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The Skaergaard Layered Series. Part VI. Excluded Trace Elements 总被引:1,自引:2,他引:1
In contrast to the smooth trends of major elements and mineralcompositions, the excluded trace elements in the SkaergaardLayered Series have an irregular distribution that does notconform to the normal trends of Rayleigh-type fractionation.Their concentrations are about constant or even decline throughthe Lower and Middle Zones before increasing sharply to reachmaximum concentrations 100200 m above the Sandwich Horizon.As in the case of included elements, the relative concentrationsof excluded elements in coexisting phases deviate widely fromthose predicted by experimentally determined partition coefficientsunder presumed magmatic conditions. This is seen most clearlyin the immiscible melanogranophyres and conjugate ferrogabbros.Although the major elements conform to the experimentally determinedrelations for immiscible liquids, the trace elements do not;they follow a totally independent trend. The abrupt increasein the concentrations of excluded elements in the upper partof the intrusion could plausibly be attributed to an additionof new magma or to a density inversion that resulted in upwardmigration of a late liquid or fluid, but these possibilitiesare inconsistent with the compositional and spatial relationsof the upper parts of the intrusion. Although a late residualliquid certainly migrated upward, the most likely explanationfor the observed distribution of excluded elements is that thepartition coefficients were altered by volatile components,which gradually increased during the early stages of crystallizationthen began to exsolve near the top of the Middle Zone. KEY WORDS: igneous differentiation; Skaergaard intrusion 相似文献
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The oribatid mite Maudheimia wilsoni Dalenius was found to be numerous on the underside of stones at Jutulsessen (72°S, 3'E) in Dronning Maud Land, Antarctica. Daily temperature fluctuations of the microhabitat from as high as 19°C and to as low as – 17°C were observed during the austral summer. Optimal activity of the mites occurred at 10°C. Even in January the mean supercooling point of adult mites was as low as -30.8±4.7°C. Haemolymph osmolality ranged from 500 to 800mOsmol and thermal hystersis freezing points from −4.7 to −6.1°C. Adult mites had a mean water content of 43.6% and a water loss rate of 0.12 μgh−1 at 15°C and 10% relative humidity. 相似文献
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EDWARD R. D. SCOTT ALEXANDER N. KROT AKIRA YAMAGUCHI 《Meteoritics & planetary science》1998,33(4):709-719
Abstract— Carbonates in Martian meteorite Allan Hills 84001 occur as grains on pyroxene grain boundaries, in crushed zones, and as disks, veins, and irregularly shaped grains in healed pyroxene fractures. Some carbonate disks have tapered Mg-rich edges and are accompanied by smaller, thinner and relatively homogeneous, magnesite microdisks. Except for the microdisks, all types of carbonate grains show the same unique chemical zoning pattern on MgCO3-FeCO3-CaCO3 plots. This chemical characteristic and the close spatial association of diverse carbonate types show that all carbonates formed by a similar process. The heterogeneous distribution of carbonates in fractures, tapered shapes of some disks, and the localized occurrence of Mg-rich microdisks appear to be incompatible with growth from an externally derived CO2-rich fluid that changed in composition over time. These features suggest instead that the fractures were closed as carbonates grew from an internally derived fluid and that the microdisks formed from a residual Mg-rich fluid that was squeezed along fractures. Carbonate in pyroxene fractures is most abundant near grains of plagioclase glass that are located on pyroxene grain boundaries and commonly contain major or minor amounts of carbonate. We infer that carbonates in fractures formed from grain boundary carbonates associated with plagioclase that were melted by impact and dispersed into the surrounding fractured pyroxene. Carbonates in fractures, which include those studied by McKay et al. (1996), could not have formed at low temperatures and preserved mineralogical evidence for Martian organisms. 相似文献
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ALEXANDER GILLESPIE 《New Zealand geographer》1998,54(1):19-26
It has long been assumed that Māori1, like many other indigenous peoples, have utilised ecologically sustainable practices. However, over recent years a chasm has developed between many conservationists and various Māori groupings as environmental objectives and philosophies have come into conflict. This article seeks to examine this chasm, and then move towards an understanding about what may really be the basis of the claim for sustainable practices in this area. 相似文献
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Z. MARTINS C. M. O'D. ALEXANDER G. E. ORZECHOWSKA M. L. FOGEL P. EHRENFREUND 《Meteoritics & planetary science》2007,42(12):2125-2136
Abstract— –CR chondrites are among the most primitive meteorites. In this paper, we report the first measurements of amino acids in Antarctic CR meteorites. Three CRs, Elephant Moraine (EET) 92042, Graves Nunataks (GRA) 95229, and Grosvenor Mountains (GRO) 95577, were analyzed for their amino acid content using high‐performance liquid chromatography with UV fluorescence detection (HPLC‐FD) and gas chromatography–mass spectrometry (GC‐MS). Our data show that EET 92042 and GRA 95229 are the most amino acid–rich chondrites ever analyzed, with total amino acid concentrations ranging from 180 ppm to 249 ppm. The most abundant amino acids present in the EET 92042 and GRA 95229 meteorites are the α‐amino acids glycine, isovaline, α‐aminoisobutyric acid (α‐AIB), and alanine, with δ13C values ranging from +31.6‰ to +50.5‰. The carbon isotope results together with racemic enantiomeric ratios determined for most amino acids strongly indicate an extraterrestrial origin for these compounds. Compared to Elephant Moraine (EET) 92042 and GRA 95229, the more aqueously altered GRO 95577 is depleted in amino acids. In both CRs and CMs, the absolute amino acid abundances appear to be related to the degree of aqueous alteration in their parent bodies. In addition, the relative abundances of α‐AIB and β‐alanine in the Antarctic CRs also appear to depend on the degree of aqueous alteration. 相似文献
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KROON NORRIS KLAUS IAN T. ALEXANDER LEON PAUL BARDOT CHARLES E. BARKER JEAN-PIERRE BELLIER CHARLES D. BLOME LEON J. CLARKE JOCHEN ERBACHER KRISTINA L. FAUL MARY ANNE HOLMES BRIAN T. HUBER MIRIAM E. KATZ KENNETH G. MACLEOD SANDRA MARCA FRANCISA C. MARTINEZ-RUIZ ISAO MITA MUTSUMI NAKAI JAMES G. OGG DOROTHY K. PAK THOMAS K. PLETSCH JEAN M. SELF-TRIAL NICHOLAS J. SHACKLETON JAN SMIT WILLIAM USSLERIII DAVID K. WATKINS JOEN WIDMARK & PAUL A. WILSON 《Geology Today》1998,14(6):222-226
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