CO2 transfer between the upper mantle and the atmosphere: temporary storage in the lower continental crust

The CO₂ atmospheric content has shown large variations over geological times. High contents (up to one order of magnitude more than present-day values) ultimately correspond to discrete episodes of mantle degassing, either juvenile, or subduction-related (carbon recycling). A number of arguments (e.g. the continuous volume increase of carbonate-bearing sediments with time) suggest that, throughout the Earth's history, juvenile CO₂ has formed a major contribution to the global carbon budget of the Earth.
The absence of a direct relationship between major volcanic episodes and the average CO₂ atmospheric content suggests that volcanoes might not be the only way by which mantle CO₂ is transported to the surface. It is proposed that large quantities of juvenile CO₂ could temporarily be stored in the lower continental crust during major episodes of granulite formation. These are primarily caused by magmatic underplating and they result in a vertical accretion of the crust by accumulation of CO₂-bearing, mantle-derived magmas. Most of the CO₂ migrates through the crust during post-metamorphic evolution and isostatic restoration of the normal continental thickness. However, large quantities of CO₂ can still be present in some areas, notably as high-density fluids enclosed in minerals.     

Application of a confluence‐based sediment‐fingerprinting approach to a dynamic sedimentary catchment,New Zealand

Fine sediment is a dynamic component of the fluvial system, contributing to the physical form, chemistry and ecological health of a river. It is important to understand rates and patterns of sediment delivery, transport and deposition. Sediment fingerprinting is a means of directly determining sediment sources via their geochemical properties, but it faces challenges in discriminating sources within larger catchments. In this research, sediment fingerprinting was applied to major river confluences in the Manawatu catchment as a broad‐scale application to characterizing sub‐catchment sediment contributions for a sedimentary catchment dominated by agriculture. Stepwise discriminant function analysis and principal component analysis of bulk geochemical concentrations and geochemical indicators were used to investigate sub‐catchment geochemical signatures. Each confluence displayed a unique array of geochemical variables suited for discrimination. Geochemical variation in upstream sediment samples was likely a result of the varying geological source compositions. The Tiraumea sub‐catchment provided the dominant signature at the major confluence with the Upper Manawatu and Mangatainoka sub‐catchments. Subsequent downstream confluences are dominated by the upstream geochemical signatures from the main stem of Manawatu River. Variability in the downstream geochemical signature is likely due to incomplete mixing caused in part by channel configuration. Results from this exploratory investigation indicate that numerous geochemical elements have the ability to differentiate fine sediment sources using a broad‐scale confluence‐based approach and suggest there is enough geochemical variation throughout a large sedimentary catchment for a full sediment fingerprint model. Combining powerful statistical procedures with other geochemical analyses is critical to understanding the processes or spatial patterns responsible for sediment signature variation within this type of catchment. Copyright © 2015 John Wiley & Sons, Ltd.     

Modelling the effect of land management interventions and climate change on sediment loads in the Manawatū–Whanganui region

ABSTRACT

SedNetNZ is used to model the effect of erosion control undertaken under the Sustainable Land Use Initiative (SLUI) and predict the effect of climate change on sediment load in the Manawatū–Whanganui region. Sediment load in 2004 is estimated at 13.4?Mt?yr^?1; by 2018, ≈5000?km² of land had farm plans implemented and annual sediment load reduced by 6.2% of the 2004 load. If SLUI stops at the 2018 level of implementation, by 2038 it is predicted to achieve a 15.7% reduction in annual sediment load. If SLUI continues to implement farm plans, 7949?km² of land will be treated by 2043 and annual sediment load could be reduced by a further 14.7%. Climate change is predicted to substantially increase sediment loads. By 2043 annual sediment load for the region is predicted to increase, compared to 2004, by between 8.3 and 23.7%. However, this can largely be offset by SLUI works. By 2090 an annual sediment load increase of between 53 and 224% due to climate change is predicted. The results suggest climate warming may dominate changes in sediment load in the future.     

Epi- and endobiont faunal communities on an Egyptian Mediterranean rocky shore: species composition and their competition for space

The exposed calcareous rocky area of the Abu Qir Headland,east of Alexandria,Egypt which range from coarse grains,through pebbles,cobbles,and boulders to rocky platforms,was significantly colonized by sclerobionts(epibionts and endobionts).The epibiont species diversity was comparatively higher than that of endobionts.Epibiont communities included bryozoans(the anascan-grade cheilostome Bifiustra savartii),serpulid(Hydroides elegans,Spirobranchus cf.tetraceros,Vermiliopsis striaticeps and Protula or Apomatus) and spirorbid(Spirorbis) wormtubes,and balanoid barnacles(Amphibalanus amphitrite,Balanus trigonus,and Perforatus perforatus).The cheilostome bryozoan colonies,which developed extensive sheets,proliferated on the study rocky shore either encrusting the bioeroded basement directly,or encrusting other epilithic taxa,particularly balanoid barnacles and serpulid worms.Encrusters displayed a remarkable marginal competitive interaction(overgrowth and stand-off) for space on the study rocky shore.On the other hand,endobionts were not well represented on the studied rocky shore exposure.It was possible to identify three ichnotaxa:Gastrochaenolites,Maeandropolydora,and Finichnus.The findings documented represent a significant contribution to our knowledge of sclerobionts composition,sequence of their colonization and/or bioero sion,and their mutual relationships on the intertidal rocky shore of the Abu Qir Headland.     

Storm event sediment fingerprinting for temporal and spatial sediment source tracing

Sediment fingerprinting has been widely used to distinguish discrete sediment sources; however, application to intra-storm sediment source variability has received relatively little focus despite the benefit being long recognized. In this investigation, sediment fingerprinting was applied to a 53-hr storm event sampled hourly to determine sediment source dynamics throughout the event. Sediment sources were differentiated using 16 variables, and source contribution determined using Bayesian and Frequentist mixing models for comparison. Both models provided comparable source predictions for the dominant source estimates and the general temporal pattern. The Frequentist model appeared to exhibit some unreliable values coinciding with low GOF and attributed to inherent model structure. The Bayesian model showed higher uncertainty, likely due to the “process error” utilized associated with single sample mixtures. High variability in sediment source contribution was observed between hourly time steps; however, local smoothing reveals temporal trends during the event. A higher average proportion of mudstone is found in the falling limb (0.544) compared with the rising limb (0.464), and the reverse is observed for mountain range (0.218 vs. 0.283) and unconsolidated (0.073 vs. 0.055). In the initial hours of the storm, mudstone source contribution significantly drops, whereas mountain range and unconsolidated contributions peak. The SSC-Q clockwise hysteresis indicates proximal sediment sources, suggesting the mudstone sediment is stored channel sediment and easily entrained. This sediment flushes through, coinciding with a drop as the distal mountain range and unconsolidated sources arrive to peak contribution. The wider Manawatū discharge and sediment load then arrive, delivering increasing levels of mudstone throughout the remainder of the event while mountain range sediment diminishes. Spatial representation of the sediment source contribution was derived from distributing sediment source loads to the spatial extent of the source material according to sub-catchment sediment loads and was weighted according to slope. This provided an effective means to visualize the origin of the sediment and a better spatial interpretation of sediment fingerprinting results, which is typically limited by poor spatial resolution.     

Predicting spatial patterns in riverbank erosion for catchment sediment budgets

Riverbank erosion is an important component of catchment sediment budget models but remains one of the least well-understood processes, particularly at large spatial scales. Here, we develop and test a new bank migration model in New Zealand for large catchment applications that (1) better represents spatial variability in factors influencing bank erosion and (2) improves predictive performance. We represent bank migration rates as a function of reach-scale stream power, channel sinuosity, soil texture, valley confinement, riparian woody vegetation and channel protection works. The new model significantly improves prediction compared to the SedNetNZ model. Comparison of measured bank migration rates with individual variables shows percent silt + clay derived from soil maps exhibited the strongest correlation, whereas other variables were non-significant. The model results demonstrate that improved prediction can be achieved by combining spatial representation of multiple factors over large areas, despite low correlation between individual variables and bank migration rates.     

Late Eocene marginal marine deposits and paleoenvironment characterisation from the Maadi Formation (Northern Eastern Egypt)

Two beds containing relatively thick and highly concentrated oyster shell banks occurring in the densely fossiliferous Wadi Al Abraq outcrop (Upper Eocene Maadi Formation, Cairo-Sukhna Road, Egypt). Such shell beds are almost monospecific. The upper level consists mainly of Ostrea clotbeyi Bellardi, topped by a considerable concentration of Carolia placunoides Cantraine, while in the lower level occurs Ostrea multicostata Deshayes. In both beds, the upper contact with the overlying marl bed (about 2 m thick) is sharp and sometimes erosive. Similarly, the contact with the underlying shale (1.5 m thick) is sharp and erosional. The shell beds are composed mainly of loosely packed oyster shells and their fragments (usually with a high proportion of disarticulated specimens) set in the sandy limestone matrix. The collected oysters show bioerosion and skeletobiont assemblages. Bioerosion trace fossils comprise ten ichnospecies while skeletozoans comprise five taxa. In general, shells of O. clotbeyi show a higher incidence of bioerosion than O. multicostata. The shells' chaotic orientation and their moderate fragmentation indicate that the shell bed formation was associated with high energy events. On the other hand, the low frequency of articulated specimens suggests that the shell beds are parautochthonous oyster banks' remnants. The taphonomic features of the studied assemblage indicate deposition in a shallow-water, wave-dominated environment.     

Homogenisation and trend detection analysis of broken series of solar UV-B data

Summary Statistical techniques have been developed to homogenise a broken series of clear-sky solar UV-B radiation, measured by a Robertson Berger (RB) meter over the period 1981–90 at Invercargill, New Zealand, and to analyse the series for long term trend. Statistical modelling of the quasi-linear UV-B/ozone relationship evident in the departures of daily clear-sky UV-B data and coincident satellite ozone data from their respective mean references has been used to provide a self-consistent de-seasonalised data set of UV-B and ozone departures, and to bridge a major gap in calibration that separates the data set into two periods, 1981–86 and 1988–90. The choice of UV-B reference is important to the quality of the results and particular attention was given to the methodology for defining it. Four alternative objective adjustment procedures for calibrating the 1988–90 period against the 1981–86 period were examined. Because our interest lies primarily in the higher values of summer, a UV-B-weighted procedure was chosen. The modelling and homogenisation techniques developed may have application in related analysis problems. Analysis of the data for the independent 1981–86 period showed large trends in ozone and UV-B, but this was mostly due to a period of very low ozone values during 1985. Over the whole period, 1981–90, the ozone trend was –4.7%/decade. The corresponding UV-B trend was +5.8%/decade, but this result is not independent of the corresponding ozone trend because the homogenisation procedure imposes the assumption of the derived UV-B/ozone relationship on the 1988–90 UV-B data. However, the evidence suggests there is little reason to doubt that solar UV-B radiation has increased at the site by about +6% per decade.With 10 Figures     

Soil-stratigraphic techniques in the study of soil and landform evolution across the Southern Alps, New Zealand

The Southern Alps lie along the convergent Pacific-Indian plate boundary. Geomorphically distinct eastern, axial and western regions reflect the east-west gradient in tectonic uplift (1 to 10 mm a⁻¹) and precipitation (600 to 10,000 mm a⁻¹). The eastern region is divided into front-ange and basin-and-range subregions. Soil-sequence studies on terraces established temporal contrasts in pedogenesis within and between eastern and western regions encompassing Entisols, Inceptisols and Spodosols. On Late Pleistocene and early Holocene terraces Dystrochrepts are persistent soils in the eastern region and Aquods in the western region. These soil sequences are used in the interpretation of relative soil age, stratigraphy and erosion history in hill and mountain drainage basins of the eastern and western regions. In the subhumid to humid eastern front-range subregion, simple soil forms occur as catenary sequences, and there is little evidence of erosion following the destruction of forests in the last millenium. Mollisols are dominant in the subhumid, and Dystrochrepts in humid areas, respectively. Soil-debris mantle regoliths date from the early Holocene and are still developing on slopes. The soil pattern on mountain slopes in the humid, eastern basin-and-range subregion is a complex array of simple, eroded, composite and compound soils. This pattern has resulted from erosion following forest destruction within the last millenium. The oldest surface or buried forest soils are Dystrochrepts dating from the Late Pleistocene to early Holocene. Wind erosion of these low-fertility soils contributes to the loessial sediments in which younger soils have formed. In the western region, soil patterns and soil stratigraphy indicate continous instability with a complex pattern of highly leached, shallow Orthents and bedrock outcrops on slopes. The soils are eroded from slopes within 2 ka. These contrasts in soil development and erosion periodicity in the eastern and western regions of the Southern Alps parallel the east-west contrasts in erosion rates of ca. 1–10 mm a⁻¹.