluctuations are climatically driven. Furthermore, the pattern of glacier fluctuations over the 20th century broadly reflects the temperature oscillations recorded at nearby meteorological stations. Much of the climatic variation experienced in southern Iceland, and the glacier fluctuations that result, can be explained by secular changes in the North Atlantic Oscillation (NAO) Advances of Lambatungnajökull generally occur during prolonged periods of negative NAO index. The main implication of this work relates to the exact timing of the Little Ice Age in the Northeast Atlantic. Mounting evidence now suggests that the period between AD 1750 and 1800, rather than the late 19th century, represented the culmination of the Little Ice Age in Iceland.     

The Sulfide Capacity and the Sulfur Content at Sulfide Saturation of Silicate Melts at 1400{degrees}C and 1 bar

The solubility of sulfur as S^2– has been experimentallydetermined for 19 silicate melt compositions in the system CaO–MgO–Al₂O₃–SiO₂(CMAS)± TiO₂ ± FeO, at 1400°C and 1 bar, using CO–CO₂–SO₂gas mixtures to vary oxygen fugacity (fO₂) and sulfur fugacity(fS₂). For all compositions, the S solubility is confirmed tobe proportional to (fS₂/fO₂)^1/2, allowing the definition ofthe sulfide capacity (C_S) of a silicate melt as C_S = [S](fO₂/fS₂)^1/2.Additional experiments covering over 150 melt compositions,including some with Na and K, were then used to determine C_Sas a function of melt composition at 1400°C. The resultswere fitted to the equation