Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.     

黑龙江哈尔滨白渔泡国家湿地公园沼泽、林地和农田土壤物理、化学和生物性质差异

为了揭示黑龙江哈尔滨白渔泡国家湿地公园沼泽、林地和农田土壤物理、化学和生物性质的差异,于2018年7月25日~8月2日,在湿地公园内,在天然芦苇(Phragmites australis)沼泽、林地、旱田和水田中设置采样地,采集不同深度(0~10 cm、10~20 cm和20~30 cm)的土壤样品,测定土壤样品的物理、化学和生物指标。研究结果表明,白渔泡国家湿地公园不同采样地土壤指标存在差异;与天然芦苇沼泽土壤相比,其它采样地土壤的含水量明显偏低,土壤全氮、全磷、碱解氮和有机质含量都明显偏小,水田土壤速效磷含量偏大;天然芦苇沼泽土壤脲酶、硝酸还原酶、纤维素酶、蛋白酶和β-葡萄糖苷酶活性都高于林地和农田土壤,水田0~10 cm和10~20 cm深度土壤的硝酸还原酶活性显著高于旱田和林地;与天然芦苇沼泽土壤相比,旱田土壤小于0.25 mm的小团聚体含量偏大,而其它采样地土壤的各粒级团聚体的比例变化较小,水田土壤团聚体平均重量直径比天然芦苇沼泽和旱田土壤低。     

自然和自然贡献情景模型研究综述

本文回顾了自然和自然贡献情景模型发展的背景、历史和内容,概括总结了自然和自然贡献情景模型的发展进程以及联合国生物多样性与生态系统服务政府间科学—政策平台(IPBES)情景模型的概念框架,讨论了自然和自然贡献情景模型存在的问题和发展方向。为了在全球层面解决现有综合集成模型存在的问题,根据地球表层建模基本定理和生态环境曲面建模基本定理,提出了具有中国原创特点的自然与自然贡献情景模型概念框架。     

有关边界层问题中一类奇异积分方程新的存在性结果

对边界层理论新结果中出现的一类奇异积分方程w（t）=∫1 t（1-s）（λ＋λs＋s）/w（s）ds＋（1-t）∫t 0s/w（s）ds,t∈（0,1）进行讨论，并得出了上述方程在λ∈（-1/2,0）上正解存在性的新结果。     

居民收入与通信网络市场经济效益研究--以河北省通信网络为实例

利用Logisitic曲线模型和扩展支撑模型对居民可支配收入预测和单项消费预测，以河北省居民的收入及其消费支出为实例，研究了城镇居民和农民的可支配收入分配和单项边际消费倾向，合理建立了预测模型，并理论计算了1999～2003年的通信消费方面的边际消费倾向、预测了2004～2008年通信消费情况。最后，根据预测结果对通信网络建设提出了一些有价值的建议。     

The efifect of wave breaking on surface wave imaging by Synthetic Aperture Radar

The effect of ocean wave breaking as a non-Bragg mechanism on backscattering cross-section and modulation transfer functions (MTF) of radar was investigated based on Bragg resonance theory and parametric method. The result showed that the additional effect of wave breaking on backscattering cross-section is not more than 20% except for the small incident angle of VV polarized electromagnetic (e.m.) wave but is significant for HH polarized e.m. wave. Breaking waves lead to increase in the modulus of tilt modulation MTF and the larger the wind speed, the faster the increase. For large incident angle, the modulus of tilt modulation MTF with wave breaking decreases quickly with incident angle for HH polarization and approach to that without wave breaking for VV polarization. The hydrodynamic MTF increases 30%-60% when considering wave breaking and the increase is larger for HH polarization than for VV polarization.     

Geological environment conflicts of Kunming Basin and its urban sustainable development

Kunming Basin locates middle of Yunnan altiplano and has a particularity in geography,topographic and geological environment.With the urban dilation quickly,add the reason of the unreasonable city layout,conflicts between environment and urban resources consumption become shrill increasingly.It is human being activities that lead to vulnerability and depravation of geological environment in local.Take a few examples on geological environment to expatiate relationship between urban construction and geological environment carrying capacity,and find a way how to make a better plan for urban sustainable development to achieve new balance between man and nature in local.     

泰安市地下水污染现状与成因分析

采用参数分级评分叠加型指数法对泰安市地下水污染现状进行的评价结果显示 ,泰安地下水已遭受严重污染。地下水污染以地下水中宏量组分、NO-3 、硬度、TDS的迅速上升高以及地下水遭受人为环境物质的污染为主要标志 ;地下水污染主要受地下水系统水文地质结构、纳污河流、污水灌溉及地下水开采控制和影响 ,地下水污染是人类活动影响的结果。     

Fast iterative solution of large undrained soil‐structure interaction problems

In view of rapid developments in iterative solvers, it is timely to re‐examine the merits of using mixed formulation for incompressible problems. This paper presents extensive numerical studies to compare the accuracy of undrained solutions resulting from the standard displacement formulation with a penalty term and the two‐field mixed formulation. The standard displacement and two‐field mixed formulations are solved using both direct and iterative approaches to assess if it is cost‐effective to achieve more accurate solutions. Numerical studies of a simple footing problem show that the mixed formulation is able to solve the incompressible problem ‘exactly’, does not create pressure and stress instabilities, and obviate the need for an ad hoc penalty number. In addition, for large‐scale problems where it is not possible to perform direct solutions entirely within available random access memory, it turns out that the larger system of equations from mixed formulation also can be solved much more efficiently than the smaller system of equations arising from standard formulation by using the symmetric quasi‐minimal residual (SQMR) method with the generalized Jacobi (GJ) preconditioner. Iterative solution by SQMR with GJ preconditioning also is more elegant, faster, and more accurate than the popular Uzawa method. Copyright © 2003 John Wiley & Sons, Ltd.     

激光拉曼光谱法分析多种显微组分荧光变化及其应用

利用激发488 nm激光的氩离子激光器作为RENISHAW inVia型激光拉曼光谱仪的光源,建立了多种显微组分荧光变化(FAMM)分析方法,并对镜质体反射率明显抑制的东营凹陷有效烃源岩进行了测定。结果表明,东营凹陷有效烃源岩的有机质类型越好,镜质体反射率抑制程度越高,有效烃源岩的真实成熟度应主要处于0.64%~1.30%,而不是实测镜质体反射率所反映的0.37%~1.10%。