Experimental evidence for rapid biotic and abiotic reduction of Fe (III) at low temperatures in salt marsh sediments: a possible mechanism for formation of modern sedimentary siderite concretions

Fe (III) reduction is a key component of the global iron cycle, and an important control on carbon mineralization. However, little is known about the relative roles and rates of microbial (biotic) iron reduction, which utilizes organic matter, versus abiotic iron reduction, which occurs without carbon mineralization. This paper reports on the capacity for salt marsh sediments, which typically are rich in iron, to support abiotic reduction of mineral Fe (III) driven by oxidation of sulphide. Sediment was reacted with amorphous FeS under strictly anaerobic conditions at a range of temperatures in biotic and abiotic microcosm experiments. Fe (III) reduction driven by sulphide oxidation occurs abiotically at all temperatures, leading to Fe (II) and elemental sulphur production in all abiotic experiments. In biotic experiments elemental sulphur is also the oxidized sulphur product but higher bicarbonate production leads to FeCO₃ precipitation. Abiotic reduction of Fe (III) occurs at rates that are significant compared with microbial Fe (III) reduction in salt marsh sediments. The solid phases produced by coupled abiotic and biotic reactions, namely elemental sulphur and FeCO₃, are comparable to those seen in nature at Warham, Norfolk, UK. Furthermore, the rates of these processes measured in the microcosm experiments are sufficient to generate siderite concretions on the rapid time scales observed in the field. This work highlights the importance of abiotic Fe (III) reduction alongside heterotrophic reduction, which has implications for iron cycling and carbon mineralization in modern and ancient sediments.     

Air Pollution Exposure Index for New Zealand

This study proposes a regional air pollution exposure index (RAPEI) for Auckland, Canterbury, Otago and Wellington regions. The air pollution index multiplies an emission index (NOx emissions kg/annum), a surrogate for ambient air pollution levels, with a population density index (people per sq km), a surrogate for population exposure. Census Area Units (CAUs), and subsequently defined “key areas” within a region are ranked from 0 to 16. This is one method of investigating the effectiveness of air quality monitoring networks and identifying urban exposure airsheds in New Zealand. Results verified New Zealand's urban exposure airsheds and highlighted areas that may be potential “hot spots” in terms of relatively high ambient air pollution levels and potentially high population exposures. It is possible that these areas should be closely monitored. The GIS‐based maps also show New Zealand's permanent and temporary air quality monitoring stations.     

STRUCTURAL GLACIOLOGY OF A TEMPERATE MARITIME GLACIER: LOWER FOX GLACIER,NEW ZEALAND

This paper describes the structural glaciology of the lower Fox Glacier, a 12.7 km‐long valley glacier draining the western side of the Southern Alps, New Zealand. Field data are combined with analysis of aerial photographs to present a structural interpretation of a 5 km‐long segment covering the lower trunk of the glacier, from the upper icefall down‐glacier to the terminus. The glacier typifies the structural patterns observed in many other alpine glaciers, including: primary stratification visible within crevasse walls in the lower icefall; foliation visible in crevasses below the lower icefall; a complex set of intersecting crevasse traces; splaying and chevron crevasses at the glacier margins; transverse crevasses forming due to longitudinal extension; longitudinal crevasses due to lateral extension near the snout; and, arcuate up‐glacier dipping structures between the foot of the lower icefall and the terminus. The latter are interpreted as crevasse traces that have been reactivated as thrust faults, accommodating longitudinal compression at the glacier snout. Weak band‐ogives are visible below the upper icefall, and these could be formed by multiple shearing zones uplifting basal ice to the glacier surface to produce the darker bands, rather than by discrete fault planes. Many structures such as crevasses traces do not show a clear relationship with measured surface strain‐rates, in which case they may be ‘close to crevassing’, or are undergoing passive transport down‐glacier.     

The anatomy of a deep water mud-mound complex to the southwest of the Dinantian platform in Derbyshire, UK

ABSTRACT An elongate Waulsortian mud-mound complex developed at Dovedale on a ramp to the southwest of a developing carbonate platform in Derbyshire during Chadian (early Viséan) times. The complex occupied an area of approximately 6 km² and grew to a maximum relief of 80 m with longitudinal and transverse valleys developed near the southern margin. Five mound associated facies have been identified: mound core, mound flank (fine), mound flank (coarse), intermound (fine) and intermound (coarse). The mound core facies is a massive skeletal wackestone with comminuted sponge debris, foraminifera, ostracodes and crinoid debris set in a matrix of clotted micrite. The mound flank sediments display moderately inclined bedding surfaces. While the mound flank (fine) contains sponge debris, the mound flank (coarse) is dominated by articulated crinoid columnals, and includes algal-encrusted micritized intraclasts and coarse peloids. The well-bedded intermound (fine) facies is bituminous and micritic while the intermound (coarse) facies is composed of skeletal-peloidal-intraclast grainstones which locally contain calcified algae. Although the fauna is diverse, the density of colonization by metazoans was low and the supply of macrofossil debris modest. The clotted micrite texture is interpreted as the product of micro-organisms which precipitated and trapped fine-grained sediment. The mud-mound complex is dominated by the bathymetric assemblages B and C proposed by Lees, Hallet & Hibo which on their model of the Belgian Waulsortian, indicate depths of between 220 and 280 m. Intercalation of assemblages B/C and C/D on the northern margin of the complex is interpreted as the result of local storm disturbance. A deep water drift is postulated to explain the NW-SE alignment of the complex which probably fitted the ‘export model’ of Bosence, Rowlands & Quine. Beneath the sediment surface, phreatic flow eroded unlithified sediments and developed interconnected cavities which were filled by cement and sediment relatively eariy. Mound instability triggered the opening of fissures which filled with crinoid debris, peloids, indurated lithoclasts and micrite.